Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
It is very important to know the morphology and chemical properties of subscales of oxide layers on surface for controlling and understanding high temperature oxidation in electrical steel. In present work, the oxide layers were investigated by various methods of transmission electron microscopy (TEM) such as scanning…
The aim of this study was to assess the influence of different types of carbon nanotubes (CNTs) on cell phagocytosis. Three kinds of carbon nanotubes: single-walled carbon nanohorns (SWCNHs), multiwalled carbon nanotubes (MWCNTs), and ultra-long single-walled carbon nanotubes (ULSWCNTs) before and after additional che…
Cationic Mn(III) N-alkylpyridylporphyrins (MnPs) are potent SOD mimics and peroxynitrite scavengers and diminish oxidative stress in a variety of animal models of central nervous system (CNS) injuries, cancer, radiation, diabetes, etc. Recently, properties other than antioxidant potency, such as lipophilicity, size, s…
The search from time immemorial for stronger, lighter and more durable materials used in construction and tools continues to this day. This urge to discover, invent and synthesize new materials has resulted in innumerable kinds of alloys, plastics and composites owing to the very exacting demands from different indust…
One of the most commonly used plastics in electrical cables is flexible PVC, which includes 30-40 wt. % combustible plasticizers. In this work, the effects of the modelling decisions and parameter estimation methods on the pyrolysis modelling of two PVC cables were studied. The kinetic and thermal parameters were esti…
This paper presents the catalytic role of the gadolinia-doped ceria (GDC) and its surface grain boundaries in enhancing the oxygen incorporation kinetics of low-temperature solid oxide fuel cells (LT-SOFC). Epitaxial and polycrystalline GDC thin films were grown by pulsed laser deposition (PLD) on the cathode side of…
Spatially confined semiconductors form an exciting type of material with potential for numerous applications, many of which rely on the material's optical properties and excitation dynamics. For successful realization of the applications a detailed analysis of excitations in these materials is needed, extending beyond…
A series of rigid Pt(II) diimine diacetylide complexes and their corresponding metallocyclic derivatives were synthesized through coordination-driven self-assembly. The photophysical properties of these complexes have been studied in detail, revealing exceptionally high RT phosphorescence quantum yields and lifetimes…
Overcoming the structural instability of a single-phase thin-film-processed cathode by replacing it with a cathode-electrolyte composite thin-film cathode is presented. The effect of the deposition materials change from a single-phase lanthanum strontium cobaltite (LSC) to a LSC-gadolinia-doped ceria (GDC) composite a…
The Layer-by-Layer fabrication of polyelectrolyte capsules with and without Au nanoparticles embedded into their walls is reported. We have studied the behaviour of these capsules under microwave irradiation. Their properties have been investigated by transmission electron microscopy and dynamic light scattering measu…
Three enantiopure isostructural sandwich-type clusters, Ln(III)(3)Mn(III)(6) (Ln = Dy (1), Tb (2) and Gd (3)) have been synthesized through reactions of a chiral Schiff-base ligand ((S,E)-4-(2-hydroxybenzylideneamino)-2-hydroxybutanoic acid, H(3)L) with manganese and lanthanide ions, showing intramolecular antiferroma…
Palladium (Pd) nanostructures with urchin-like, hemispherical, flower-like, and plate-like morphologies were controllably deposited on silicon substrates in aqueous hydrogen fluoride (HF) solution at room temperature. The morphology of the Pd nanostructures changed from urchin-like to hemispherical and flowerlike in t…
In this work we studied the possibility to achieve a hybrid-surface through the modification, via a facile wet chemical process, of the surface of films of poly(ethylene-co-acrylic acid) (EAA) with amino-modified silica nanoparticles. Films of EAA were preliminarily activated by the introduction of –COCl groups on the…
Ten novel inorganic–organic hybrid polyoxometalates, namely, [1,3-bis(pyridinium) propane]2[α-Mo8O26] (1), [1,4-bis(pyridinium)butane]2[1D-Mo8O26] (2), [1,5-bis(pyridinium)pentane]2[θ-Mo8O26] (3), [1,6-bis(pyridinium)hexane]2[1D-Mo8O26] (4), [1,7-bis(pyridinium)heptane]2[β-Mo8O26] (5), [1,8-bis(pyridinium)octane]2[θ-M…
We report a new application of gold nanoparticles for visual detection of copper ions with high sensitivity and selectivity based on the colorimetric difference due to the strong and specific inhibition of Cu(NH3)62+ to the corrosion of gold nanoparticles at low concentration.
This study reports the size-controlled synthesis of truncated octahedral Fe3−δO4 nanoparticles varying from 5 to 22 nm in edge length. Size-dependent XRD spectra show that the iron oxide gradually shifted from magnetite toward maghemite as the size decreased. The nonstoichiometric Fe3−δO4 was expressed the resulting i…
Biodegradable magnesium-calcium (MgCa) alloy is a very attractive orthopedic biomaterial compared to permanent metallic alloys. However, the critical issue is that MgCa alloy corrodes too fast in the human organism. It is expected that surface integrity of an MgCa implant has significant impact on the corrosion perfor…
In this work we have studied the structure of silver(I) thiolate oligomers that lead to the formation of argentophilic hydrogels. The results showed two different and clearly distinguishable systems, depending on the neutral or acidic character of the thiol. Neutral systems gave opaque hydrogels, showed a fibrilar mic…
As an alternative to the partial oxidation of methane to synthesis gas followed by methanol synthesis and the subsequent generation of olefins, we have studied the production of light olefins (ethylene and propylene) from the reaction of methyl bromide over various modified microporous silico-aluminophosphate molecula…
Acid-base bifunctional activity governed by -NH(2) group's microenvironment is evident from two different catalysts scrutinized by interchanging the location of -SO(3)H/NH(2) groups on periodic mesoporous ethylenesilica. The hydrophobic local environment plays a significant role in one-pot deacetalization/nitroaldol c…