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Highly emissive organic solids with remarkably broad color tunability based on N,C-chelate, four-coordinate organoborons

Aslam C. Shaikh、Dnyanesh S. Ranade、Shridhar H. Thorat 等 8 位作者2015-01-01Chemical Communications

Molecular fluorophores based on N,C-chelate, four-coordinate organoborons exhibit tunable solid-state emission colors that cover the whole visible region from blue to red. The emission color can be tuned through the substituents on either quinolines or the boron center.

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsOrganoboron and organosilicon chemistry

Electro-deposition of CoNi 2 S 4 flower-like nanosheets on 3D hierarchically porous nickel skeletons with high electrochemical capacitive performance

Tao Wang、Bo Zhao、Hong Jiang 等 9 位作者2015-01-01Journal of Materials Chemistry A

Electro-deposited CoNi 2 S 4 nanosheets on 3D hierarchically porous nickel skeletons demonstrate excellent electrochemical capacitive performance.

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Nitrogen-rich conjugated microporous polymers: impact of building blocks on porosity and gas adsorption

Xiaoyan Wang、Yang Zhao、Lingling Wei 等 5 位作者2015-01-01Journal of Materials Chemistry A

A series of nitrogen-rich conjugated microporous polymers has been designed and synthesized. The polymers produced from the rigid building block show an increased specific surface area up to 1146 m 2 g −1 with a remarkable CO 2 uptake of 3.72 mmol g −1 at 1.13 bar and 273 K.

Metal-Organic Frameworks: Synthesis and ApplicationsCarbon Dioxide Capture TechnologiesCovalent Organic Framework Applications

Tuning thermal contact conductance at graphene–copper interface via surface nanoengineering

Yang Hong、Lei Li、Xiao Cheng Zeng 等 4 位作者2015-01-01Nanoscale

Due to rapidly increasing power densities in nanoelectronics, efficient heat removal has become one of the most critical issues in thermal management and nanocircuit design. In this study, we report a surface nanoengineering design that can reduce the interfacial thermal resistance between graphene and copper substrat…

Graphene research and applicationsAdvanced Thermoelectric Materials and DevicesThermal properties of materials

Nano- and micro-sized rare-earth carbonates and their use as precursors and sacrificial templates for the synthesis of new innovative materials

Anna M. Kaczmarek、Kristof Van Hecke、Rik Van Deun2015-01-01Chemical Society Reviews

This review focuses on rare-earth carbonate materials of nano- and micro-size. It discusses in depth the different types of rare-earth carbonate compounds, diverse synthetic approaches and possibilities for chemical tuning of the size, shape and morphology. The interesting luminescence properties of lanthanide doped r…

Bone Tissue Engineering MaterialsLuminescence Properties of Advanced MaterialsRadioactive element chemistry and processing

Field-induced slow magnetic relaxation of octahedrally coordinated mononuclear Fe( iii )-, Co( ii )-, and Mn( iii )-containing polyoxometalates

Rinta Sato、Kosuke Suzuki、Takuo Minato 等 6 位作者2015-01-01Chemical Communications

Herein, we report for the first time polyoxometalate (POM)-based single-molecule magnets with mononuclear transition metal cores. The mononuclear Fe(III)-, Co(II)-, and Mn(III)-containing POMs have successfully been synthesized from a trivacant lacunary Keggin-type silicotungstate precursor TBA4H6[A-α-SiW9O34]·2H2O (T…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesPolyoxometalates: Synthesis and Applications

Surface bioengineering of diatomite based nanovectors for efficient intracellular uptake and drug delivery

Monica Terracciano、Mohammad‐Ali Shahbazi、Alexandra Correia 等 7 位作者2015-01-01Nanoscale

Diatomite is a natural porous silica material of sedimentary origin. Due to its peculiar properties, it can be considered as a valid surrogate of synthetic porous silica for nano-based drug delivery. In this work, we exploit the potential of diatomite nanoparticles (DNPs) for drug delivery with the aim of developing a…

Bone Tissue Engineering MaterialsPolymer Surface Interaction StudiesDiatoms and Algae Research

Environmentally benign synthesis of saturated and unsaturated aliphatic polyesters via enzymatic polymerization of biobased monomers derived from renewable resources

Yi Jiang、Albert J. J. Woortman、Gert O. R. Alberda van Ekenstein 等 4 位作者2015-01-01Polymer Chemistry

Biobased saturated aliphatic polyesters and photo-curable unsaturated aliphatic polyesters are enzymatically polymerized, and their structure–property relationships are systematically studied.

biodegradable polymer synthesis and propertiesCatalysis for Biomass ConversionCarbon dioxide utilization in catalysis

Platinum nanoparticles/graphene-oxide hybrid with excellent peroxidase-like activity and its application for cysteine detection

Xiaoqing Lin、Hao‐Hua Deng、Gang-Wei Wu 等 8 位作者2015-01-01The Analyst

A facile approach is proposed for the growth of platinum nanoparticles on graphene oxide (PtNPs/GO). The resulting PtNPs/GO hybrid has been proved to function as peroxidase mimics that can catalyze the oxidation of peroxidase substrates in the presence of hydrogen peroxide (H2O2). Kinetic studies indicate that the PtN…

Advanced biosensing and bioanalysis techniquesElectrochemical sensors and biosensorsAdvanced Nanomaterials in Catalysis

Plasmonic multi-shell nanomatryoshka particles as highly tunable SERS tags with built-in reporters

Li Lin、Hongchen Gu、Jian Ye2015-01-01Chemical Communications

Here we report on the synthesis and averaged SERS measurements of multi-shell nanomatryoshka SERS tags. By tuning the number of shells or by changing the Raman reporters in different gap layers, their Raman intensities and spectral bands were tunable. These tags show great potential for SERS-based biosensing and bioim…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesSpectroscopy Techniques in Biomedical and Chemical Research

Single-composition white-emitting NaSrBO 3 :Ce 3+ ,Sm 3+ ,Tb 3+ phosphors for NUV light-emitting diodes

Ming Xin、Datao Tu、Haomiao Zhu 等 9 位作者2015-01-01Journal of Materials Chemistry C

Highly efficient single-composition white-emitting phosphors based on NaSrBO 3 :Ce 3+ ,Sm 3+ ,Tb 3+ have been developed for the fabrication of near-UV excited white LEDs with a high color rendering index.

Advanced Photocatalysis TechniquesLuminescence Properties of Advanced MaterialsPerovskite Materials and Applications

The role of SBA-15 in drug delivery

Vaezeh Fathi Vavsari、Ghodsi Mohammadi Ziarani、Alireza Badiei2015-01-01RSC Advances

In this review, preparation, characterization and application of various types of SBA-15 as drug delivery agents is investigated.

Nanoparticle-Based Drug DeliveryMesoporous Materials and CatalysisSupramolecular Self-Assembly in Materials

Potential of PVA-doped bacterial nano-cellulose tubular composites for artificial blood vessels

Jingyu Tang、Luhan Bao、Xue Li 等 5 位作者2015-01-01Journal of Materials Chemistry B

Bacterial nano-cellulose (BNC) hydrogel has been suggested as a promising biomaterial for artificial blood vessels. However, some properties of BNC do not achieve all of the requirements of a native blood vessel - compliance, for instance. In order to improve the properties of BNC tubes, poly(vinyl alcohol) (PVA) was…

Advanced Cellulose Research StudiesElectrospun Nanofibers in Biomedical ApplicationsElectrohydrodynamics and Fluid Dynamics