Materials Literature
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Planar microscale ionization devices that operate in atmospheric air have been developed out of highly graphitic polycrystalline diamond (HGPD). The devices have been fabricated on both silicon and quartz substrates with electrode gaps ranging from 5 to 20 µm. Experiments show that the HGPD devices operate in the pre-…
We demonstrate an intriguing liquid crystal display (LCD) mode that comprises an optically isotropic LC composite incorporating in-plane electric field geometry. No surface treatment, such as rubbing, is required to fabricate the LCD mode because it is based on an isotropic state. The measured response time is of subm…
To study the phase stability and the phase transformation behavior in the nanocrystalline (NC) stoichiometric alloys, a thermodynamic model has been developed in the present paper. Using the NC Sm–Co alloy as an example, the thermodynamic properties of various phases in the alloy system were evaluated systematically.…
In this paper, the contribution of the domain walls motion to the dielectric and piezoelectric responses for the 0.65Pb(Mg1/3Nb2/3)O-3-0.35PbTiO(3) system is investigated. A monotonically increasing temperature dependence of the dielectric permittivity is observed from very low temperatures up to the ferroelectric-par…
Fullerenelike hydrogenated carbon films were produced by pulse bias-assisted rf inductively coupled plasma enhanced chemical vapor deposition (ICPECVD). The effects of pulse duty cycle on the microstructure and mechanical properties of the resultant films were investigated by means of high resolution transmission elec…
Laboratory experiments, modeling the methylation of inorganic Sn(II) by methylcobalamin and the decomposition of methyltin under irradiation with UV light in aqueous solution, have been performed. Methyltin has been separated from inorganic Sn using anion-exchange chromatography and subjected to Sn isotope ratio measu…
The pressure evolution of the local structure and dynamics of polar nanoregions in PbSc(0.5)Nb(0.5)O(3) relaxor ferroelectric is analysed by Raman spectroscopy. The pressure dependence of phonon modes up to 10 GPa reveals three characteristic pressures related to changes in the local structure: near 2 GPa, at which fe…
A theory of nuclear magnetic resonance (NMR) in graphene is presented. The canonical form of the electron-nucleus hyperfine interaction is strongly modified by the linear electronic dispersion. The NMR shift and spin-lattice relaxation time are calculated as a function of temperature, chemical potential, and magnetic…
One-dimensional MgZnO nanostructures were grown directly on p-Si substrates by thermal evaporation at a variety of synthesis temperatures. Transmission electron microscopy and energy dispersive x-ray spectroscopy analysis revealed the formation of slim ZnO nanowires with twin boundaries on low Mg content nanosheets at…
Abstract The inhibitive effect of some amino acids, glycine (Gly), alanine (Ala), valine (Val), leucine (Leu), isoleucine (Ile), serine (Ser), threonine (Thr), methionine (Met), phenylalanine (Phe), tyrosine (Tyr), trytophan (Try), aspartic acid (Asp), asparagine (Asn), glutamic acid (Glu), and lysine (Lys) against th…
During poling and application in actuators, piezoelectric ceramics like lead-zirconate-titanate are exposed to static or cyclically varying electric fields, often leading to pronounced changes in the electromechanical properties. These fatigue phenomena depend on time, peak electric load, and temperature. Although thi…
Spectroscopic properties of Er3+/Yb3+ codoped barium gallogermanate glass demonstrate that an efficient energy transfer from Yb3+ to Er3+ ions occurs while the back energy transfer from Er3+ to Yb3+ ions cannot be ignored. Based on the rate equations of electron transitions, the forward energy transfer Yb3+(F25/2)+Er3…
Electrospun polyacrylonitrile (PAN) fiber precursor-based carbon nanofiber (CNF) mats were produced and impregnated with epoxy resin. The mechanical properties of as-prepared nanofibers in the mat and short fiber filled epoxy nanocomposite forms were determined to demonstrate the effect of fiber aspect ratio on those…
BACKGROUND: Targeted magnetic resonance contrast agents have enabled the imaging of biological processes in vivo, and current insights have opened up new perspectives for the monitoring and diagnosis of many diseases. PURPOSE: To develop a contrast agent for targeting somatostatin receptors (SSTRs) expressed on breast…
This paper deals with the analysis of nanoparticles polymerized in nitrogen/acetylene and argon/acetylene gas mixtures in low temperature rf discharges. The polymerization process was monitored by means of mass spectroscopy. The chemical characteristics of the material were obtained in situ by infrared absorption spec…
Abstract The corrosion and electrochemical behaviors of pure aluminum in KOH‐ionic liquid‐water solutions with variable volume ratios of water and the ionic liquid 1‐butyl‐3‐methyl imidazolium tetrafluoroborate (BMIMBF 4 ) were for the first time investigated by means of hydrogen collection, polarization curve, galvan…
Rare earth doped opaque aluminum tellurite ceramics exhibiting multicolor upconversion and color tunability have been synthesized and characterized. The multicolor fluorescence comprises of green, red, and blue upconversion emissions from Ho3+ and Tm3+ ions. By varying the intensity ratios between the upconversion emi…
Materials based on rare-earth and iron have drawn much attention due to their high performance properties for permanent magnet application. Substitution of Fe by a transition metal remains of considerable interest owing to the relatively modest magnetic properties of the binary Sm–Fe compounds. The structure of the na…
Abstract [C 4 mim][Tb(hfacac) 4 ] ( 1 ) and [C 4 mpyr][Tb(hfacac) 4 ] ( 2 ) (C 4 mim = 1‐butyl‐3‐methylimidazolium, C 4 mpyr = N ‐butyl‐ N ‐methylpyrrolidinium) were obtained by reacting [C 4 mim]Cl (for 1 ) or [C 4 mpyr]Br (for 2 ) with (hexafluoroacetyl)acetone and terbium(III) chloride in a basic ethanol/water solu…
The electronic thermal transport in metallic nanofilms has been extensively studied. There are, however, rare reports on the influence of phonon on the thermal and electrical transports in metallic films. In the present work, equilibrium molecular dynamics with embedded-atom method is used to investigate the lattice t…