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Resistive Switching Memory Based on Bioinspired Natural Solid Polymer Electrolytes

Niloufar Raeis‐Hosseini、Jang‐Sik Lee2014-12-16ACS Nano

A solution-processed, chitosan-based resistive-switching memory device is demonstrated with Pt/Ag-doped chitosan/Ag structure. The memory device shows reproducible and reliable bipolar resistive switching characteristics. A memory device based on natural organic material is a promising device toward the next generatio…

Advanced Memory and Neural ComputingConducting polymers and applicationsNeuroscience and Neural Engineering

Measuring Forces and Spatiotemporal Evolution of Thin Water Films between an Air Bubble and Solid Surfaces of Different Hydrophobicity

Chen Shi、Xin Cui、Lei Xie 等 7 位作者2014-12-16ACS Nano

A combination of atomic force microscopy (AFM) and reflection interference contrast microscopy (RICM) was used to measure simultaneously the interaction force and the spatiotemporal evolution of the thin water film between a bubble in water and mica surfaces with varying degrees of hydrophobicity. Stable films, suppor…

Surface Modification and SuperhydrophobicityFluid Dynamics and MixingMinerals Flotation and Separation Techniques

High-performance semitransparent perovskite solar cells with solution-processed silver nanowires as top electrodes

Fei Guo、Hamed Azimi、Yi Hou 等 10 位作者2014-12-16Nanoscale

In this work, we report efficient semitransparent perovskite solar cells using solution-processed silver nanowires (AgNWs) as top electrodes. A thin layer of zinc oxide nanoparticles is introduced beneath the AgNWs, which fulfills two essential functionalities: it ensures ohmic contact between the PC60BM and the AgNWs…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesConducting polymers and applications

Water-assisted production of honeycomb-like g-C 3 N 4 with ultralong carrier lifetime and outstanding photocatalytic activity

Zhenyu Wang、Wei Guan、Yanjuan Sun 等 6 位作者2014-12-16Nanoscale

Graphitic carbon nitride (g-C3N4) is a visible light photocatalyst, limited by low activity mainly caused by rapid recombination of charge carriers. In the present work, honeycomb-like g-C3N4 was synthesized via thermal condensation of urea with addition of water at 450 °C for 1 h. Prolonging the condensation time cau…

Advanced Photocatalysis TechniquesZnO doping and propertiesPerovskite Materials and Applications

Au Nanorod Helical Superstructures with Designed Chirality

Xiang Lan、Xuxing Lu、Chenqi Shen 等 6 位作者2014-12-16Journal of the American Chemical Society

A great challenge for nanotechnology is to controllably organize anisotropic nanomaterials into well-defined three-dimensional superstructures with customized properties. Here we successfully constructed anisotropic Au nanorod (AuNR) helical superstructures (helices) with tailored chirality in a programmable manner. B…

Advanced biosensing and bioanalysis techniquesMetamaterials and Metasurfaces ApplicationsSupramolecular Self-Assembly in Materials

Eu(III)-Functionalized MIL-124 as Fluorescent Probe for Highly Selectively Sensing Ions and Organic Small Molecules Especially for Fe(III) and Fe(II)

Xiaoyu Xu、Bing Yan2014-12-16ACS Applied Materials & Interfaces

A layerlike MOF (MIL-124, orGa2(OH)4(C9O6H4)) has been prepared and chosen as a parent compound to encapsulate Eu(3+) cations by one uncoordinated carbonyl group in its pores. The Eu(3+)-incorporated sample (Eu(3+)@MIL-124) is fully characterized, which shows excellent luminescence and good fluorescence stability in w…

Metal-Organic Frameworks: Synthesis and ApplicationsMolecular Sensors and Ion DetectionCovalent Organic Framework Applications

A Double Energy Transition of Nanocrystalline CdxZn1-xS Films Deposited by Chemical Bath

J. A. Pescador Rojas、A.I. Oliva2014-12-16Materials and Manufacturing Processes

Ternary films of CdxZn1-xS were deposited on Corning glass substrates by the chemical bath deposition technique at 80°C. A process for depositing thin films of the ternary CdxZn1-xS is proposed. Different induction times in the methodology for films deposition were included. The chemical bath was composed of zinc chlo…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Aggregation Behavior of Rod–Coil–Rod Triblock Copolymers in a Coil-Selective Solvent

Ahmad K. Omar、Ben Hanson、Ryan T. Haws 等 7 位作者2014-12-16The Journal of Physical Chemistry B

Recent experiments have reported that the self-assembly of conjugated polymers mimicking rod-coil-rod triblock copolymers (BCPs) in selective solvents exhibits unique aggregate morphologies. However, the nature of the arrangement of the polymers within the aggregates and the spatial organization of the aggregates rema…

Advanced Polymer Synthesis and CharacterizationSurfactants and Colloidal SystemsBlock Copolymer Self-Assembly

Tuning the spin dynamics of single molecule magnets via dipolar interactions

Andrea Hofmann、Z. Salman2014-12-16Journal of Physics Conference Series

We present calculations of the dipolar field distribution acting on a single molecule magnet due to its neighbours in thin films. The calculations are presented for different packing/configuration scenarios, with different easy axis orientations. The potential for controlling the molecular spin dynamics by tuning the…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Hydrogen storage in Ti, V and their oxides-based thin films

Z. Tarnawski、K. Zakrzewska、N.-T.H. Kim-Ngan 等 8 位作者2014-12-16Advances in Natural Sciences Nanoscience and Nanotechnology

We have investigated the hydrogen storage ability and the effect of hydrogenation on structure and physical properties of Ti/V and their oxides-based thin films. A series of Ti–TiO 2 and VO x –TiO 2 thin films with different layer structures, geometries and thicknesses have been prepared by the sputtering technique on…

ZnO doping and propertiesCatalytic Processes in Materials ScienceTransition Metal Oxide Nanomaterials

Effect of nanoadditives on the kinetics of CaSO4 · 2H2O formation and the mosaic structure of crystals

V. A. Tyumentsev、A. G. Fazlitdinova、D. V. Dozhdikova 等 4 位作者2014-12-16Inorganic Materials

The effect of nanoadditives on the fine structure and formation kinetics of CaSO 4 · 2H 2 O crystals has been studied by X-ray diffraction and scanning electron microscopy. The results demonstrate that the formation of gypsum dihydrate occurred most actively in a material containing microadditions of nanotubes. The ca…

Calcium Carbonate Crystallization and InhibitionMinerals Flotation and Separation TechniquesCrystallization and Solubility Studies

Nanocapsules for 5-fluorouracil delivery decorated with a poly(2-ethylhexyl methacrylate-co-7-(4-trifluoromethyl)coumarin acrylamide) cross-linked wall

Małgorzata Sierant、Sławomir Kaźmierski、A. Rozanski 等 6 位作者2014-12-16New Journal of Chemistry

Nanocapsules with reverse cross-linked polymer walls containing coumarin moieties are capable of encapsulating 5-fluorouracil and accomplishing a comprehensive strategy in a drug delivery system.

Mesoporous Materials and CatalysisSynthetic Organic Chemistry MethodsSynthesis and properties of polymers

Asp48 function in the hydrogen-bonding network involving Asp52 of hen egg-white lysozyme

Yuya Kawaguchi、Kazunari Yoneda、Takao Torikata 等 4 位作者2014-12-16Bioscience Biotechnology and Biochemistry

To characterize the hydrogen-bonding network in lysozyme, we focused on the residue of Asp48 located at the active site in hen egg-white lysozyme. We constructed a mutant lysozyme (D48A) and analyzed using (GlcNAc)3 and chitin-affinity chromatography. The substrate binding of subsites D-F in D48A and the activity agai…

Protein Structure and DynamicsGlycosylation and Glycoproteins ResearchEnzyme Structure and Function

Carrier-dependent magnetic anisotropy of cobalt doped titanium dioxide

Bin Shao、Min Feng、Xu Zuo2014-12-16Scientific Reports

Using first-principles calculations, we predict that the magnetic anisotropy energy of Co-doped TiO2 sensitively depends on carrier accumulation. This magnetoelectric phenomenon provides a potential route to a direct manipulation of the magnetization direction in diluted magnetic semiconductor by external electric-fie…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Structure cristalline de type alluaudite KNa5Mn3(MoO4)6

Chahira Bouzidi、Wafa Frigui、Mohamed Faouzi Zid2014-12-16Acta Crystallographica Section E Crystallographic Communications

The new phase potassium penta-sodium trimanganese hexa-kis(molybdate), KNa5Mn3Mo6O24, has been synthesized using solid-state methods. The structure is composed of M 2O10 (M = Mn, Na) dimers and MoO4 tetra-hedra (point group symmetry 2) sharing corners and forming layers parallel to (100), which are linked via common c…

Metal-Organic Frameworks: Synthesis and ApplicationsCrystal Structures and PropertiesPolyoxometalates: Synthesis and Applications

Enhancing ionic conductivity in lithium amide for improved energy storage materials

Rosalind A. Davies、David R. Hewett、Paul A. Anderson2014-12-16Advances in Natural Sciences Nanoscience and Nanotechnology

Non-stoichiometry and bulk cation transport have been identified as key factors in the release and uptake of hydrogen in the Li–N–H system. Amide halide phases have been synthesized that have ionic conductivities several orders of magnitude greater than lithium amide, a faster rate of hydrogen release and elimination…

Advanced Battery Materials and TechnologiesHydrogen Storage and MaterialsAmmonia Synthesis and Nitrogen Reduction

Nuclear quantum effects in a 1-D model of hydrogen bonded ferroelectrics

Kjartan Thor Wikfeldt2014-12-16Journal of Physics Conference Series

A one dimensional model of a coupled hydrogen (H) bonding chain is developed and parametrized to density functional theory (DFT) calculations on squaric acid, a prototypical H-bonded antiferroelectric crystal. The energetics of single and collective proton jumps and its dependence on H-bond length, as obtained by DFT,…

Crystallography and molecular interactionsAdvanced NMR Techniques and ApplicationsSolid-state spectroscopy and crystallography

Effects of Chemical Structure of Phenolic Resin on Damping Properties of Acrylate Rubber-Based Blends

Chang Su、Cunbin Zhao、Lihuan Xu 等 4 位作者2014-12-16Journal of Macromolecular Science Part B

Two types of acrylate rubber (AR)-based damping blends were prepared by using two types of phenolic resins (PF), a resole resin (RR) and a novolac resin (NR), as organic fillers. The structure and damping properties of the AR/RR and AR/NR blends obtained by hot-pressing were characterized and compared by Fourier trans…

Polymer Nanocomposites and PropertiesPolymer composites and self-healingTribology and Wear Analysis

QD-Salt Mixed Crystals: the Influence of Salt-Type, Free-Stabilizer, and pH

Marcus Adam、Remo Tietze、Nikolai Gaponik 等 4 位作者2014-12-16Zeitschrift für Physikalische Chemie

Abstract Colloidal quantum dots (QDs) bear a huge potential in different application fields due to their unique properties. Unfortunately, their limited stability against environmental influences and the limited processability of the colloidal solutions restricts, among other factors, their widespread implementation.…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Synthesis of cyclopentyloxy terphenyl liquid crystals with negative dielectric anisotropy

Tien-Hsin Lee、Jiun‐Tai Chen、Chain‐Shu Hsu2014-12-16Liquid Crystals

Liquid crystalline materials possessing negative dielectric anisotropy (Δε) have attracted considerable attention because they can be used to formulate eutectic mixture for several display applications. The negative Δε can be achieved by introducing a lateral polar substituent onto the mesogen core of a liquid crystal…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsSynthesis and properties of polymers