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Synthesis and liquid crystalline structures of poly(L-lysine) containing undecanamidobiphenyl units in the side chains

Céline Guillermain、Bernard Gallot2002-01-01Liquid Crystals

In order to obtain liquid crystalline comb-like poly(L-lysine) bearing biphenylyl mesogenic groups in their side chains, we synthesized the 11-(biphenyl-4-carboxamido)undecanamidoL-lysine (KC10φφ) from L-lysine by a five step procedure and transformed the KC10 φφ into its polymerizable cyclic derivative (the N-carboxy…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesBiopolymer Synthesis and Applications

Structural Steels. Effect of Sulfide Morphologies on the Machinability of Shape-Controlled-Sulfide Free Machining Steel.

Masakazu Hayaishi2002-01-01DENKI-SEIKO

Since lead contaminates the environment, the various types of shape-controlled-sulfide (SCS) free machining steel, in which sulfide shapes are controlled to be spherical, have been developed to replace the leaded ones. However, in these SCS free machining steels, the effect of aspect ratio, size, and composition of su…

Microstructure and Mechanical Properties of SteelsMetallurgy and Material FormingMetal Alloys Wear and Properties

Comment on “Lattice Contraction and Surface Stress of fcc Nanocrystals”

Jörg Weißmüller2002-01-01The Journal of Physical Chemistry B

ADVERTISEMENT RETURN TO ISSUEPREVCommentComment on "Lattice Contraction and Surface Stress of fcc Nanocrystals"J. WeissmüllerView Author Information Forschungszentrum Karlsruhe, Institut für Nanotechnologie, D-76021 Karlsruhe, Germany and Universität des Saarlandes, Technische Physik, Saarbrücken, Germany Cite this: J…

Microstructure and mechanical propertiesnanoparticles nucleation surface interactionsSurface and Thin Film Phenomena

An energy criterion for the initiation of interface failure ahead of a matrix crack in brittle matrix composites

E. Martin、Dominique Leguillon、Cécile Lacroix2002-01-01Composite Interfaces

The mechanism of interfacial failure occurring as a consequence of the stress concentration induced by a matrix crack located in the vicinity of the interface is analysed. For this purpose, an asymptotic analysis is carried out to assess the competition between the propagation of the matrix crack towards the interface…

Advanced ceramic materials synthesisMechanical Behavior of CompositesNumerical methods in engineering

Phase Transitions in Ba 1− x Sr x TiO 3 Ceramics

P. S. Dobal、Anju Dixit、Ram S. Katiyar 等 6 位作者2002-01-01Ferroelectrics Letters Section

Raman spectroscopy has been utilized to investigate the Sr-substitution, stress/strain, and grain size effects in Ba 1 m x Sr x TiO 3 ceramics. Ceramic samples were prepared for x = 0.00, 0.10, 0.30, and 0.35 compositions using a solid-state reaction technique. Single-phase perovskite structure of the ceramics was ide…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisDielectric properties of ceramics

Effects of Ga Addition on the Mechanical Properties of 35Ag-30Pd-20Au-15Cu Alloy.

Masahiko YAMANAKA、Shinichi Goto、Pornkiat Churnjitapirom 等 4 位作者2002-01-01Dental Materials Journal

Ten 35Ag-30Pd-20Au-15Cu alloys containing 0.00, 0.25, 0.50, 0.75, 1.00, 1.25, 1.50, 2.00, 4.00, or 6.00% Ga were experimentally prepared to investigate the effect of Ga on their mechanical properties in addition to their use for denture frameworks, connectors and clasps. The effect of Ga addition on the mechanical pro…

Aluminum Alloy Microstructure PropertiesMetallurgy and Material FormingMetallurgical and Alloy Processes

MODULATION BYACANTHOSPERMUM AUSTRALEEXTRACTS OF THE TUMOR INDUCED HEMATOPOIETIC CHANGES IN MICE

Luciana Mirandola、Giselle Z. Justo、Mary L.S. Queiroz2002-01-01Immunopharmacology and Immunotoxicology

Previous studies on the Ehrlich ascites tumor (EAT) model indicate that tumor progression is associated with reduced myelopoiesis and increased extramedullar hematopoiesis. In order to investigate the in vivo antitumor activity of Acanthospermum australe, its hydroalcoholic extract was partitioned with different solve…

Phytochemistry and Biological ActivitiesPlant-derived Lignans Synthesis and BioactivityPhytochemistry and Bioactive Compounds

Effects of Annealing Conditions on Crystallization of Hexagonal Manganite Films

Kazuyuki Suzuki、Kaori Nishizawa、Takeshi Miki 等 4 位作者2002-01-01Ferroelectrics

(Y,Yb)MnO 3 thin films were prepared on Pt(111)/TiO x /SiO 2 /Si substrates using alkoxy-derived precursor solutions. The annealing conditions were critical for crystallization of (Y,Yb)MnO 3 films. The (Y,Yb)MnO 3 films crystallized in vacuum were hexagonal phase and the orientation of the films changed with composit…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Predicting adhesion between a crystalline polymer and silane-treated glass surfaces in filled composites

Andrew C. Miller、John C. Berg2002-01-01Journal of Adhesion Science and Technology

Results reported earlier showing a close correlation between measured adhesion strength of bonds between silane-modified glass and various amorphous thermoplastics and a thermodynamic compatibility criterion based on UNIFAC are extended to the case of a crystalline polymer matrix. The criterion used is the magnitude o…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesAdhesion, Friction, and Surface Interactions

The effects of grinding on the physico-chemical characteristics of white sepiolite from Golesh

Dušan Vučelić、Dana Simic、Olgica Kovacevic 等 5 位作者2002-01-01Journal of the Serbian Chemical Society

The influence of grinding white sepiolites from the Magure-Golesh mine in Southern Serbia on their structure and on the rheological characteristics of their aqueous suspensions was investigated. Sepiolite samples of hard and soft consistency were ground in three different types of mills: a ball mill air-stream mill, a…

Clay minerals and soil interactionsMineral Processing and Grinding

Development of the alternating current stress measurement model for magnetostriction behaviour of mild steel under orthogonal magnetic fields for stress measurement

Shaojie Han、Feargal Brennan、W.D. Dover2002-01-01The Journal of Strain Analysis for Engineering Design

Basic studies have been conducted on stress measurement using magnetostriction features of mild steel under orthogonal magnetic fields. Most studies on the magnetostriction characteristics have been made using a single magnetic field when dealing with biaxial stress fields. An idealized model is proposed that is based…

Microstructure and Mechanical Properties of SteelsMagnetic Properties and ApplicationsNon-Destructive Testing Techniques

Advanced modelling of the harmonic impedances of AC-DC converters

G.N. Bathurst、J. Arrillaga、N.R. Watson 等 4 位作者2002-01-01IEE Proceedings - Generation Transmission and Distribution

A fast numerical-linearisation technique is used with the harmonic-domain algorithm to calculate the harmonic impedances of AC-DC converters. The accuracy of the new method is illustrated by comparison with existing simplified models. The method is then used to determine the effect of local and remote converter plant…

Power System Optimization and StabilityHigh voltage insulation and dielectric phenomenaMagnetic Properties and Applications

Lattice dynamics of antiperovskite structure compounds a3ox (a=na, k; x=ci, br)

В. И. Зиненко、N. G. Zamkova2002-01-01Ferroelectrics

The phonon spectra, Born effective charges, dielectric constants and elastic modules of Na3OCl, Na3OBr, K3OCl and K3OBr have been calculated by the generalized Gordon-Kim method. In the phonon spectra of Na3OCl, K3OCl and K3OBr unstable modes are found

Perovskite Materials and ApplicationsSolid-state spectroscopy and crystallographyThermal Expansion and Ionic Conductivity

Interface Engineering in ZnO Epitaxy

Soon‐Ku Hong、Y. Chen、H. J. Ko 等 4 位作者2002-01-01physica status solidi (b)

We report interface engineering in ZnO epitaxy to grow high-quality layers by plasma-assisted molecular beam epitaxy. Through interface engineering, we have succeeded in two-dimensional layer-by-layer growth of ZnO both on sapphire and GaN, and control of lattice polarity of ZnO films on a Ga-polar GaN template. MgO b…

ZnO doping and propertiesGaN-based semiconductor devices and materialsGa2O3 and related materials

Matrix effect on local structure surrounding Yb3+and spontaneous emission probability in oxide glasses

Tatsunori Murata、K. Mazeno、K. Morinaga2002-01-01Science and Technology of Advanced Materials

Extended X-ray absorption fine structure measurements have been performed on Yb3+ in silicate, borate, phosphate, and gallate glasses in order to investigate the local structures surrounding Yb3+. The local structures of Yb3+ ions in silicate, borate, and phosphate glasses were similar to those of Er3+ ions. Yb3+ ions…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsAdvanced Condensed Matter Physics

The Nature of the Interaction Between Polyaniline and 2,5-Dimercapto-1,3,4-thiadiazole in Electrochemical Redox Processes

Peng Wang2002-01-01Journal of The Electrochemical Society

The interaction between polyaniline (PAn) and 2,5-dimercapto-1,3,4-thiadiazole (DMcT) was investigated by means of cyclic voltammetry and UV-visible spectroscopy. The results show that the polymerization-depolymerization reaction of DMcT or its dilithium salt Li 2 DMcT is a kinetically quasi-reversible process. PAn ex…

Conducting polymers and applicationsElectrochemical Analysis and ApplicationsAnalytical Chemistry and Sensors

Determination of Chemical Diffusion and Surface Exchange Coefficients of Oxygen by Electrochemical Impedance Spectroscopy

Stefan Diethelm、Alexandre Closset、Jan Van herle 等 4 位作者2002-01-01Journal of The Electrochemical Society

A rigorous mathematical model is developed for the complex impedance of a solid-state electrochemical cell, which is commonly used for the measurement of oxygen transport, oxygen exchange kinetics, and thermodynamic properties of nonstoichiometric mixed conducting oxides. The model leads to a simple equivalent circuit…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Thermal Activation Constitutive Model for Polymers Applied to Polytetrafluoroethylene

Frank J. Zerilli2002-01-01AIP conference proceedings

A constitutive model with a thermal activation plastic component combined with a Maxwell‐Weichert linear viscoelastic component was applied to describe the dynamic elastic and plastic stress‐strain behavior of polytetrafluoroethylene as a function of temperature, strain rate, and pressure. The linear viscoelastic comp…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesTribology and Wear Analysis

Applications and commercial products

義治 土肥、A. Steinbüchel2002-01-01Wiley-VCH eBooks

Properties and application of aliphatic polyester products (Masatsugi Mochizuki) Aliphatic polyesters (Ann--Christine Albertson and Indra K. Varma) Biodegradable polyester Biopol(R) (Jawed Asrar and Kenneth J. Gruys) Applications of PHAs in medicine and pharmacy (Simon F. Williams and David P. Martin) Polylactides (Hi…

biodegradable polymer synthesis and propertiesBiopolymer Synthesis and Applications

Deproteination of chrome waste by washing and enzymatic hydrolysis

Jan Růžička、Karel Kolamaznik、J. Kupec 等 5 位作者2002-01-01Journal of the American Leather Chemists Association

Waste from the manufacture of chrome-tanned leathers (so-called shavings) can be processed (apart from alkaline or acid breakdown) by enzymatic hydrolysis employing alkaline proteases. Under mild reaction conditions, a soluble collagen hydrolyzate is formed and a solid fraction (so-called chrome cake) with high chromi…

Protein Hydrolysis and Bioactive PeptidesEnzyme Production and CharacterizationCollagen: Extraction and Characterization