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Nanostructuring graphene for controlled and reproducible functionalization

Kunal S. Mali、John Greenwood、Jinne Adisoejoso 等 5 位作者2015-01-01Nanoscale

The 'graphene rush' that started almost a decade ago is far from over. The dazzling properties of graphene have long warranted a number of applications in various domains of science and technology. Harnessing the exceptional properties of graphene for practical applications however has proved to be a massive task. Apa…

Advancements in Battery MaterialsGraphene research and applicationsGraphene and Nanomaterials Applications

Invited Article: A round robin test of the uncertainty on the measurement of the thermoelectric dimensionless figure of merit of Co0.97Ni0.03Sb3

E. Alleno、David Bérardan、Céline Byl 等 17 位作者2015-01-01Review of Scientific Instruments

A round robin test aiming at measuring the high-temperature thermoelectric properties was carried out by a group of European (mainly French) laboratories (labs). Polycrystalline skutterudite Co0.97Ni0.03Sb3 was characterized by Seebeck coefficient (8 labs), electrical resistivity (9 labs), thermal diffusivity (6 labs)…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermodynamic and Structural Properties of Metals and Alloys

Thermal properties of graphene and few‐layer graphene: applications in electronics

Zhong Yan、Denis L. Nika、Alexander A. Balandin2015-01-01IET Circuits Devices & Systems

The authors review thermal properties of graphene and few‐layer graphene (FLG), and discuss applications of these materials in thermal management of advanced electronics. The intrinsic thermal conductivity of graphene – among the highest of known materials – is dominated by phonons near the room temperature. The examp…

Graphene research and applicationsThermal properties of materialsThermal Radiation and Cooling Technologies

Dissolving process of a cellulose bunch in ionic liquids: a molecular dynamics study

Yao Li、Xiaomin Liu、Suojiang Zhang 等 7 位作者2015-01-01Physical Chemistry Chemical Physics

In recent years, a variety of ionic liquids (ILs) were found to be capable of dissolving cellulose and mechanistic studies were also reported. However, there is still a lack of detailed information at the molecular level. Here, long time molecular dynamics simulations of cellulose bunch in 1-ethyl-3-methylimidazolium…

Biofuel production and bioconversionAdvanced Cellulose Research StudiesLignin and Wood Chemistry

The promotional role of Ce in Cu/ZSM-5 and in situ surface reaction for selective catalytic reduction of NO x with NH 3

Shuangshuang Lai、Dongmei Meng、Wangcheng Zhan 等 7 位作者2015-01-01RSC Advances

Ce doped Cu/ZSM-5 catalysts were prepared by the incipient-wetness-impregnation method, and the effect of Ce doping on the structure and the catalytic performance was investigated in detail for the selective catalytic reduction of NO with NH 3

Catalytic Processes in Materials ScienceGas Sensing Nanomaterials and SensorsCatalysis and Oxidation Reactions

Dynamics of a caged imidazolium cation–toward understanding the order-disorder phase transition and the switchable dielectric constant

Xi Zhang、Xiu‐Dan Shao、Si-Chao Li 等 7 位作者2015-01-01Chemical Communications

A molecular compass-like behaviour is found in a perovskite-type cage compound (HIm)2[KCo(CN)6] (HIm = imidazolium cation). The dynamic changes in the HIm cation from the static to rotating state along with the rearrangement of the host cage result in switchable and anisotropic dielectric constants.

Metal-Organic Frameworks: Synthesis and ApplicationsPerovskite Materials and ApplicationsOrganic and Molecular Conductors Research

Two-dimensional graphene-like C 2 N: an experimentally available porous membrane for hydrogen purification

Bo Xu、Hongjun Xiang、Qi‐Huo Wei 等 7 位作者2015-01-01Physical Chemistry Chemical Physics

We theoretically demonstrate that the two-dimensional porous C2N sheet exhibits an extremely high selectivity and large permeance in favour of H2 among other atmospheric gases. This experimentally available porous C2N is superior to traditional membranes, such as polymers and silica, and could have great potential for…

Graphene research and applicationsBoron and Carbon Nanomaterials ResearchMXene and MAX Phase Materials

Framboidal ABC triblock copolymer vesicles: a new class of efficient Pickering emulsifier

Charlotte J. Mable、Nicholas J. Warren、Kate L. Thompson 等 5 位作者2015-01-01Chemical Science

increasing from 36% up to 94%. This is a significant improvement in Pickering emulsifier efficiency compared to that reported previously for similar vesicles with smooth surfaces. In summary, nanoparticles with appreciable surface roughness are much more effective Pickering emulsifiers and this parameter can be readil…

Advanced Polymer Synthesis and CharacterizationBlock Copolymer Self-AssemblyPickering emulsions and particle stabilization

Tunable Schottky contacts in hybrid graphene–phosphorene nanocomposites

Wei Hu、Tian Wang、Jinlong Yang2015-01-01Journal of Materials Chemistry C

Varying interfacial distance can control tunable Schottky contacts and barriers in hybrid graphene–phosphorene nanocomposites.

Graphene research and applications2D Materials and ApplicationsTopological Materials and Phenomena

Correlation between hierarchical structure of crystal networks and macroscopic performance of mesoscopic soft materials and engineering principles

Naibo Lin、Xiang Yang Liu2015-01-01Chemical Society Reviews

This review examines how the concepts and ideas of crystallization can be extended further and applied to the field of mesoscopic soft materials. It concerns the structural characteristics vs. the macroscopic performance, and the formation mechanism of crystal networks. Although this subject can be discussed in a broa…

Calcium Carbonate Crystallization and InhibitionSupramolecular Self-Assembly in MaterialsSilk-based biomaterials and applications

Nanotechnology in Food Industry; Advances in Food processing, Packaging and Food Safety

Mahmoud M. Berekaa、Saudi Arabia2015-01-01OpenAlex

A B S T R A C T This review focuses on tremendous benefits of nanotechnology in food industry in terms of food processing, packaging, safety and quality control. Nanotechnology can modify permeability of packaging material, increasing barrier properties, improving mechanical and heat-resistance, developing active anti…

Nanoparticles: synthesis and applicationsMicroplastics and Plastic PollutionNanotechnology research and applications

Synthesis of covalent triazine-based frameworks with high CO 2 adsorption and selectivity

Chunyang Gu、Deyu Liu、Wei Huang 等 5 位作者2015-01-01Polymer Chemistry

PCTF-4 with benzothiadiazole exhibited the highest CO 2 uptake (20.5 wt%) and CO 2 /N 2 selectivity (56) among the reported covalent triazine-based frameworks.

Metal-Organic Frameworks: Synthesis and ApplicationsMembrane Separation and Gas TransportCovalent Organic Framework Applications

Mechanisms of hydrogen bond formation between ionic liquids and cellulose and the influence of water content

Brooks D. Rabideau、Ahmed E. Ismail2015-01-01Physical Chemistry Chemical Physics

We study the dynamics of the formation of multiple hydrogen bonds between ionic liquid anions and cellulose using molecular dynamics simulations. We examine fifteen different ionic liquids composed of 1-alkyl-3-methylimidazolium cations ([Cnmim], n = 1, 2, 3, 4, 5) paired with either chloride, acetate or dimethylphosp…

Ionic liquids properties and applicationsAdvanced Cellulose Research StudiesLignin and Wood Chemistry

Chemical sporulation and germination: cytoprotective nanocoating of individual mammalian cells with a degradable tannic acid–Fe III complex

Juno Lee、Hyeoncheol Cho、Jinsu Choi 等 8 位作者2015-01-01Nanoscale

Individual mammalian cells were coated with cytoprotective and degradable films by cytocompatible processes maintaining the cell viability. Three types of mammalian cells (HeLa, NIH 3T3, and Jurkat cells) were coated with a metal-organic complex of tannic acid (TA) and ferric ion, and the TA-Fe(III) nanocoat effective…

Nanoparticle-Based Drug DeliveryRNA Interference and Gene DeliveryPolymer Surface Interaction Studies