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Radiopaque tantalum oxide coated persistent luminescent nanoparticles as multimodal probes for in vivo near-infrared luminescence and computed tomography bioimaging

Yu‐Chen Lu、Cheng‐Xiong Yang、Xiu‐Ping Yan2015-01-01Nanoscale

The design and fabrication of multimodal imaging nanoparticles is of great importance in medical diagnosis. Here we report the fabrication of core-shell structured Zn2.94Ga1.96Ge2O10:Cr(3+),Pr(3+)@TaOx@SiO2 nanoparticles for persistent luminescence and X-ray computed tomography (CT) imaging. Persistent luminescent nan…

Luminescence Properties of Advanced MaterialsNanoplatforms for cancer theranosticsAtomic and Subatomic Physics Research

A series of tetraazalene radical-bridged M 2 (M = Cr III , Mn II , Fe II , Co II ) complexes with strong magnetic exchange coupling

Jordan A. DeGayner、Ie‐Rang Jeon、T. David Harris2015-01-01Chemical Science

. These results highlight the ability of redox-active tetraazalene bridging ligands to enable dramatic enhancement of magnetic exchange coupling upon redox chemistry and provide a rare opportunity to examine metal-radical coupling trends across a transmetallic series of complexes.

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesOrganic and Molecular Conductors Research

Trap density probing on top-gate MoS 2 nanosheet field-effect transistors by photo-excited charge collection spectroscopy

Kyunghee Choi、Syed Raza Ali Raza、Kwang H. Lee 等 11 位作者2015-01-01Nanoscale

Two-dimensional (2D) molybdenum disulfide (MoS₂) field-effect transistors (FETs) have been extensively studied, but most of the FETs with gate insulators have displayed negative threshold voltage values, which indicates the presence of interfacial traps both shallow and deep in energy level. Despite such interface tra…

Graphene research and applications2D Materials and ApplicationsNanowire Synthesis and Applications

A pH-switched Pickering emulsion catalytic system: high reaction efficiency and facile catalyst recycling

Jianping Huang、Hengquan Yang2015-01-01Chemical Communications

A smart Pickering emulsion catalytic system is constructed, which not only exhibits fivefold reaction rate enhancement effects in comparison to the conventional biphasic system but also can be facilely demulsified by tuning pH, allowing for in situ recycling nanocatalysts.

Polymer Surface Interaction StudiesMicro and Nano RoboticsPickering emulsions and particle stabilization

Nano graphene oxide-wrapped gold nanostars as ultrasensitive and stable SERS nanoprobes

Ghulam Jalani、Marta Cerruti2015-01-01Nanoscale

We report a facile method to synthesize highly branched gold nanostars wrapped with nano graphene oxide (nGO) sheets with or without the addition of Raman dyes, as nanoprobes with high SERS activity. Both cysteamine and nGO are added to gold nanostars; the positively charged amino groups help self-assembly of nGO flak…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Modulation of single-molecule magnet behaviour via photochemical [2+2] cycloaddition

Long‐Fei Wang、Jiang‐Zhen Qiu、Jun‐Liang Liu 等 8 位作者2015-01-01Chemical Communications

The first example of phototunable SMMs has been reported. Upon UV irradiation, variations of the coordination sphere around Dy(III) ions actually affect the magnetic behaviour of the compound via [2+2] cycloaddition reaction, leading to a magnetic transformation from the SMM behaviour to a field-induced slow relaxatio…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Luminescence and electrochemical properties of rare earth (Gd, Nd) doped V 2 O 5 nanostructures synthesized by a non-aqueous sol–gel route

Arumugam Venkatesan、Nagamuthu Raja Krishna Chandar、Arumugam Kandasamy 等 7 位作者2015-01-01RSC Advances

Vanadium pentoxide nanostructures have been obtained from an alkoxide sol–gel, prepared by a simple and inexpensive facile non-aqueous method.

Catalytic Processes in Materials ScienceTransition Metal Oxide NanomaterialsCatalysis and Oxidation Reactions

A novel fabrication of nitrogen-containing carbon nanospheres with high rate capability as electrode materials for supercapacitors

Hui Peng、Guofu Ma、Kanjun Sun 等 6 位作者2015-01-01RSC Advances

Nitrogen-containing polyaniline-based carbon nanospheres (C-PANI) with diameters of about 200 nm are prepared through a direct carbonization method using polyaniline (PANI) nanospheres as carbon precursors at different temperatures.

Supercapacitor Materials and FabricationElectrochemical sensors and biosensorsConducting polymers and applications

Short-term changes in intracellular ROS localisation after the silver nanoparticles exposure depending on particle size

Akira Onodera、Fumiko Nishiumi、Kisa Kakiguchi 等 13 位作者2015-01-01Toxicology Reports

• Exposing cells to nanosilver particles (AgNPs) immediately induces ROS. • Smaller AgNPs induce mitochondrial ROS production. • AgNP-induced mitochondrial ROS are independent of particle internalisation. Silver nanoparticles (AgNPs) induce the production of reactive oxygen species (ROS) and apoptosis. These effects a…

Nanoparticles: synthesis and applicationsAir Quality and Health ImpactsAnesthesia and Neurotoxicity Research

High energy density titanium doped-vanadium oxide-vertically aligned CNT composite electrodes for supercapacitor applications

Prashanth Jampani、Oleg I. Velikokhatnyi、Karan Kadakia 等 8 位作者2015-01-01Journal of Materials Chemistry A

In this study, we provide the first report on the supercapacitance behavior of titanium doped vanadium oxide films grown on vertically aligned carbon nanotubes using a chemical vapor deposition (CVD) technique.

Electrocatalysts for Energy ConversionSupercapacitor Materials and FabricationTransition Metal Oxide Nanomaterials

Selective oxidation of veratryl alcohol with composites of Au nanoparticles and graphene quantum dots as catalysts

Xiaochen Wu、Shouwu Guo、Jingyan Zhang2015-01-01Chemical Communications

Veratryl alcohol can be oxidized to veratryl aldehyde or veratric acid with excellent selectivity and efficient conversion under acidic and alkaline conditions using Au nanoparticles and graphene quantum dot composites (Au/GQDs) as catalysts.

Catalytic Processes in Materials ScienceNanomaterials for catalytic reactionsAdvanced Nanomaterials in Catalysis

Cellulose Isolation from Tropical Water Hyacinth for Membrane Preparation

Titik Istirokhatun、Nur Rokhati、Richa Rachmawaty 等 6 位作者2015-01-01Procedia Environmental Sciences

The presence of water hyacinth (Eichhornia crassipes) as an aquatic plant in many lakes or other basins causes many conservation problems. Many efforts have been devoted to overcome these problems such as by utilization of water hyacinth for energy production, for water treatment, etc. In this research, cellulose was…

Advanced Cellulose Research StudiesDNA and Biological ComputingElectrohydrodynamics and Fluid Dynamics

Hydrochlorination of acetylene using supported phosphorus-doped Cu-based catalysts

Hang Li、Fumin Wang、Wangfeng Cai 等 5 位作者2015-01-01Catalysis Science & Technology

Phosphorus doping facilitates the dispersion of copper species, enhances the interaction between metal and support, and restrains the growth of copper components during acetylene hydrochlorination.

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsNanomaterials for catalytic reactions

A pH-responsive AIE nanoprobe as a drug delivery system for bioimaging and cancer therapy

Haibo Wang、Gongyan Liu、Shihua Dong 等 6 位作者2015-01-01Journal of Materials Chemistry B

To construct a smart drug delivery system for simultaneous cellular imaging and cancer therapy, a pH-responsive amphiphilic polymer (MPEG-hyd-TPE) with aggregation-induced emission (AIE) character was designed and successfully synthesized. Polymeric micelles self-assembled from MPEG-hyd-TPE exhibited a significant AIE…

Advanced biosensing and bioanalysis techniquesNanoplatforms for cancer theranosticsLuminescence and Fluorescent Materials

High mobility flexible graphene field-effect transistors and ambipolar radio-frequency circuits

Yiran Liang、Xuelei Liang、Zhiyong Zhang 等 6 位作者2015-01-01Nanoscale

Field-effect transistors (GFETs) were fabricated on mechanically flexible substrates using chemical vapor deposition grown graphene. High current density (nearly 200 μA μm(-1)) with saturation, almost perfect ambipolar electron-hole behavior, high transconductance (120 μS μm(-1)) and good stability over 381 days were…

Graphene research and applications2D Materials and ApplicationsGraphene and Nanomaterials Applications

Targeted synthesis of core–shell porous aromatic frameworks for selective detection of nitro aromatic explosives via fluorescence two-dimensional response

Heping Ma、Bin Li、Liming Zhang 等 5 位作者2015-01-01Journal of Materials Chemistry A

A series of conjugated core–shell porous aromatic frameworks are synthesized for selective detection of nitro-explosives. The core–shell PAFs can recognize nitro aromatic explosives in the fluorescent 2D map.

Metal-Organic Frameworks: Synthesis and ApplicationsLuminescence and Fluorescent MaterialsCovalent Organic Framework Applications