Materials Literature
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Porous ZnO nanowires were obtained in an inexpensive and simple way by thermally oxidizing ZnSe nanowires in air. The morphologies of the precursor and resulted nanowires are almost identical. X-ray diffraction and energy-dispersive X-ray spectroscopy reveal that the zinc blende ZnSe nanowires were transformed into wu…
A new end-on azide-bridged dimeric Mn(III) complex has been synthesized by using the tridentate N-isonicotinamidosalicylaidimine ligand. Magnetic studies show that the complex has a high-spin ground state of S = 4 and is ac out-of-phase frequency-dependent.
Binding of clusters of gold atoms (Au) with the guanine-cytosine (GC) and adenine-thymine (AT) Watson-Crick DNA base pairs was studied using the density functional theory (DFT). Geometries of the neutral GC-Au(n) and AT-Au(n) and the corresponding anionic (GC-Au(n))(-1) and (AT-Au(n))(-1) (n = 4, 8) complexes were ful…
A simple hydrothermal method has been developed for the one-step synthesis of copper-core/carbon-sheath nanocables in solution. The obtained nanostructures were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), and high-resolution TEM (HRTEM), Raman, and UV-vis spectrum analysis. These…
Different ways to reduce hysteresis in a capacitive-type thermally carbonized porous silicon (TC-PS) humidity sensor are studied and compared. Modification of the contact angle of the dielectric surface, enlargement of the pore size of dielectric, and operating the sensor at elevated temperature proved all to be possi…
Reactive uptake coefficients for nitric acid onto size-selected (d(ve) = 102 and 233 nm) sodium chloride aerosols are determined for relative humidities (RH) between 85% and 10%. Both pure sodium chloride and sodium chloride mixed with magnesium chloride (X(Mg/Na) = 0.114, typical of sea salt) are studied. The aerosol…
The effect of chain architecture on the morphological and tensile properties of series of multigraft copolymers, with regularly spaced tri-, tetra-, and hexafunctional junction points, was investigated using transmission electron microscopy (TEM), small-angle X-ray scattering (SAXS), and tensile testing. The materials…
Twisted nematic liquid crystal displays (TN-LCDs), doped with the nanoparticles of metal, such as Pd, Ag, or Ag-Pd, which are protected with ligand molecules, such as nematic liquid crystal, exhibit a frequency modulation (FM) electro-optical (EO) response with short response time of milliseconds (ms) or sub-ms order…
A series of well-defined second (G-2) and third (G-3) generation dendritic polybutadienes (PBd) were synthesized by the coupling of the living G-2 and G-3 dendrons with methyltrichlorosilane, using anionic polymerization high-vacuum techniques. The synthetic approach of the living G-2 dendrons involves (a) the synthes…
Scientists, risk practitioners, and regulators have debated the need to be proactive in assessing the potential health and environmental risks and benefits of unregulated nano-scale technologies. Many nanotech-based products and applications are already in use or development. Application of a proactive risk-based appr…
We study the resonance behavior of the unusual Raman feature known as the coalescence-inducing mode (CIM), observed at $\ensuremath{\sim}1850\phantom{\rule{0.3em}{0ex}}{\mathrm{cm}}^{\ensuremath{-}1}$, in samples of double-wall carbon nanotubes annealed at high temperatures. Resonance Raman spectra taken with differen…
Treatment of malignant gliomas represents one of the most formidable challenges in oncology. The combination of surgery, radiation, and chemotherapy yields median survivals of less than one year. Here we demonstrate the use of a minimally invasive surgical technique, convection-enhanced delivery (CED), for local admin…
Superhydrophobic surfaces of n-hexatriacontane were fabricated in a single-step process. The low surface energy of n-hexatriacontane together with the randomly distributed micro- and nanoscale roughness features guarantees very large contact angles and a small roll-off angle for water drops. The advantage of n-hexatri…
We fabricated reproducible high transparency superconducting contacts consisting of superconducting Ti/Al/Ti trilayers to gated single-wall carbon nanotubes. The reported semiconducting single-wall carbon nanotubes have normal state differential conductance up to 3e2/h and exhibit clear Fabry-Perot interference patter…
This paper proposes a 10-kW power conditioning system for a 5-kW solid oxide fuel cells (SOFCs) low-voltage battery hybrid power generation that has been developed for participation in the 2003 Future Energy Challenge Competition organized by the U.S. Department of Energy and the IEEE. The objective of the competition…
We demonstrate the design, fabrication, and characterization of single-mode low-loss waveguides for mid-infrared (MIR) wavelengths. Planar waveguide structures were fabricated from multilayer thin films of arsenic-based chalcogenide glasses followed by the creation of channel waveguides by using the photodarkening eff…
Characterization is a central aspect of catalyst development [1,2]. The elucidation of the structures, compositions, and chemical properties of both the solids used in heterogeneous catalysis and the adsorbates and intermediates present on the surfaces of the catalysts during reaction is vital for a better understandi…
The present review covers the production of new materials under high pressures. A primary limitation on the use of pressures higher than 1 GPa is a small volume and mass of a produced material. Therefore, despite an extremely wide range of new high-pressure synthesized substances with unique properties, synthesis on a…
In the impact ionization process, a hot carrier relaxes by generating an exciton. We present tight binding calculations showing that the rate of this process in PbSe nanocrystals has a strong energy dependence and that the relaxation energy increases linearly with the carrier excess energy. The impact ionization can b…
Dynamic fracture in a wide class of materials reveals "fracture energy" $Γ$ much larger than the expected nominal surface energy due to the formation of two fresh surfaces. Moreover, the fracture energy depends on the crack velocity, $Γ=Γ(v)$. We show that a simple dynamical theory of visco-plasticity coupled to asymp…