Materials Literature
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Structural modifications in InP(111) due to 1.5 MeV implantation of Sb have been characterized using first-order and second-order Raman spectroscopy. With both longitudinal optical (LO) and transverse optical (TO) modes allowed for InP(111), we have investigated the evolution of both these modes as a function of fluen…
Raman micro/macro-spectroscopy allows for a non-destructive remote analysis: body and glaze, crystalline and amorphous phases can be identified, including the nanosized pigments colouring the glaze. Last generation instruments are portable which allows for examination in museum, on sites, etc. This paper gives an over…
In this paper, we investigate the effect of spatial dispersion on a double-lattice metamaterial which has both magnetic and electric response. A numerical scheme based on a dipolar model is developed to extract the non-local effective medium of the metamaterial. We found a structure-induced bianisotropy near the reson…
Pb(Mg1/3Nb2/3)O3-PbTiO3 solid solution (PMN(1-x)-PTx) ceramics with 0
We report the results of ac and dc magnetic susceptibility (chi), heat-capacity (C), isothermal magnetization and isothermal remanent magnetization measurements on the compound, Sr3CuRhO6, crystallizing in a K4CdCl6-derived monoclinic structure. The magnetization data reveal distinct magnetic anomalies near 6 and 12 K…
Entropy changes in the compounds of La1−xPrxFe11.5Si1.5 (x=0.3 and 0.4) have been experimentally studied. A tower-shaped entropy change of the height of ∼27J∕kgK is obtained based on the analyses of heat capacity, while the Maxwell relation predicts an extra entropy peak of the height of ∼99J∕kgK, slightly varying wit…
Plasma waves in the two-dimensional electron-hole system in a graphene-based heterostructure controlled by a highly conducting gate are studied theoretically. The energy spectra of two-dimensional electrons and holes are assumed to be conical (neutrinolike), i.e., corresponding to their zero effective masses. Using th…
In this paper, the small scaling parameter e0 of the nonlocal Timoshenko beam theory is calibrated for the free vibration problem of single-walled carbon nanotubes (SWCNTs). The calibration exercise is performed by using vibration frequencies generated from molecular dynamics simulations at room temperature. It was fo…
β - Ga 2 O 3 thin films have been prepared on (0001) sapphire substrates by the sol-gel method. X-ray diffraction showed that β-Ga2O3 polycrystalline films were formed at heat-treatment temperatures above 600°C. With increasing heat-treatment temperature above 900°C, the lattice constants of the β-Ga2O3 films decrease…
Stringing them along: The pores of a mesoporous silica particle were filled with guest molecules and then blocked by threading cyclodextrin molecules (CDs) onto the surface-grafted polyethylenimine (PEI) chains at pH 11. At pH 5.5, the guest molecules can be released from the pores of the particle by reversible dethre…
It is fairly well known that rotation in three dimensions can be expressed as a quadratic in a skew symmetric matrix via the Euler-Rodrigues formula. A generalized Euler-Rodrigues polynomial of degree 2n in a skew symmetric generating matrix is derived for the rotation matrix of tensors of order $n$. The Euler-Rodrigu…
p-Conjugated materials, including small molecules and polymers, are attracting substantial attention as novel gain media in semiconductor lasers; they offer many potential advantages not achievable with conventional inorganic semiconductors: simple processing, low cost, easy tuneability of the spectrum, and large-area…
We systematically studied the magnetic and transport properties for the polycrystalline samples of Fe-doped perovskite cobaltites: Pr$_{1-y}$Ca$_{y}$Co$_{1-x}$Fe$_x$O$_3$ ($y$=0.3, $x$=0-0.15; $y$=0.45, $x$=0-0.3) and Gd$_{0.55}$Sr$_{0.45}$Co$_{1-x}$Fe$_x$O$_{3}$ ($x$=0-0.3). Fe doping leads to an enhancement of the f…
Abstract A new photochromic compound of tetraazaporphyrin magnesium(II) appended with eight ferrocene units by ethynyl TPF was synthesized. Its photochromic properties and electrochemical properties were studied. As its redox potential was reversibly changed accompanying the open- and closed-ring photoisomerization of…
The volatilization of radionuclides during the stabilization/solidification of radioactive wastes at high temperatures is one of the major problems to be considered in choosing suitable wasteforms, process, material systems, etc. This paper reports a novel method to convert volatile wastes into nonvolatile compounds v…
A general relationship is derived for the abundance of an imperfect dendrimer with a given number of missing constitutional repeating units in the two outmost layers. The relationship is used in the interpretation of the MALDI TOF mass spectrum of the second-generation carbosilane dendrimer prepared by the iterative d…
OBJECTIVES: Gadolinium complexes are not considered to be a drug class at high risk for prolonging cardiac repolarization, which can lead to potentially life-threatening arrhythmias such as torsade de pointes. However, only limited robust data are available on these compounds despite their extensive use as contrast en…
The structure and viscoelastic properties of an organic-inorganic hybrid system composed of an organically modified polysiloxane network were examined, and the influence of organic groups on elastic-modulus variation by heat treatment was studied. The increase in the number of phenyl (Ph) groups per silicon decelerate…
Polyperoxide, as a new kind of thermally degradable polymer, is synthesized by the radical alternating copolymerization of a 1,3-diene monomer with oxygen. The introduction of polyperoxide units into any other polymer is useful for the fragmentation of polymers and a change in the physical properties of polymeric mate…
The generation of long, mutually oriented nanofibers of functionalized phenylene oligomers is reported for the case of symmetrically 4,4‘ ‘‘-functionalized p -quaterphenylene molecules with chloride groups. Two domains of up to 30 μm long, oriented fibers with nanoscopic widths and heights grow along muscovite mica 〈1…