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Interfacial Oxygen Stabilizes Composite Silicon Anodes

Chuan‐Fu Sun、Hongli Zhu、Morihiro Okada 等 7 位作者2014-12-16Nano Letters

Silicon can store Li(+) at a capacity 10 times that of graphite anodes. However, to harness this remarkable potential for electrical energy storage, one has to address the multifaceted challenge of volume change inherent to high capacity electrode materials. Here, we show that, solely by chemical tailoring of Si-carbo…

Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesConducting polymers and applications

Carboxylation of terminal alkynes with CO 2 catalyzed by bis(amidate) rare-earth metal amides

Hao Cheng、Bei Zhao、Yingming Yao 等 4 位作者2014-12-16Green Chemistry

Three novel bis(amidate) rare-earth metal amides were prepared and characterized. Treatment of CO 2 with terminal alkynes obtained propiolic acids in high to excellent yields using the highest reactive Nd-based catalyst at ambient pressure.

Organometallic Complex Synthesis and Catalysisbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

Remarkable Improvement of Gas-Sensing Abilities in p-type Oxide Nanowires by Local Modification of the Hole-Accumulation Layer

Sun-Woo Choi、Akash Katoch、Jae‐Hun Kim 等 4 位作者2014-12-16ACS Applied Materials & Interfaces

This paper proposes a method for improving the reducing or oxidizing gas-sensing abilities of p-type oxide nanowires (NWs) by locally modifying the hole-accumulation channel through the attachment of p-type nanoparticles (NPs) with different upper valence band levels. In this study, the sensing behaviors of p-CuO NWs…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

Self-Assembly Formation of Lipid Bilayer Coatings on Bare Aluminum Oxide: Overcoming the Force of Interfacial Water

Joshua A. Jackman、Seyed R. Tabaei、Zhilei Zhao 等 5 位作者2014-12-16ACS Applied Materials & Interfaces

Widely used in catalysis and biosensing applications, aluminum oxide has become popular for surface functionalization with biological macromolecules, including lipid bilayer coatings. However, it is difficult to form supported lipid bilayers on aluminum oxide, and current methods require covalent surface modification,…

Lipid Membrane Structure and BehaviorSpectroscopy and Quantum Chemical StudiesSupramolecular Self-Assembly in Materials

Photocatalytic H 2 production under visible-light irradiation based on covalent attachment of manganese phthalocyanine to graphene

Dandan Wang、Jie Huang、Xia Li 等 7 位作者2014-12-16Journal of Materials Chemistry A

In this paper, a manganese phthalocyanine (MnPc) covalently functionalized graphene nanohybrid (MnPcG) has been successfully synthesized via 1,3-dipolar cycloaddition, and used as a photocatalyst after modifying it with platinum nanoparticles via photodeposition.

Advanced Photocatalysis TechniquesGraphene research and applicationsCovalent Organic Framework Applications

Postsynthesis of mesoporous ZSM-5 zeolite by piperidine-assisted desilication and its superior catalytic properties in hydrocarbon cracking

Darui Wang、Lin Zhang、Li Chen 等 5 位作者2014-12-16Journal of Materials Chemistry A

Mesoporous ZSM-5 zeolites with unique hydrocarbon cracking properties have been postsynthesized from conventional ZSM-5 samples using small molecular organic amine-assisted desilication technique.

Catalytic Processes in Materials ScienceZeolite Catalysis and SynthesisMesoporous Materials and Catalysis

Classical and quantum plasmonics in graphene nanodisks: Role of edge states

Thomas Christensen、Weihua Wang、Antti‐Pekka Jauho 等 5 位作者2014-12-16Physical Review B

Edge states are ubiquitous for many condensed matter systems with multicomponent wave functions. For example, edge states play a crucial role in transport in zigzag graphene nanoribbons. Here, we report microscopic calculations of quantum plasmonics in doped graphene nanodisks with zigzag edges. We express the nanodis…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchNonlinear Optical Materials Studies

Synthesis of conjugated polymers via an exclusive direct-arylation coupling reaction: a facile and straightforward way to synthesize thiophene-flanked benzothiadiazole derivatives and their copolymers

Xiaochen Wang、Kai Wang、Mingfeng Wang2014-12-16Polymer Chemistry

Thiophene-flanked benzothiadiazole derivatives and their copolymers were synthesized via exclusive direct-arylation coupling reactions.

Organic Electronics and PhotovoltaicsConducting polymers and applicationsSulfur-Based Synthesis Techniques

Trafficking of Plant Plasma Membrane Aquaporins: Multiple Regulation Levels and Complex Sorting Signals

Adrien S. Chevalier、François Chaumont2014-12-16Plant and Cell Physiology

Aquaporins are small channel proteins which facilitate the diffusion of water and small neutral molecules across biological membranes. Compared with animals, plant genomes encode numerous aquaporins, which display a large variety of subcellular localization patterns. More specifically, plant aquaporins of the plasma m…

Supercapacitor Materials and FabricationPlant nutrient uptake and metabolismPlant Micronutrient Interactions and Effects

Capturing composites manufacturing waste flows through process mapping

Justyna Rybicka、Ashutosh Tiwari、Pedro Alvarez Del Campo 等 4 位作者2014-12-16Journal of Cleaner Production

The necessity of high performance materials has become latent in high technology sectors such as aerospace, automotive, renewable energy, nuclear engineering and sports. The expanding impact on future manufacturing of the EU waste management legislation and increasing price of current waste management methods stress t…

Fiber-reinforced polymer compositesRecycling and Waste Management TechniquesGraphite, nuclear technology, radiation studies

Fluidized Capacitive Bioanode As a Novel Reactor Concept for the Microbial Fuel Cell

Alexandra Deeke、Tom Sleutels、Tim F. W. Donkers 等 6 位作者2014-12-16Environmental Science & Technology

The use of granular electrodes in Microbial Fuel Cells (MFCs) is attractive because granules provide a cost-effective way to create a high electrode surface area, which is essential to achieve high current and power densities. Here, we show a novel reactor design based on capacitive granules: the fluidized capacitive…

Supercapacitor Materials and FabricationElectrochemical sensors and biosensorsMicrobial Fuel Cells and Bioremediation

Wear-Resistant and Antismudge Superoleophobic Coating on Polyethylene Terephthalate Substrate Using SiO2 Nanoparticles

Yongxin Wang、Bharat Bhushan2014-12-16ACS Applied Materials & Interfaces

It is of interest to create superoleophobic surfaces that exhibit high oil contact angle, low contact angle hysteresis, high wear resistance, antismudge properties, and optical transparency for industrial applications. In the superoleophobic surfaces developed to date, the mechanical durability data is lacking. By dip…

Surface Modification and SuperhydrophobicityDiamond and Carbon-based Materials ResearchTribology and Wear Analysis

Quantitative Determination of Ligand Densities on Nanomaterials by X-ray Photoelectron Spectroscopy

Marco D. Torelli、Rebecca A. Putans、Yizheng Tan 等 6 位作者2014-12-16ACS Applied Materials & Interfaces

X-ray photoelectron spectroscopy (XPS) is a nearly universal method for quantitative characterization of both organic and inorganic layers on surfaces. When applied to nanoparticles, the analysis is complicated by the strong curvature of the surface and by the fact that the electron attenuation length can be comparabl…

Semiconductor materials and devicesMolecular Junctions and NanostructuresElectron and X-Ray Spectroscopy Techniques

Preparation and Size Control of Sub-100 nm Pure Nanodrugs

Jinfeng Zhang、Yanan Li、Feifei An 等 6 位作者2014-12-16Nano Letters

Pure nanodrugs (PNDs), nanoparticles consisting entirely of drug molecules, have been considered as promising candidates for next-generation nanodrugs. However, the traditional preparation method via reprecipitation faces critical challenges including low production rates, relatively large particle sizes, and batch-to…

Nanoparticle-Based Drug DeliveryAdvanced biosensing and bioanalysis techniquesRNA Interference and Gene Delivery

Expanding the Dimensionality of Polymers Populated with Organic Robust Radicals toward Flow Cell Application: Synthesis of TEMPO-Crowded Bottlebrush Polymers Using Anionic Polymerization and ROMP

Takashi Sukegawa、Issei Masuko、Kenichi Oyaizu 等 4 位作者2014-12-16Macromolecules

High Resolution Image Download MS PowerPoint Slide Poly(norbornene)- g -poly(4-methacryloyloxy-2,2,6,6-tetramethylpiperidin-1-oxyl) (PNB- g -PTMA) was prepared by a grafting-through approach based on anionic polymerization of 4-methacryloyloxy-2,2,6,6-tetramethylpiperidin-1-oxyl using a norbornene-substituted diphenyl…

Fuel Cells and Related MaterialsConducting polymers and applicationsAdvanced battery technologies research

Photo-Oxidation of Water on Defective Hematite(0001)

Manh‐Thuong Nguyen、Simone Piccinin、Nicola Seriani 等 4 位作者2014-12-16ACS Catalysis

Defects are unavoidable and usually originate exotic properties in realistic materials. One of the most fundamental defect-induced properties of a solid surface is its reactivity to adsorbed species. Defects in anodes of electrochemical cells for water splitting could therefore play a critical role in the interatomic…

Metal Extraction and BioleachingIron oxide chemistry and applicationsCopper-based nanomaterials and applications