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Qualitative identification of isocyanurate rings in urethane-isocyanurate elastomers and their hydrolyzates

Roksana Samborska‐Skowron、A. Balas2003-05-01Polimery

It has been stated that reliable qualitative identification of isocyanurate rings directly in urethane-isocyanurate elastomers (EUI) can not be realized using ATR method. Such identification becomes possible only on the basis of the analysis of EUI hydrolysis in acid medium products. It was done using following method…

Polymer Synthesis and Characterization

Crystal structure of non-stoichiometric copper selenides studied by neutron scattering and X-ray diffraction

Н. Н. Биккулова、Sergey Danilkin、H. Fueß 等 8 位作者2003-05-01Crystallography Reports

Structural characteristics of non-stoichiometric copper selenides were studied by the elastic neutron and X-ray scattering techniques. Rietveld analysis was used to refine the structure of the high-temperature β-phase of the Cu 1.75 Se, Cu 1.78 Se, and Cu 1.83 Se samples. The homogeneity ranges of the cubic phase were…

Chalcogenide Semiconductor Thin FilmsRare-earth and actinide compoundsCrystal Structures and Properties

The Effect of High Energy Milling on the Solid State Synthesis of MnFe2O4 from Mixtures of MnO-Fe2O3 and Mn3O4-Fe2O3

Vittorio Berbenni、A. Marinia、Antonella Profumo 等 4 位作者2003-05-01Zeitschrift für Naturforschung B

A thermal treatment at 900°C (under nitrogen) of a milled mixture MnO-Fe 2 O 3 yields MnFe 2 O 4 mainly as the product of the reaction between Mn 3 O 4 (produced by ball milling) and Fe 2 O 3 . Under the same experimental conditions but starting from an unmilled MnO- Fe 2 O 3 mixture, the formation of MnFe 2 O 4 is on…

Aluminum Alloys Composites PropertiesMagnetic Properties and Synthesis of FerritesIron oxide chemistry and applications

Preparation and characterization of agglomerates of flurbiprofen by spherical crystallization technique

Manish K. Chourasia、Nitin Jain、Sanjay Jain 等 5 位作者2003-05-01Indian Journal of Pharmaceutical Sciences

Flurbiprofen is an analgesic and antiinflammatory drug with poor water solubility and compressibility. Flurbiprofen conventional drug crystals were converted into spherical crystal agglomerates via the spherical crystallization technique using acetone-water-hexane solvent system. The various parameters optimized were…

Drug Solubulity and Delivery SystemsInnovative Microfluidic and Catalytic Techniques InnovationCrystallization and Solubility Studies

Low-temperature thermal conductivity of solid carbon dioxide

V. V. Sumarokov、P. Stachowiak、A. Jeżowski2003-05-01Low Temperature Physics

Preliminary measurements of the thermal conductivity of pure carbon dioxide in the temperature range 1.5–35 K are reported. The first data below 25 K have been obtained. The thermal conductivity reaches very high values, about 700 W/(m⋅K), which is unusual for simple molecular crystals. A straightforward analysis of t…

Carbon Nanotubes in CompositesPhase Equilibria and ThermodynamicsThermal properties of materials

Compost and Calcium Surface Treatment Effects on Subsoil Chemistry in Acidic Minespoil Columns

Frank J. von Willert、Richard C. Stehouwer2003-05-01Journal of Environmental Quality

Surface incorporation of a liming agent in combination with compost or biosolids is a proven way to revegetate acidic minespoils, but little is known about the effect of the surface amendments on subsoil chemistry. We conducted a greenhouse column experiment to investigate how different surface amendments affected pla…

Soil and Unsaturated FlowClay minerals and soil interactionsMine drainage and remediation techniques

Specific features of magnetic and transport properties of La1−xMn1+xO3 manganites

V. Dyakonov、V. P. Pashchenko、E. Zubov 等 11 位作者2003-05-01Physics of the Solid State

The magnetic and transport properties of La 1− x Mn 1+ x O 3 manganites with excess manganese are studied. It is shown that magnetic and charge ordering heavily depends on the superstoichiometric manganese content, magnetic field, and pressure. The magnetoresistive effect (MRE) is enhanced as the manganese concentrati…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsAdvanced Condensed Matter Physics

Analyses of the OECD Main Steam Line Break Benchmark with the DYN3D and ATHLET Codes

U. Grundmann、S. Kliem2003-05-01Nuclear Technology

The Organization for Economic Cooperation and Development (OECD) Main Steam Line Break (MSLB) Benchmark was defined to validate the thermal-hydraulic system codes coupled with three-dimensional (3-D) neutron kinetic codes. The reference problem is an MSLB in a pressurized water reactor at end of cycle. The analyses we…

Nuclear reactor physics and engineeringNuclear Materials and PropertiesNuclear Engineering Thermal-Hydraulics

Study on the thermal decomposition kinetics of nano-sized calcium carbonate

Daixi Li、Shi Hong-Yun、Jie Deng 等 4 位作者2003-05-01Journal of Zhejiang University. Science A

This study of the thermal decomposition kinetics of various average diameter nano-particles of calcium carbonate by means of TG-DTA ( thermogravimetry and differential thermal analysis) showed that the thermal decomposition kinetic mechanisms of the same crystal type of calcium carbonate samples do not vary with decre…

Energetic Materials and CombustionThermal and Kinetic AnalysisPolymer Synthesis and Characterization

Potassium, Calcium, and Magnesium Mineralization in Manure-Treated Soils

A. Egrinya Eneji、Muhammad Irshad、Toshimasa Honna 等 6 位作者2003-05-01Communications in Soil Science and Plant Analysis

Studies into cation release in manured soils are very limited and poorly documented. The present investigation was therefore aimed at comparing the influence of manure application on cation [calcium (Ca), magnesium (Mg) and potassium (K)] mineralization in four different soils. Four sources of livestock manure: chicke…

Soil Carbon and Nitrogen DynamicsSoil and Unsaturated FlowClay minerals and soil interactions

Trifenylmethane Compounds as Copper Corrosion Inhibitors in Hydrochloric Acid Solution

J. L. Polo、Paz Pinilla、E. Cano 等 4 位作者2003-05-01CORROSION

Fuchsin basic (FB) and fuchsin acid (FA) were tested as new corrosion inhibitors for copper in 0.001, 0.005, and 0.01 M hydrochloric acid (HCl) solutions. Benzotriazole (BTA) was also tested for comparative purposes. Twelve FB, FA, and BTA concentrations, from 1 × 10–5 M to 1 × 10–1 M, were added to the acid solution…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Microstructural Aspects and Optimization of Thin Slab Direct Rolling of Steels

Radko Kašpar2003-05-01steel research international

By using a thin slab casting simulator combined with the hot deformation simulator WUMSI, laboratory tests were performed to investigate the microstructure processes and mechanical properties in the process of thin slab direct rolling (TSDR). The paper shows the possibilities to improve the initial as‐cast state of mi…

Microstructure and Mechanical Properties of SteelsMetallurgy and Material FormingMetal Alloys Wear and Properties

Use of Real-time FTIR to Characterize Kinetics of Amine Catalysts and to Develop New Grades for Various Polyurethane Applications, Including Low Emission Catalysts

Pierre Chaffanjon、R. A. Grisgby、Ernest L. Rister 等 4 位作者2003-05-01Journal of Cellular Plastics

The use of in situ Fourier Transform Infrared (FTIR) to follow PU reaction kinetics has been studied using a heated probe matching the PU material temperature. The results obtained show that, although not giving access to concentration of formed chemical bonds, the technique is a unique tool to assess subtle differenc…

Polymer composites and self-healingFlame retardant materials and propertiesCarbon dioxide utilization in catalysis

Current-voltage characteristics of poly(diphenylenephthalide) thin films

A. A. Bunakov、А. Н. Лачинов、R. B. Salikhov2003-05-01Technical Physics

Charge transfer near the threshold of polymer film transition (induced by a low uniaxial pressure) to the high-conductivity state is studied in an attempt to tackle the question of how the energy band structure of a wide-gap organic insulator varies near this threshold. The I-V characteristics of poly(diphenylenephtha…

Organic Light-Emitting Diodes ResearchConducting polymers and applicationsAnalytical Chemistry and Sensors

Intensive Quenching Theory and Application for Imparting High Residual Surface Compressive Stresses in Pressure Vessel Components

Andrew M. Freborg、B. Lynn Ferguson、M. A. Aronov 等 5 位作者2003-05-01Journal of Pressure Vessel Technology

An alternative method for the hardening of steel parts has been developed as a means of providing steel products with superior mechanical properties through development of high residual compressive stresses on the part surface, and involves the application of intensive quenching during heat treatment. This processing…

Metal and Thin Film MechanicsMicrostructure and Mechanical Properties of SteelsMetal Alloys Wear and Properties

Fabrication of suspended porous silicon micro-hotplates for thermal sensor applications

C. Tsamis、A. Tserepi、A. G. Nassiopoulou2003-05-01physica status solidi (a)

In this work, we describe a process for the fabrication of suspended porous silicon micro-hotplates for application in thermal sensors. Membrane release is achieved by means of lateral isotropic etching of the bulk silicon substrate, the etching being highly selective to the porous silicon and the photoresist used to…

Silicon Nanostructures and PhotoluminescenceNanowire Synthesis and ApplicationsAnalytical Chemistry and Sensors

X-ray study of modulated structures of beta-Cu x V 2 O 5

Nobuaki Nagao、Yoshio Nogami、K. Oshima 等 5 位作者2003-05-01Padua Research Archive (University of Padova)

Adsorption isotherms of He-4 on Na and on Rb measured with a quartz crystal microbalance are presented. The isotherms on Na indicate complete wetting at coexistence and the growth of a thin film at low relative pressures, which may become superfluid at lower temperatures. The results on Rb indicate clear prewetting ju…

Transition Metal Oxide NanomaterialsCopper Interconnects and ReliabilityCatalysis and Oxidation Reactions

The reality of negative refraction

David R. Smith2003-05-01Physics World

One of the most fundamental phenomena in optics is refraction. When a beam of light crosses the interface between two different materials, its path is altered depending on the difference in the refractive indices of the materials. The greater the difference, the greater the refraction of the beam. For all known natura…

Optical Coatings and Gratings

Ignition and combustion of low‐density polyimide foam

Fu‐Yu Hshieh、David B. Hirsch、Harold D. Beeson2003-05-01Fire and Materials

Abstract The ignition, flaming and smoldering combustion of low‐density polyimide foam have been studied using a cone calorimeter. Low‐density polyimide foam exhibits a high ignition resistance. The minimum heat flux for the ignition of flaming combustion ranges from 48 to 54 kW/m 2 . This minimum heat flux also indic…

Fire dynamics and safety researchFlame retardant materials and propertiesThermal and Kinetic Analysis

Anomalous thermal expansion behaviour of Na8[AlSiO4]6(NO3)2-sodalite:P43ntoPm3nphase transition by untilting and contraction of TO4units

Claus H. Rüscher、Thorsten M. Gesing、Josef‐Christian Buhl2003-05-01Zeitschrift für Kristallographie - Crystalline Materials

Abstract X-ray single crystal, X-ray powder and specific heat investigations were carried out on alumosilicate NaNO 3 -sodalite between 290 K and 1100 K. Single crystal structure determinations at 295 K, 505 K and 720 K reveal the sodalite structure in its partially collapsed form in space group P 4̅3 n whereas at 935…

Glass properties and applicationsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography