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Superhydrophobic cotton textile with robust composite film and flame retardancy

Ming Zhang、Deli Zang、Junyou Shi 等 6 位作者2015-01-01RSC Advances

A cotton textile with robust composite film showed extraordinary superhydrophobicity, flame retardancy, durability and efficiency for water/organic solvent separation.

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsFlame retardant materials and properties

Construction of polyoxometalates from dynamic lacunary polyoxotungstate building blocks and lanthanide linkers

Lulu Li、Hua-Yan Han、Yonghui Wang 等 6 位作者2015-01-01Dalton Transactions

A series of polynuclear metal-oxo clusters have been constructed from the dynamic polyoxometalate (POM) building block {B-α-Sb(III)W9O33} and lanthanide (Ln) linkers via a stepwise synthetic strategy with the molecular formulas of [Ln2(H2O)4{WO2(pic)}2(SbW8O30)2](10-) (Na4Li6[La-1]·28H2O, Na3Li7[Pr-2]·30H2O) and [{Ln(…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Study of the Diffraction Grating on a Convex Surface as a Dispersive Element

С. В. Карпеев、Svetlana N. Khonina、Sergey I. Kharitonov2015-01-01Computer Optics

A dispersive element in the form of the diffraction grating on a convex mirror surface is investigated. The groove profile of the grating is measured and the intensity distribution between the diffraction orders is calculated as a function of wavelength for the visible spectrum. Optomechanical elements for the require…

Photonic and Optical DevicesAdvanced Measurement and Metrology TechniquesOptical Coatings and Gratings

Modification of both d 33 and T C in a potassium–sodium niobate ternary system

Bo Wu、Jiagang Wu、Dingquan Xiao 等 4 位作者2015-01-01Dalton Transactions

In this work, we simultaneously achieved a giant d33 and a high TC in a lead-free piezoelectric ternary system of (1-x-y)K0.48Na0.52NbO3-xBiFeO3-yBi0.5Na0.5ZrO3 {(1-x-y)KNN-xBF-yBNZ}. Owing to the rhombohedral-orthorhombic-tetragonal (R-O-T) phase coexistence and the enhanced dielectric and ferroelectric properties, t…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Carbon cladded TiO 2 nanotubes: fabrication and use in 3D-RuO 2 based supercapacitors

Zhida Gao、Zhu Xu、Yahang Li 等 6 位作者2015-01-01Chemical Communications

In this work we introduce a facile procedure that allows a highly conformal coating of self-organized TiO2 nanotubes (NTs) with a graphite-like thin carbon layer. This provides a platform to enhance the functionality of TiO2 nanotubes for a wide range of applications. Here we show that such modified nanotubes can serv…

Supercapacitor Materials and FabricationCatalytic Processes in Materials ScienceAerogels and thermal insulation

An efficient multiple healing conductive composite via host–guest inclusion

Dali Zhang、Xin Jü、Luo-Hao Li 等 7 位作者2015-01-01Chemical Communications

A self-healable conductive composite is developed by combining the small molecules and nanotubes through host-guest interactions. This material shows uniform conductivity, microwave absorption and humidity sensing properties, and can be rapidly healed to over 90% electrical and mechanical properties with the aid of wa…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsPolymer composites and self-healing

Chemical sensor development based on poly(o-anisidine)silverized–MWCNT nanocomposites deposited on glassy carbon electrodes for environmental remediation

Mohammed M. Rahman、Anish Khan、Abdullah M. Asiri2015-01-01RSC Advances

POAS–Ag/MWCNT nanocomposites were prepared by an adsorption process. A selective 3-methoxyphenolic sensor was developed by an I – V technique for the first time. It displays the highest sensitivity (∼3.829 μA cm −2 mM −1 ) ever published in the literature.

Conducting polymers and applicationsElectrochemical Analysis and ApplicationsAnalytical Chemistry and Sensors

The enhanced efficiency of graphene–silicon solar cells by electric field doping

Xuegong Yu、Lifei Yang、Qingmin Lv 等 6 位作者2015-01-01Nanoscale

The graphene-silicon (Gr-Si) Schottky junction solar cell has been recognized as one of the most low-cost candidates in photovoltaics due to its simple fabrication process. However, the low Gr-Si Schottky barrier height largely limits the power conversion efficiency of Gr-Si solar cells. Here, we demonstrate that elec…

Carbon Nanotubes in CompositesGraphene research and applicationsNanowire Synthesis and Applications

Silica shelled and block copolymer encapsulated red-emissive AIE nanoparticles with 50% quantum yield for two-photon excited vascular imaging

Junlong Geng、Chi Ching Goh、Wei Qin 等 8 位作者2015-01-01Chemical Communications

A polymer and silica co-protection strategy has been developed to encapsulate organic fluorogens with aggregation-induced emission and charge transfer characteristics into small nanoparticles (NPs). The co-pretected NPs show bright red fluorescence (50% quantum yield) with a large two-photon action cross-section (450…

Nanoplatforms for cancer theranosticsLuminescence and Fluorescent MaterialsNonlinear Optical Materials Studies

A novel carbazole-based gold( i ) complex with interesting solid-state, multistimuli-responsive characteristics

Zhao Chen、Jinhua Liang、Yuting Nie 等 7 位作者2015-01-01Dalton Transactions

A new carbazole-based mononuclear gold(i) complex was designed and synthesized. The novel luminogen shows significative solid-state reversible mechanochromism, dual-responsive thermochromism and sensitive thin-film vapochromism properties. In addition, we obtained two kinds of crystals of the luminogen that may explai…

Porphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent MaterialsPhotochromic and Fluorescence Chemistry

Synthesis of polyethylene glycol-functionalized multi-walled carbon nanotubes with a microwave-assisted approach for improved heat dissipation

Ahmad Amiri、Rad Sadri、Goodarz Ahmadi 等 7 位作者2015-01-01RSC Advances

In order to improve the dispersibility of multi-walled carbon nanotubes (MWCNT) in aqueous media, MWCNT were functionalized with tetrahydrofurfuryl polyethylene glycol (TFPEG) in a one-pot, fast and environmentally friendly method.

Carbon Nanotubes in CompositesThermal properties of materialsNanopore and Nanochannel Transport Studies

The design of underwater superoleophobic Ni/NiO microstructures with tunable oil adhesion

Enshuang Zhang、Zhongjun Cheng、Tong Lv 等 5 位作者2015-01-01Nanoscale

Controlling oil adhesion in water is a fundamental issue in many practical applications for surfaces. Currently, almost all studies on underwater oil adhesion control are concentrated on regulating surface chemistry on polymer surfaces, and structure-dependent underwater oil adhesion is still rare, especially on inorg…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsAdhesion, Friction, and Surface Interactions

Supported and inserted monomeric niobium oxide species on/in silica: a molecular picture

Diana Tranca、Anna Wojtaszek‐Gurdak、Maria Ziółek 等 4 位作者2015-01-01Physical Chemistry Chemical Physics

The geometry, energetic, and spectroscopic properties of molecular structures of silica-supported niobium oxide catalysts are studied using periodic density functional calculations (DFT) and compared with experimental data. The calculations are done for Nb oxide species inserted or grafted in/on an amorphous hydroxyla…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisCatalysis and Oxidation Reactions

Strain-induced semimetal-to-semiconductor transition and indirect-to-direct band gap transition in monolayer 1T-TiS 2

Chengyong Xu、Paul A. Brown、Kevin L. Shuford2015-01-01RSC Advances

We have investigated the effect of uniform plane strain on the electronic properties of monolayer 1T-TiS 2 using first-principles calculations. With the appropriate tensile strain, the material properties can be transformed from a semimetal to a direct band gap semiconductor.

2D Materials and ApplicationsChalcogenide Semiconductor Thin FilmsMXene and MAX Phase Materials

Effect of CaO/SiO2 Ratio on Surface Tension of CaO–SiO2–Al2O3–MgO Melts

Sohei Sukenaga、Tomoyuki Higo、Hiroyuki Shibata 等 5 位作者2015-01-01ISIJ International

The effect of the CaO/SiO2 molar ratio on the surface tension of calcium aluminosilicate melts containing magnesia (CaO–SiO2–Al2O3–MgO) has been explored using a ring method at 1723–1823 K; the Al2O3 and MgO contents were approximately 12 and 8 mol%, respectively. The CaO/SiO2 molar ratio of the samples was varied in…

Advanced ceramic materials synthesisGlass properties and applicationsMagnesium Oxide Properties and Applications

Wurtzite CZTS nanocrystals and phase evolution to kesterite thin film for solar energy harvesting

Uma V. Ghorpade、Mahesh P. Suryawanshi、Seung Wook Shin 等 9 位作者2015-01-01Physical Chemistry Chemical Physics

A quaternary indium- and gallium-free kesterite (KS)-based compound, copper zinc tin sulfide (Cu2ZnSnS4, CZTS), has received significant attention for its potential applications in low cost and sustainable solar cells. It is well known that the reaction time, reactivity of the precursors, and types of capping ligands…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications