Materials Literature
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Two types of fluorene-based organic dyes featuring T-shape/rod-shape molecular configuration with phenothiazine donor and cyanoacrylic acid acceptor have been synthesized and characterized as sensitizers for dye-sensitized solar cells. Phenothiazine is functionalized at either nitrogen (N10) or carbon (C3) to obtain T…
We report the fabrication of multiple emulsions where both the enclosed and the external water phases are structured using a combination of two non-gelling biopolymers. Emulsions (with gelled inner water droplets and gelled water continuous phase) were created using a simple ‘one-step’ process where the oil phase (tri…
Human skin exhibits highly nonlinear elastic properties that are essential to its physiological functions. It is soft at low strain but stiff at high strain, thereby protecting internal organs and tissues from mechanical trauma. However, to date, the development of materials to mimic the unique mechanical properties o…
Dually fixed SnO2 nanoparticles (DF-SnO2 NPs) on graphene nanosheets by a polyaniline (Pani) coating was successfully fabricated via two facile wet chemistry processes, including anchoring SnO2 NPs onto graphene nanosheets via reducing graphene oxide by Sn(2+) ion, followed by in situ surface sealing with the Pani coa…
The present work describes an improved process for preparation of silica aerogel microparticles (SAMs) for drug delivery from rice husk ash (RHA), an inexpensive source rich in biocompatible silica. The wet gel microparticles were produced by a sol–gel method using water-in-oil emulsion, where a mineral oil replaced v…
The optical response of a plasmonic gap-antenna is mainly determined by the Coulomb interaction of the two constituent arms of the antenna. Using rigorous calculations supported by simple analytical models, we observe how the morphology of a nanometric gap separating two metallic rods dramatically modifies the plasmon…
We report numerical simulations based on a non-Markovian density matrix propagation scheme of singlet fission (SF) in molecular crystals. Ab initio electronic structure calculations were used to parametrize the exciton and phonon Hamiltonian as well as the interactions between the exciton and the intramolecular and in…
Porous graphene oxide can be used as a metal-free catalyst in the presence of air for oxidative coupling of primary amines. Herein, we explore a GO-catalyzed carbon-carbon or/and carbon-heteroatom bond formation strategy to functionalize primary amines in tandem to produce a series of valuable products, i.e., α-aminop…
Oriental Journal of Chemistry is a peer reviewed quarterly research journal of pure and applied chemistry. It publishes standard research papers in almost all thrust areas of current chemistry of academic and commercial importance. It provides a platform for rapid publication of quality research papers, reviews and ch…
Despite playing important roles throughout biology, molecular recognition mechanisms in intrinsically disordered proteins remain poorly understood. We present a combination of (1)H(N), (13)C', and (15)N relaxation dispersion NMR, measured at multiple titration points, to map the interaction between the disordered doma…
Localized surface plasmon resonance (LSPR) of doped Si nanocrystals (NCs) is critical to the development of Si-based plasmonics. We now experimentally show that LSPR can be obtained from both B- and P-doped Si NCs in the mid-infrared region. Both experiments and calculations demonstrate that the Drude model can be use…
Z-schematic water splitting was successfully demonstrated using metal sulfide photocatalysts that were usually unsuitable for water splitting as single particulate photocatalysts due to photocorrosion. When metal sulfide photocatalysts with a p-type semiconductor character as a H2-evolving photocatalyst were combined…
Moving nanoparticles/atoms to study the nearfield interaction between them is\none of the many approaches to explore the optical and electrical properties of\nthese assemblies. Traditional approach included the self assembly by spinning\nor drying nanoparticles in aqua on the substrate is well practiced. Lithography\n…
The scattering and absorption suppression of the silica microspheres is\nexperimentally achieved by semicontinuous gold shell synthesized on the silica\nmicrospheres. These fractal gold shells on the silica spheres are shown to have\nsignificant extinction in the visible and mid-infrared spectral range. It is\nfound t…
$Y_2O_3$ 세라믹 소결체를 제작하기 위해, $Y_2O_3$ 분말을 분산한 상태에서 슬러리에 pH 조절제인 NaOH를 첨가하였으며 결합제로는 PVA, 가소제로는 PEG를 첨가하여 열분무 건조 공정을 거쳐 $Y_2O_3$ 과립형 분말을 제조하였다. ${\phi}14mm$ 크기의 $Y_2O_3$ 세라믹 성형체를 성형하고, $1650^{\circ}C$ 의 온도에서 소결하여 $Y_2O_3$ 세라믹 소결체를 제작하였다. $Y_2O_3$ 소결체의 미세구조, 밀도 및 내플라즈마 특성이 성형압력 및 소결시간에 따라 분석되었다. $Y_2O_3$ 소결체는 $CHF_3/O_2/Ar…
본 실험적 연구는 고속 비상체에 의한 강섬유보강콘크리트의 내충격성을 파악하는데 그 목적이 있다. 이 연구에서는 패널두께 대 탄환지름 비가 3.5 이하인 패널 실험체에 강섬유 혼입률, 패널 두께, 충격 속도, 골재 크기를 변수로 조절하면서 고속충격을 가하여서 실험체의 성능을 비교하였다. 강섬유 혼입률이 증가할수록 중량손실량 및 표면 탈락률은 감소하지만, 관입깊이는 증가하는 추세를 보였다. 그리고 충격하중을 받을 때의 거동은 골재 20 mm를 사용하였을 경우 더욱 불리하게 나타났다. 실험결과는 기존 모델에 의한 예측값과 비교하였고, 이를 통해 패널두께 대 탄환지름 비가…
The most common way of renovation of the working parts of agricultural machinery is surfacing by hardfacing coated electrodes and piped hardfacing wires. Another way to prolong the working life of the machinery is the chemical heat treatment of the material surface by nitriding. By nitriding, high hardness is obtained…
Oriental Journal of Chemistry is a peer reviewed quarterly research journal of pure and applied chemistry. It publishes standard research papers in almost all thrust areas of current chemistry of academic and commercial importance. It provides a platform for rapid publication of quality research papers, reviews and ch…
The Bitter method is an adequate method for domains observation, and depends on careful metallographic preparation and also on a proper magnetic colloid solution. In this study, Bitter patterns were obtained for a Nd-Fe-B as-cast alloy. The Nd2Fe14B grains show strong anisotropy during growing, and are larger for the…
새로운 2종의 피페라지노메틸-비스-포스폰산염을 합성하였다. 그리고 이들을 가지고 처리된 리기다 소나무 시험편의 연소성을 기 합성된 화학물질들과 비교 시험하였다. 15 wt%의 알킬렌디아미노알킬-비스-포스폰산염 수용액으로 리기다 소나무에 3회 붓칠한 시험편은 실온에서 건조시킨 후, 콘칼로리미터(ISO 5660-1)를 이용하여 그의 연소성을 시험하였다. 그 결과, 알킬렌디아미노알킬-비스-포스폰산염으로 처리한 시험편은 피페라지노메틸-비스-포스폰산으로 처리한 시험편에 비하여 그의 연소 억제성을 부분적으로 향상시켰다. 특히 알킬렌디아미노알킬-비스-포스폰산염으로 처리한 시험편…