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Ratiometric fluorescence and mesoporous structure dual signal amplification for sensitive and selective detection of TNT based on MIP@QD fluorescence sensors

Shoufang Xu、Hongzhi Lu2015-01-01Chemical Communications

Molecularly imprinted polymer coated quantum dot (MIP@QD) fluorescence sensors combined with ratiometric fluorescence techniques and mesoporous silica materials have been applied to detect TNT for the first time. The assay platform exhibited excellent selectivity and sensitivity with a detection limit as low as 15 nM.

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsAdvanced Chemical Sensor Technologies

Investigation of different aqueous electrolytes on the electrochemical performance of activated carbon-based supercapacitors

Farshad Barzegar、Damilola Momodu、Omobosede O. Fashedemi 等 6 位作者2015-01-01RSC Advances

Porous activated carbons was synthesized by an environmentally friendly technique, with an in-depth experimental study carried out to understand the electrochemical behaviour in different aqueous electrolytes (KOH, LiCl, and Na 2 SO 4 ).

Supercapacitor Materials and FabricationAdvanced Battery Materials and TechnologiesAdvanced battery technologies research

Surface electrochemistry of CO 2 reduction and CO oxidation on Sm-doped CeO 2−x : coupling between Ce 3+ and carbonate adsorbates

Zhuoluo A. Feng、Michael L. Machala、William C. Chueh2015-01-01Physical Chemistry Chemical Physics

The efficient electro-reduction of CO2 to chemical fuels and the electro-oxidation of hydrocarbons for generating electricity are critical toward a carbon-neutral energy cycle. The simplest reactions involving carbon species in solid-oxide fuel cells and electrolyzer cells are CO oxidation and CO2 reduction, respectiv…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceAdvancements in Solid Oxide Fuel Cells

Phase stability and Raman vibration of the molybdenum ditelluride (MoTe 2 ) monolayer

Min Kan、Hong Gi Nam、Young Hee Lee 等 4 位作者2015-01-01Physical Chemistry Chemical Physics

The phase stability and phase transition of transition metal dichalcogenide (TMD) monolayer materials have attracted tremendous attention due to their attractive diverse potential applications. Here, first-principles calculations based on density-functional theory are carried out to study the newly synthesized MoTe2 m…

Perovskite Materials and Applications2D Materials and ApplicationsMXene and MAX Phase Materials

Hypercrosslinked porous polycarbazoles via one-step oxidative coupling reaction and Friedel–Crafts alkylation

Long Pan、Qi Chen、Jianhua Zhu 等 6 位作者2015-01-01Polymer Chemistry

Facile preparation of hypercrosslinked carbazole-based porous organic polymers via FeCl 3 -promoted one-step oxidative coupling reaction and Friedel–Crafts alkylation from the vinyl or hydroxymethyl functionalized carbazole is reported.

Graphene research and applicationsMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework Applications

Highly electrical and thermoelectric properties of a PEDOT:PSS thin-film via direct dilution–filtration

Jinhua Xiong、Fengxing Jiang、Weiqiang Zhou 等 5 位作者2015-01-01RSC Advances

A flexible PEDOT:PSS thin-film achieves a high electrical conductivity (1500 S cm −1 ) and a high thermoelectric figure of merit ( ZT ∼ 0.1) by a rapid direct dilution–filtration with common organic solvents.

Advanced Sensor and Energy Harvesting MaterialsAdvanced Thermoelectric Materials and DevicesConducting polymers and applications

Mesoporous ZnCo 2 O 4 nanoflakes grown on nickel foam as electrodes for high performance supercapacitors

Jinbing Cheng、Yang Lu、Kangwen Qiu 等 10 位作者2015-01-01Physical Chemistry Chemical Physics

ZnCo2O4 nanoflakes, as electrodes for supercapacitors, are grown on a cellular nickel foam using a cost-effective hydrothermal procedure. The mesoporous ZnCo2O4 nanoflakes have large electroactive surface areas with strong adhesion to the Ni foam, allowing fast ion and electron transport. The nanoarchitecture electrod…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced battery technologies research

A sensitive turn-on fluorescent probe for intracellular imaging of glutathione using single-layer MnO 2 nanosheet-quenched fluorescent carbon quantum dots

Dinggeng He、Xiaoxiao Yang、Xiaoxiao He 等 9 位作者2015-01-01Chemical Communications

A sensitive turn-on fluorescent sensor based on single-layer MnO2 nanosheet-quenched fluorescent carbon quantum dots has been developed for rapid and selective sensing of glutathione in aqueous solutions, as well as in living cells.

Carbon and Quantum Dots ApplicationsSulfur Compounds in BiologyNanocluster Synthesis and Applications

High-performance n-MoS 2 /i-SiO 2 /p-Si heterojunction solar cells

Lanzhong Hao、Wei Gao、Y. J. Liu 等 8 位作者2015-01-01Nanoscale

A solar cell based on the n-MoS2/i-SiO2/p-Si heterojunction is fabricated. The device exhibits a high power-conversion efficiency of 4.5% due to the incorporation of a nano-scale SiO2 buffer into the MoS2/Si interface. The present device architectures are envisaged as potentially valuable candidates for high-performan…

2D Materials and ApplicationsNanowire Synthesis and ApplicationsSemiconductor materials and interfaces

An acid-free microwave approach to prepare highly luminescent boron-doped graphene quantum dots for cell imaging

Xin Hai、Quan-Xing Mao、Wenjing Wang 等 6 位作者2015-01-01Journal of Materials Chemistry B

Highly luminescent graphene quantum dots (GQDs) are obtained by restoring the defects of GQDs via incorporation of B atoms into the graphene framework, which exhibits great potential in bio-imaging.

Carbon and Quantum Dots ApplicationsNanocluster Synthesis and ApplicationsGraphene and Nanomaterials Applications

Composition dependence of colossal permittivity in (Sm 0.5 Ta 0.5 ) x Ti 1−x O 2 ceramics

Zhenwei Li、Jiagang Wu、Wenjuan Wu2015-01-01Journal of Materials Chemistry C

In this study, colossal permittivity (CP) (10 4 –10 5 ) is attained in the (Sm 0.5 Ta 0.5 ) x Ti 1−x O 2 ceramics, and their dielectric loss can be further decreased by doping oxides and optimizing the sintering temperatures.

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsDielectric properties of ceramics

An insight into thermodynamics of adsorptive removal of fluoride by calcined Ca–Al–(NO 3 ) layered double hydroxide

Partha Ghosal、Ashok Kumar Gupta2015-01-01RSC Advances

A framework for determination of thermodynamic equilibrium constant and Gibbs free surface energy change was presented. The interactive effect of temperature on adsorption process was addressed by RSM. Endothermic, spontaneous reaction was observed.

Layered Double Hydroxides Synthesis and ApplicationsFluoride Effects and RemovalInorganic Fluorides and Related Compounds