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Luminescence, magnetocaloric effect and single-molecule magnet behavior in lanthanide complexes based on a tridentate ligand derived from 8-hydroxyquinoline

Hai-Yun Shen、Wen‐Min Wang、Yan-Xia Bi 等 6 位作者2015-01-01Dalton Transactions

A new family of lanthanide complexes, [Ln2(hfac)4L2] (Ln = Eu (1), Gd (2), Tb (3), Dy (4), Ho (5), Er (6), Lu (7); hfac = hexafluoroacetylacetonate, HL = 2-(2′-benzothiazole)-8-hydroxyquinoline), was synthesized and characterized using single-crystal X-ray diffraction, elemental analysis (EA), thermal gravimetric anal…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Design and synthesis of 3D hierarchical NiCo 2 S 4 @MnO 2 core–shell nanosheet arrays for high-performance pseudocapacitors

Kaibing Xu、Qilong Ren、Qian Liu 等 6 位作者2015-01-01RSC Advances

3D hierarchical NiCo 2 S 4 @MnO 2 hybrid materials have been successfully prepared for high-performance pseudocapacitors, which show outstanding electrochemical performance in supercapacitors such as high areal capacitance and good cyclic stability.

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced battery technologies research

Doped quantum dot@silica nanocomposites for white light-emitting diodes

Bingxia Zhao、Yulian Yao、Mengyu Gao 等 6 位作者2015-01-01Nanoscale

This work reports the use of a near-UV-LED chip in combination with blue, green-yellow and red emitting doped ZnSe QD@silica nanocomposites to construct a novel WLED with reduced scattering and no reabsorption. Blue, green-yellow and red emitting Cu or Mn doped ZnSe QDs with enlarged Stokes shifts and similar absorpti…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

MoSe2 porous microspheres comprising monolayer flakes with high electrocatalytic activity

Ye-jun、Zhang、Qiufang 等 11 位作者2015-01-01纳米研究:英文版

2 microspheres 展览为 electrocatalytic 氢进化反应的显著活动和耐久性她在酸,维持 77 mV 的小发作过电位并且为 5 妈/厘米的当前的密度保留 100 mV 的小过电位在 1,000 以后的 2 骑车。另外,类似的 3D WSe 2 microspheres 能被使用这个方法也准备。我们期望这条灵巧的胶体的线路能进一步被扩展综合将在域例如里发现应用的另外的多孔的结构在精力存储,催化作用,并且察觉到。

Electrocatalysts for Energy ConversionAdvanced Photocatalysis Techniques2D Materials and Applications

A double supramolecular crosslinked polymer gel exhibiting macroscale expansion and contraction behavior and multistimuli responsiveness

Xiaofan Ji、Kecheng Jie、Steven C. Zimmerman 等 4 位作者2015-01-01Polymer Chemistry

Here we report a novel supramolecular polymer gel containing two types of physical crosslinks that are orthogonal to each other. It shows macroscale expansion and contraction behavior and multistimuli responsiveness.

Hydrogels: synthesis, properties, applicationsPolymer composites and self-healingSupramolecular Self-Assembly in Materials

Controlled Texturing of Aluminum Sheet for Solar Energy Applications

C. O. Ayieko、Robinson Musembi、Alex Ogacho 等 6 位作者2015-01-01Advances in Materials Physics and Chemistry

Aluminum sheets were polished to reduce ruggedness and then textured in varying acid-ethanol concentration etchant to form pores. The textured surface was characterized structurally by using X-ray diffraction (XRD) which revealed aluminum crystallographic planes (1 1 1), (2 0 0), (2 2 0) and (3 1 1). Its morphology wa…

Surface Modification and SuperhydrophobicityAdvanced Surface Polishing TechniquesFiber-reinforced polymer composites

Temperature-dependent studies of [(CH 3 ) 2 NH 2 ][Fe III M II (HCOO) 6 ] frameworks (M II = Fe and Mg): structural, magnetic, dielectric and phonon properties

Aneta Ciupa、Mirosław Mączka、Anna Gągor 等 7 位作者2015-01-01Dalton Transactions

Novel heterometallic formate [(CH3)2NH2][Fe(III)Mg(II)(HCOO)6] (DMFeMg) was prepared and characterized by single crystal X-ray diffraction, DSC, dielectric, magnetic susceptibility, Raman and IR methods. We also report thermal, Raman and IR studies of the known compound [(CH3)2NH2][Fe(III)Fe(II)(HCOO)6] (DMFeFe). DMFe…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesCrystal Structures and Properties

Masking agent-free and channel-switch-mode simultaneous sensing of Fe 3+ and Hg 2+ using dual-excitation graphene quantum dots

Fengzhou Xu、Hui Shi、Xiaoxiao He 等 10 位作者2015-01-01The Analyst

A novel channel-switch-mode strategy for simultaneous sensing of Fe(3+) and Hg(2+) is developed with dual-excitation single-emission graphene quantum dots (GQDs). By utilizing the dual-channel fluorescence response performance of GQDs, this strategy achieved a facile, low-cost, masking agent-free, quantitative and sel…

Advanced biosensing and bioanalysis techniquesMolecular Sensors and Ion DetectionCarbon and Quantum Dots Applications

A facile method to prepare highly compressible three-dimensional graphene-only sponge

Jinhui Li、Songfang Zhao、Guoping Zhang 等 7 位作者2015-01-01Journal of Materials Chemistry A

Highly compressible three-dimensional graphene-only sponges (CGSs) were prepared through a facile method. The CGSs show ultralow density, high porosity, great compressibility and excellent stability which make them great candidates for pressure-responsive sensors, elastic conductors and other applications.

Graphene research and applicationsAdvanced Sensor and Energy Harvesting MaterialsGraphene and Nanomaterials Applications

Novel photochromic infinite coordination polymer particles derived from a diarylethene photoswitch

Xiao Guang Hu、Xiaoliang Li、Sung Ik Yang2015-01-01Chemical Communications

A novel infinite coordination polymer (DAE-ICP) based on zinc nitrite and a diarylethene photoswitch, with reversible photochromic properties in solution and the solid state upon applying photostimuli, was synthesized and characterized by FT-IR, EDX, FE-SEM and FE-TEM.

Metal-Organic Frameworks: Synthesis and ApplicationsNanoplatforms for cancer theranosticsPhotochromic and Fluorescence Chemistry

Three-dimensionally ordered macroporous spinel-type MCr 2 O 4 (M = Co, Ni, Zn, Mn) catalysts with highly enhanced catalytic performance for soot combustion

Jinguo Wang、Gaoyang Yang、Li Cheng 等 5 位作者2015-01-01Catalysis Science & Technology

MCr 2 O 4 catalysts with three-dimensional ordered macroporous structures displayed superior catalytic activity for soot combustion to their bulk counterparts.

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsNanomaterials for catalytic reactions

Extraction, Addition and Characterization of Hemicelluloses from Corn Cobs to Development of Paper Properties

Ana Carolina da Silva、Rubens Chaves de Oliveira、Armando da Silva Neto 等 5 位作者2015-01-01Procedia Materials Science

The corncob is a product found in significant amounts in the residues of agriculture, which has potential for use underexplored. This paper presents a study of the chemical characterization of corn cobs, extraction and application of hemicelluloses present in these wastes. Two fractions of hemicelluloses were obtained…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research StudiesLignin and Wood Chemistry

Repeated self-healing of nano and micro scale cracks in epoxy based composites by tri-axial electrospun fibers including different healing agents

Jamal Seyyed Monfared Zanjani、Burcu Saner Okan、Ilse Letofsky‐Papst 等 5 位作者2015-01-01RSC Advances

Multi-walled healing fibers with a novel architecture are fabricated through a direct, one-step tri-axial electrospinning process to encapsulate different healing agents inside the fibers with two distinct protective walls.

Electrospun Nanofibers in Biomedical ApplicationsPolymer composites and self-healingPolydiacetylene-based materials and applications

A single multifunctional nanoplatform based on upconversion luminescence and gold nanorods

Yue Huang、Federico Rosei、Fiorenzo Vetrone2015-01-01Nanoscale

Lanthanide-doped upconverting nanoparticles (UCNPs), which convert near-infrared (NIR) light to higher energy light have been intensively studied for theranostic applications. Here, we developed a hybrid core/shell nanocomposite with multifunctional properties using a multistep strategy consisting of a gold nanorod (G…

Luminescence Properties of Advanced MaterialsNanoplatforms for cancer theranosticsLuminescence and Fluorescent Materials

Biointerfacing polymeric microcapsules for in vivo near-infrared light-triggered drug release

Jingxin Shao、Mingjun Xuan、Tieyan Si 等 5 位作者2015-01-01Nanoscale

Seeking safe and effective water-soluble drug carriers is of great significance in nanomedicine. To achieve this goal, we present a novel drug delivery system based on biointerfacing hollow polymeric microcapsules for effectively encapsulating water-soluble antitumor drug and gold nanorod (GNR) functionalization for t…

Nanoparticle-Based Drug DeliveryElectrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction Studies

Synthesis of an acid-labile polymeric prodrug DOX-acetal-PEG-acetal-DOX with high drug loading content for pH-triggered intracellular drug release

Hairong Wang、Jinlin He、Dongling Cao 等 7 位作者2015-01-01Polymer Chemistry

PEGylated doxorubicin (DOX) prodrugs with high drug loading content have been prepared via a combination of CuAAC “click” reaction and ammonolysis reaction, which can be used for pH-triggered delivery of doxorubicin.

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsDendrimers and Hyperbranched Polymers

Speciation of metal-based nanomaterials in human serum characterized by capillary electrophoresis coupled to ICP-MS: a case study of gold nanoparticles

Magdalena Matczuk、Karolina Anecka、Federica Scaletti 等 7 位作者2015-01-01Metallomics

The development and optimization of a versatile analytical system for the speciation analysis of metal-containing nanoscale materials in blood serum is reported herein. Based on capillary electrophoresis (CE) interfaced with inductively coupled plasma mass spectrometry (ICP-MS), the method was shown to be feasible to…

Nanoparticles: synthesis and applicationsRadiation Therapy and DosimetryIon-surface interactions and analysis