Materials Literature
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In Saccharomyces cerevisiae, the first committed step in the lysine (Lys) biosynthetic pathway is catalysed by the Lys20 and Lys21 homocitrate synthase (HCS) isoforms. Overexpression of Lys20 resulted in eightfold increased Lys, as well as 2-oxoglutarate pools, which were not attained by overexpressing Lys21 or other…
We report surface-enhanced Raman scattering (SERS) from Ag nanoparticles decorated on thin carbon nanowalls (CNWs) grown by microwave plasma chemical vapor deposition. The Ag morphology is controlled by exposing the CNWs to oxygen plasma and through the electrodeposition process by varying the number of deposition cyc…
A new doping strategy to incorporate transition metal dopant ions in semiconductor hosts has been reported here where dopant ions are incorporated in the host lattice following a feasible cation exchange process. Composition variable Cd x Zn 1– x Se alloy nanocrystals have been chosen as an appropriate host which is f…
Abstract The effects of particle size of titanium dioxide (TiO 2 ) on mechanical, thermal, and morphological properties of pure polyoxymethylene (POM) and POM/TiO 2 nanocomposites were investigated and compared with the results for nanoparticle ZnO in the same matrix, reported in a previous paper. POM/TiO 2 nanocompos…
The feasibility of using gold nanoparticles (AuNPs) for biomedical applications has led to considerable interest in the development of novel synthetic protocols and surface modification strategies for AuNPs to produce biocompatible molecular probes. This investigation is, to our knowledge, the first to elucidate the s…
The integration of functional polymers and semiconducting nanorods can lead to properties unattainable by either of the components independently. Elongated nanocrystals provide advantageous anisotropic physical properties which could be uniquely harnessed via integration into hybrid materials, if control over their or…
Doped polyaniline (PANI) was obtained by the polymerization of aniline, using chemical oxidative polymerization in the presence of ammonium peroxydisulfate [(NH 4 ) 2 S 2 O 8 ]. The doped PANI was dedoped by ammonia solution. The electrospinning method was applied to solutions involving PANI–PVA, PANI–PVA–AgNO 3 , whe…
A series of phosphorescent terpyridyl platinum(II) complexes with ancillary biphenylacetylide ligands, namely, [(R(3)tpy)PtC≡C(biphenyl)]X (R=tBu, H, or Et(2)N; tpy=2,2';6',2''-terpyridyl; X is an anion) were synthesized and structurally characterized by various spectroscopic techniques and X-ray diffraction methods.…
Many metal oxides investigated for solar photocatalysis or photoelectrochemistry have band gaps that are too wide to absorb a sufficient portion of the solar spectrum. Doping with impurity ions has been extensively explored as a strategy to sensitize such oxides to visible light, but the electronic structures of the r…
A statistical model describing signal-noise generation and development along the signal formation process in a standard scanning electron microscope (SEM) using an Everhart-Thornley secondary electron detector is derived. Noise in the detector signal is modeled to originate from a cascade of five signal conversion sta…
We study the radial-hedgehog solution in a three-dimensional spherical droplet, with homeotropic boundary conditions, within the Landau–de Gennes theory for nematic liquid crystals. The radial-hedgehog solution is a candidate for a global Landau–de Gennes minimiser in this model framework and is also a prototype confi…
Purifying heterodimers: differential magnetic catch and release separation is used to purify two important hybrid nanocrystal systems, Au-Fe(3)O(4) and FePt-Fe(3)O(4). The purified samples have substantially different magnetic properties compared to the as-synthesized materials: the magnetization values are more accur…
Ligand-stabilized aluminum clusters are investigated by density functional theory calculations. Analysis of Kohn-Sham molecular orbitals and projected density of states uncovers an electronic shell structure that adheres to the superatom complex model for ligand-stabilized aluminum clusters. In this current study, we…
Electrospun nanofibers composed of biodegradable polymers are attractive candidates for cell culture scaffolds in tissue engineering. Their fine-meshed structures, resembling natural extracellular matrices, effectively interact with cell surfaces and promote cell proliferation. The application of electrospinning, howe…
Patterned vacancy clusters (or nanoholes) can modify the electronic structure of graphene, and thereby generate entirely new functionalities. Knowledge of the relative stability of various nanoholes and associated properties is essential for the rational design and fabrication of practical devices. Extensive first-pri…
We present a general method for characterizing the intrinsic electrochemical properties of graphene sheets, such as the specific double-layer capacitance, in the absence of porosity-related artifacts and uncertainties. By assembling densely tiled monolayers of electrically insulating or conductive functionalized graph…
This study reports the design growth and characterization of quaternary Mg and Ga codoped ZnO (MGZO) thin films with transparent conductive characteristics deposited on glass substrates by RF magnetron sputtering. The effects of the Ga concentration (from 0 to 2 at %) on the structural, chemical, morphological, optica…
We have examined the photophysical properties of Zn(II) tetramethylpyridyl porphyrin (ZnT4MPyP) specifically encapsulated within the cubioctahedral cavities of a ZnHKUST metal- organic framework. The encapsulated ZnT4MPyP exhibits a Soret maxima at ∼458 nm that is bathochromically shifted relative to ZnT4PyP in ethano…
Tissue regeneration into a three-dimensional scaffold requires the stimulation of blood vessel ingrowth. We have employed a freely interconnecting porous scaffold developed by us to determine the utility of a covalently bound heparin surface coating for the delivery of vascular endothelial growth factor (VEGF) and pla…
We report on a systematic temperature-dependent x-band electron paramagnetic resonance (EPR) study of nanosized graphite particles prepared by ball milling. In as-prepared samples a very intense and sharp EPR resonance at $g=2.0035$ has been measured. The EPR line width shows a Korringa-like linear temperature depende…