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A redox mediator doped gel polymer as an electrolyte and separator for a high performance solid state supercapacitor

Guofu Ma、Miaomiao Dong、Kanjun Sun 等 6 位作者2015-01-01Journal of Materials Chemistry A

A stable and effective redox-mediator gel electrolyte has been prepared by doping indigo carmine (IC) into a polyvinyl alcohol sulfuric acid polymer system (PVA–H 2 SO 4 ), and a high performance solid state supercapacitor is fabricated by utilizing activated carbon as electrodes and the prepared gel polymer (PVA–H 2…

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Enhanced adsorption removal of methyl orange from aqueous solution by nanostructured proton-containing δ-MnO 2

Yan Liu、Chao Luo、Jian Sun 等 6 位作者2015-01-01Journal of Materials Chemistry A

Two nanostructured proton-containing δ-MnO 2 (H-δ-MnO 2 ) materials were synthesized through proton exchange for K-containing δ-MnO 2 (K-δ-MnO 2 ) nanosheets and nanoparticles prepared by the hydrothermal homogeneous precipitation method and solid-state reaction.

Adsorption and biosorption for pollutant removalSupercapacitor Materials and FabricationNanomaterials for catalytic reactions

Exfoliated semiconducting pure 2H-MoS 2 and 2H-WS 2 assisted by chlorosulfonic acid

Georgia Pagona、Carla Bittencourt、Raúl Arenal 等 4 位作者2015-01-01Chemical Communications

Chlorosulfonic acid assisted the exfoliation of MoS2 and WS2 resulting in retaining their semiconducting 2H-phase, sharply contrasting the semiconducting-to-metallic phase-transition observed with the currently available exfoliation techniques.

2D Materials and ApplicationsCorrosion Behavior and InhibitionMXene and MAX Phase Materials

Formulation and evaluation of PLGA nanoparticles loaded capecitabine for prostate cancer.

Shuben Sun、Ping Liu、Fa-ming Shao 等 4 位作者2015-01-01PubMed

The objective of this work is to prepare and evaluate Poly (D, L-Lactide-co-glycolide) (PLGA) Nanoparticles (NPs) of Capecitabine, an anticancer agent loaded by solvent displacement method using stabilizer (poly vinyl alcohol). The prepared NPs were characterized by FT-IR, DSC, drug loading, entrapment efficiency, par…

Nanoparticle-Based Drug DeliveryAdvanced Drug Delivery SystemsCurcumin's Biomedical Applications

CeO x -modified RhNi nanoparticles grown on rGO as highly efficient catalysts for complete hydrogen generation from hydrazine borane and hydrazine

Zhujun Zhang、Zhang‐Hui Lu、Hongliang Tan 等 5 位作者2015-01-01Journal of Materials Chemistry A

Amorphous CeO x -doped Rh-Ni NPs grown on reduced graphene oxide nanosheets have been used as highly efficient and recyclable catalysts for complete hydrogen generation from aqueous solution of N 2 H 4 BH 3 or N 2 H 4 .

Hydrogen Storage and MaterialsAmmonia Synthesis and Nitrogen ReductionNanomaterials for catalytic reactions

Shape Memory Alloys Behaviour: A Review

Paulo Silva Lobo、João Almeida、Lúıs Guerreiro2015-01-01Procedia Engineering

Shape memory alloys are used in a variety of fields, such as medical or aeronautical. Other fields of knowledge have been researching these materials, attracted by their capacity to dissipate energy through high-strain hysteretic cycles without significant residual strains. Because of these interesting properties for…

Shape Memory Alloy Transformations

Tuning colloidal gels by shear

Nick Koumakis、Esmaeel Moghimi、R. Besseling 等 6 位作者2015-01-01Soft Matter

Using a powerful combination of experiments and simulations we demonstrate how the microstructure and its time evolution are linked with mechanical properties in a frustrated, out-of-equilibrium, particle gel under shear. An intermediate volume fraction colloid-polymer gel is used as a model system, allowing quantific…

Proteins in Food SystemsMaterial Dynamics and PropertiesPickering emulsions and particle stabilization

Calibration of the basic strength of the nitrogen groups on the nanostructured carbon materials

Bo Li、Xiaoying Sun、Dangsheng Su2015-01-01Physical Chemistry Chemical Physics

The basicity of the graphitic, pyridine, and pyrrole nitrogen groups on the graphene and single-walled carbon nanotubes is evaluated and compared in terms of both Brønsted base and Lewis base. It turns out that the pyridine group is the most strong basic site, while the graphitic nitrogen does not bring any improvemen…

Carbon Nanotubes in CompositesGraphene research and applicationsBoron and Carbon Nanomaterials Research

FRET-capable supramolecular polymers based on a BODIPY-bridged pillar[5]arene dimer with BODIPY guests for mimicking the light-harvesting system of natural photosynthesis

Lu‐Bo Meng、Dongqi Li、Shuhan Xiong 等 6 位作者2015-01-01Chemical Communications

AA/BB-type and A2/B3-type FRET-capable supramolecular polymers based on a BODIPY-bridged pillar[5]arene dimer and two BODIPY derivative guests have been successfully constructed and their application in mimicking the light-harvesting system of natural photosynthesis was studied.

Molecular Sensors and Ion DetectionSupramolecular Chemistry and ComplexesLuminescence and Fluorescent Materials

Three dimensional architectures: design, assembly and application in electrochemical capacitors

Minghao Yu、Weitao Qiu、Fuxin Wang 等 7 位作者2015-01-01Journal of Materials Chemistry A

This review presents the current progress of 3D structured electrodes, mainly focusing on their design, assembly and applications in supercapacitors. The main challenges and new trends in 3D electrode development have also been proposed.

Electrocatalysts for Energy ConversionSupercapacitor Materials and FabricationConducting polymers and applications

Tunable design of layered CuCo 2 O 4 nanosheets@MnO 2 nanoflakes core–shell arrays on Ni foam for high-performance supercapacitors

Min Kuang、Xiaoying Liu、Fan Dong 等 4 位作者2015-01-01Journal of Materials Chemistry A

Layered CuCo 2 O 4 nanosheets@MnO 2 nanoflakes core–shell arrays (CuCo 2 O 4 @MnO 2 CAs) on Ni foam have been uniformly synthesized by fine tuning the operation temperature, exhibiting superior capacitance and excellent electrochemical performance stability.

Advancements in Battery MaterialsElectrocatalysts for Energy ConversionSupercapacitor Materials and Fabrication

Fabrication of ultrathin CoMoO 4 nanosheets modified with chitosan and their improved performance in energy storage device

Ramya Ramkumar、Manickam Minakshi2015-01-01Dalton Transactions

Ultrathin nanosheet-assembled cobalt molybdate (CoMoO4) with a mesoporous morphology was synthesized by a urea-assisted solution combustion route at a temperature of 400 °C. The as-prepared CoMoO4 was modified using chitosan cross-linked with glutaraldehyde (glu) and employed as a cathode material in an aqueous hybrid…

Supercapacitor Materials and FabricationConducting polymers and applicationsAdvanced battery technologies research

Mesoporous 2D covalent organic frameworks based on shape-persistent arylene-ethynylene macrocycles

Haishen Yang、Ya Du、Shun Wan 等 6 位作者2015-01-01Chemical Science

Covalent organic frameworks with high porosity and crystallinity have been synthesized, through macrocycle-to-framework strategy, using shape-persistent arylene-ethynylene macrocycles as the key components to control the topology and modulate the porosity.

Metal-Organic Frameworks: Synthesis and ApplicationsLuminescence and Fluorescent MaterialsCovalent Organic Framework Applications

Designing the shape evolution of SnSe 2 nanosheets and their optoelectronic properties

Yun Huang、Kai Xu、Zhenxing Wang 等 8 位作者2015-01-01Nanoscale

Layered chalcogenide materials (LCMs) are emerging materials in recent years for their great potential in applications of electronics and optoelectronics. As a member of LCMs, SnSe2, an n-type semiconductor with a band gap of ∼1.0 eV, is of great value to explore. In this paper, we develop a facile CVD method, for the…

Perovskite Materials and Applications2D Materials and ApplicationsChalcogenide Semiconductor Thin Films

Inhibited corrosion-promotion activity of graphene encapsulated in nanosized silicon oxide

Wen Sun、Lida Wang、Tingting Wu 等 5 位作者2015-01-01Journal of Materials Chemistry A

The corrosion-promotion activity of graphene is inhibited when graphene is encapsulated in insulating SiO 2 because SiO 2 can act as a spacer isolating graphene from the metal substrate so as to prevent graphene–metal micro-galvanic corrosion. Incorporating rGO@SiO 2 nanosheets into a polymer coating also greatly enha…

Graphene research and applicationsCorrosion Behavior and InhibitionGraphene and Nanomaterials Applications

Combinatorial insights into doping control and transport properties of zinc tin nitride

Angela N. Fioretti、Andriy Zakutayev、Helio Moutinho 等 9 位作者2015-01-01Journal of Materials Chemistry C

A combinatorial study on semiconducting ZnSnN 2 , in which the lowest carrier density yet reported for as-deposited films is achieved, wurtzite crystal structure is confirmed, and optical bandgap is established at 1.0 eV.

ZnO doping and propertiesMetal and Thin Film MechanicsMachine Learning in Materials Science

Observation of the single-ion magnet behavior of d 8 ions on two-coordinate Co( i )–NHC complexes

Yin‐Shan Meng、Zhenbo Mo、Bing‐Wu Wang 等 6 位作者2015-01-01Chemical Science

The first single-ion magnet (SIM) [Co(IMes) 2 ][BPh 4 ] (IMes: 1,3-dimesitylimidazol-2-ylidene) with d 8 electronic configuration has been found in two-coordinate Co( i )–NHC complexes.

Magnetism in coordination complexesOrganic and Molecular Conductors ResearchN-Heterocyclic Carbenes in Organic and Inorganic Chemistry