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Fabrication of flexible reduced graphene oxide–TiO 2 freestanding films for supercapacitor application

Jinsu Kim、Wai-Hwa Khoh、Boon‐Hong Wee 等 4 位作者2015-01-01RSC Advances

A rGO/TiO 2 free standing film has been fabricated via a simple and facile vacuum filtration system. The composite electrode showed improved electrochemical properties compared to the pure rGO due to the highly expanded layer-structure.

Advancements in Battery MaterialsGraphene research and applicationsSupercapacitor Materials and Fabrication

A triazine-based porous organic polymer: a novel heterogeneous basic organocatalyst for facile one-pot synthesis of 2-amino-4H-chromenes

S. Kundu、Asim Bhaumik2015-01-01RSC Advances

A new triazine-based porous organic polymer has been synthesized through the polycondensation of cyanuric chloride and tris(2-aminoethyl)amine and it is employed as a basic organocatalyst for one-pot three-component coupling reaction.

Metal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsSynthesis and Characterization of Heterocyclic Compounds

Electrospun manganese–cobalt oxide hollow nanofibres synthesized via combustion reactions and their lithium storage performance

Soo Min Hwang、So Yeun Kim、Jae Geun Kim 等 12 位作者2015-01-01Nanoscale

Mesoporous hollow fibres of MnCo2O4 and CoMn2O4 were synthesized by electrospinning and highly exothermic oxygen-mediated combustion reactions during calcination, in which the heating rate affected the final fibre morphology (e.g., single- or double-shell). The anodes consisting of hollow fibres showed excellent elect…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationTransition Metal Oxide Nanomaterials

Varying the ionic functionalities of conjugated polyelectrolytes leads to both p- and n-type carbon nanotube composites for flexible thermoelectrics

Cheng‐Kang Mai、Boris Russ、Stephanie L. Fronk 等 9 位作者2015-01-01Energy & Environmental Science

Selective doping of single-walled carbon nanotubes can be achieved by varying pendant ionic functionalities of conjugated polyelectrolytes.

Advanced Battery Materials and TechnologiesAdvanced Thermoelectric Materials and DevicesConducting polymers and applications

Little do more: a highly effective Pt 1 /FeO x single-atom catalyst for the reduction of NO by H 2

Jian Lin、Botao Qiao、Ning Li 等 8 位作者2015-01-01Chemical Communications

A FeOx supported Pt single-atom catalyst (Pt-SAC) exhibited much higher NO conversion and selectivity to N2 than the supported Pt nanocatalyst (Pt-Nano). This better performance was attributed to not only the stronger NO adsorption and easier dissociation of the N-O bond but also the presence of more oxygen vacancies…

Catalytic Processes in Materials ScienceAmmonia Synthesis and Nitrogen ReductionNanomaterials for catalytic reactions

Mechanofluorochromic properties of β-iminoenolate boron complexes tuned by the electronic effects of terminal phenothiazine and phenothiazine-S,S-dioxide

Zhenqi Zhang、Zhu Wu、Jingbo Sun 等 7 位作者2015-01-01Journal of Materials Chemistry C

β-Iminoenolate boron complexes bearing phenothiazine exhibited high-contrast mechanofluorochromic behavior compared with that containing a phenothiazine- S , S -dioxide unit.

Organic Light-Emitting Diodes ResearchPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

Polypyrrole–polyoxometalate/reduced graphene oxide ternary nanohybrids for flexible, all-solid-state supercapacitors

Yuyun Chen、Min Han、Yujia Tang 等 7 位作者2015-01-01Chemical Communications

Novel polypyrrole-polyoxometalate/reduced graphene oxide ternary nanohybrids (TNHs) are synthesized via a one-pot redox relay strategy. The TNHs exhibit high areal specific capacitance (2.61 mF cm(-2)), and the fabricated solid device also exhibits good rate capability, excellent flexibility and mechanical stability.

Supercapacitor Materials and Fabricationbiodegradable polymer synthesis and propertiesPolyoxometalates: Synthesis and Applications

Plasma-grown graphene petals templating Ni–Co–Mn hydroxide nanoneedles for high-rate and long-cycle-life pseudocapacitive electrodes

Guoping Xiong、Pingge He、Lei Liu 等 5 位作者2015-01-01Journal of Materials Chemistry A

Ni–Co–Mn triple hydroxide (NCMTH) nanoneedles were coated on plasma-grown graphitic petals (GPs) by a facile one-step hydrothermal method for high-rate and long-cycle-life pseudocapacitive electrodes.

Advancements in Battery MaterialsSupercapacitor Materials and FabricationConducting polymers and applications

Red, far-red, and near infrared photoswitches based on azonium ions

Mingxin Dong、Amirhossein Babalhavaeji、Mickel J. Hansen 等 5 位作者2015-01-01Chemical Communications

Azonium ions formed by p-amino substituted azo compounds with both ortho- and meta-methoxy substituents exhibit strong absorbance in far-red and near infrared spectral region. The compounds undergo robust photoswitching in aqueous solution and exhibit a range of thermal relaxation rates from 10 μs-100 ms.

Luminescence and Fluorescent MaterialsPhotochromic and Fluorescence ChemistryPhotoreceptor and optogenetics research

Freestanding CNT–WO 3 hybrid electrodes for flexible asymmetric supercapacitors

Peng Sun、Zewei Deng、Peihua Yang 等 10 位作者2015-01-01Journal of Materials Chemistry A

The CNT//CNT–WO 3 asymmetric supercapacitor reaches a power density of 30.6 mW cm −3 and retains 75.8% after 50 000 cycles.

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced battery technologies research

Spectroscopic analysis of PMMA/PVC blends containing CoCl2

Naziha Suliman Alghunaim2015-01-01Results in Physics

Composites of polymethyl methacrylate (PMMA) and polyvinyl chloride (PVC) polymer blend containing different concentrations (⩽10 wt.) of cobalt chloride (CoCl2) were prepared by casting techniques. The changes of the structural, spectroscopic, optical and thermal parameters of the samples are studied using different t…

Polymer Nanocomposites and PropertiesPolymer Nanocomposite Synthesis and IrradiationPolymer Science and PVC

Revealing unusual chemical bonding in planar hyper-coordinate Ni 2 Ge and quasi-planar Ni 2 Si two-dimensional crystals

Li-Ming Yang、Ivan A. Popov、Thomas Frauenheim 等 7 位作者2015-01-01Physical Chemistry Chemical Physics

We discover unusual chemical bonding in a novel planar hyper-coordinate Ni2Ge free-standing 2D monolayer, and also in a nearly planar slightly buckled Ni2Si monolayer. This unusual bonding is revealed by Solid State Adaptive Natural Density Partitioning analysis. This analysis shows that a new type of 2c-2e Ni-Si σ an…

Graphene research and applications2D Materials and ApplicationsTopological Materials and Phenomena

Network-like mesoporous NiCo 2 O 4 grown on carbon cloth for high-performance pseudocapacitors

Suning Gao、Fan Liao、Shuzhen Ma 等 5 位作者2015-01-01Journal of Materials Chemistry A

Network-like mesoporous NiCo 2 O 4 arrays on carbon cloth show a constant rate performance of 80% shifting from 1 to 32 A g −1 , and only a 10% loss of its capacitance after 4000 recycles.

Advancements in Battery MaterialsElectrocatalysts for Energy ConversionSupercapacitor Materials and Fabrication

Exposing the intermolecular nature of the second relaxation pathway in a mononuclear cobalt( ii ) single-molecule magnet with positive anisotropy

Fatemah Habib、Ilia Korobkov、Muralee Murugesu2015-01-01Dalton Transactions

The investigation of a pentagonal bipyramidal Co(ii) complex with large positive anisotropy (D ≈ +30 cm(-1)) revealed field induced Single-Molecule Magnet behaviour with Ueff ≈ 50 K at 1.0 kOe. This compound belongs to a group of only a handful of complexes which exhibit this unique magnetic property while possessing…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Methyl viologen-templated zinc gallophosphate zeolitic material with dual photo-/thermochromism and tuneable photovoltaic activity

Junbiao Wu、Chunyao Tao、Yi Li 等 5 位作者2015-01-01Chemical Science

] cavity. The connection of these two building units forms a 3D intersecting pore system containing 8-rings along the [010] direction, and 10-rings along the [001] and [100] directions. The MV-templated JU101 zeolitic material offers a new type of electron transfer system, which endows the material with interesting ph…

Porphyrin and Phthalocyanine ChemistryTransition Metal Oxide NanomaterialsPolyoxometalates: Synthesis and Applications

Facile synthesis of shape-controlled graphene–polyaniline composites for high performance supercapacitor electrode materials

Xiaomiao Feng、Ning-Na Chen、Jinhua Zhou 等 9 位作者2015-01-01New Journal of Chemistry

The shape-controlled graphene–PANI nanocomposites showing excellent performance as supercapacitor electrode materials were successfully prepared by a facile hydrothermal method without any surfactants.

Supercapacitor Materials and FabricationElectrochemical sensors and biosensorsConducting polymers and applications