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Massively Sub-wavelength Guiding of Electromagnetic Waves

Ian R. Hooper、Ben Tremain、Joseph A. Dockrey 等 4 位作者2014-12-16Scientific Reports

Recently a new form of ultra-thin flexible waveguide consisting of a conducting comb-like structure with a thickness of the order of 1/600(th) of the operating wavelength was presented. However, whilst the thickness of the guide was massively sub-wavelength, the remaining dimensions (the height and period of the comb)…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchPhotonic Crystals and Applications

Acquired Superoxide‐Scavenging Ability of Ceria Nanoparticles

Yuanyuan Li、Xiao He、Jun‐Jie Yin 等 11 位作者2014-12-16Angewandte Chemie

Abstract Ceria nanoparticles (nanoceria) are well known as a superoxide scavenger. However, inherent superoxide‐scavenging ability has only been found in the nanoceria with sizes of less than 5 nm and with very limited shape diversity. Reported herein is a strategy to significantly improve the superoxide‐scavenging ac…

Electrochemical sensors and biosensorsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Self-Organization of Colloidal PbS Quantum Dots into Highly Ordered Superlattices

А. В. Баранов、Elena V. Ushakova、Valery V. Golubkov 等 7 位作者2014-12-16Langmuir

X-ray structural analysis, together with steady-state and transient optical spectroscopy, is used for studying the morphology and optical properties of quantum dot superlattices (QDSLs) formed on glass substrates by the self-organization of PbS quantum dots with a variety of surface ligands. The diameter of the PbS QD…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Triplet–Triplet Excitation Transfer in Palladium Porphyrin–Fullerene and Platinum Porphyrin–Fullerene Dyads

Christopher O. Obondi、Gary N. Lim、Francis D’Souza2014-12-16The Journal of Physical Chemistry C

Covalently linked donor–acceptor dyads involving palladium(II) and platinum(II) porphyrins as triplet sensitizers and fullerene as an acceptor have been newly synthesized. These dyads were characterized by optical absorbance, emission, and electrochemical methods. In contrast to the earlier reported zinc(II) porphyrin…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesLuminescence and Fluorescent Materials

A general method for the fabrication of graphene–nanoparticle hybrid material

Jaehyeung Park、H. Surangi N. Jayawardena、Xuan Chen 等 7 位作者2014-12-16Chemical Communications

We describe a simple and general approach to conjugate nanoparticles on pristine graphene. The method takes advantage of the high reactivity of perfluorophenyl nitrene towards the C[double bond, length as m-dash]C bonds in graphene, where perfluorophenyl azide-functionalized nanoparticles are conjugated to pristine gr…

Advancements in Battery MaterialsGraphene research and applicationsGraphene and Nanomaterials Applications

Fabrication of Chitin/Poly(butylene succinate)/Chondroitin Sulfate Nanoparticles Ternary Composite Hydrogel Scaffold for Skin Tissue Engineering

S. Deepthi、C. Sidhy Viha、Thitirat Chaochai 等 6 位作者2014-12-16Polymers

Skin loss is one of the oldest and still not totally resolved problems in the medical field. Since spontaneous healing of the dermal defects would not occur, the regeneration of full thickness of skin requires skin substitutes. Tissue engineering constructs would provide a three dimensional matrix for the reconstructi…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsWound Healing and Treatments

Enhanced Ferromagnetism in a Mn 3 C 12 N 12 H 12 Sheet

Junyi Liu、Qiang Sun2014-12-16ChemPhysChem

Based on a recent experimental study on the Ni3 C12 S12 sheet [J. Am. Chem. Soc. 2013, 135, 2462] and a theoretical study on the Mn3 C12 S12 sheet [Nanoscale- 2013, 5, 10404], by using density functional theory combined with a thermodynamic model, it is shown that when sulfur atoms are replaced by NH groups the resu…

2D Materials and ApplicationsBoron and Carbon Nanomaterials ResearchMXene and MAX Phase Materials

Hydrothermal/Solvothermal Crystal Growth: an Old but Adaptable Process

G. Demazeau、Alain Largeteau2014-12-16Zeitschrift für anorganische und allgemeine Chemie

Abstract Hydrothermal crystal growth can be described as a low temperature process under pressure using an aqueous solution as the solvent. The temperature gradient controls the transport phenomenon from the nutrient to the seeds. The solvothermal term is generally used when the solvent is a non‐aqueous solution. Diff…

Solidification and crystal growth phenomenaCrystallization and Solubility Studiesnanoparticles nucleation surface interactions

How Solid–Liquid Adhesive Property Regulates Liquid Slippage on Solid Surfaces?

Yahui Xue、Yang Wu、Xiaowei Pei 等 6 位作者2014-12-16Langmuir

The influence of solid-liquid adhesive property on liquid slippage at solid surfaces has been investigated using experiment approach on well-defined model surfaces as well as theoretical analysis. Based on a classical molecular-kinetic description for molecular and hydrodynamic slip, we propose a simple theoretical mo…

Surface Modification and SuperhydrophobicityMolecular Junctions and NanostructuresAdhesion, Friction, and Surface Interactions

Topological Effects on Globular Protein‐ELP Fusion Block Copolymer Self‐Assembly

Guokui Qin、Matthew Glassman、Christopher N. Lam 等 7 位作者2014-12-16Advanced Functional Materials

Perfectly defined, monodisperse fusion protein block copolymers of a thermoresponsive coil‐like protein, ELP, and a globular protein, mCherry, are demonstrated to act as fully biosynthetic analogues to protein‐polymer conjugates that can self‐assemble into biofunctional nanostructures such as hexagonal and lamellar ph…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesBlock Copolymer Self-Assembly

Preparation, Polymerization, and Performance Evaluation of Halogen-Free Radiation Curable Flame Retardant Monomers for Cotton Substrates

Brian Edwards、Stacy Michelle Rudolf、Peter J. Hauser 等 4 位作者2014-12-16Industrial & Engineering Chemistry Research

Three halogen-free, phosphorus-based flame retardant monomers were synthesized with good yields and characterized using FT-IR, 1 H NMR, and 31 P NMR. Two of the monomers were novel phosphoramides and the third was derived from cyclotriphosphazene. Each monomer was coated onto cotton substrates with the aid of a UV flo…

Fire dynamics and safety researchFlame retardant materials and propertiesEnvironmental and Industrial Safety

Synthesis and Catalytic Activity of Crown Jewel‐Structured (IrPd)/Au Trimetallic Nanoclusters

Haijun Zhang、Lilin Lu、Keisuke Kawashima 等 6 位作者2014-12-16Advanced Materials

Crown-jewel-structured (IrPd)/Au trimetallic nanoclusters are prepared by a galvanic replacement reaction using Ir/Pd nanoclusters with a structure of Ir rich in the core and Pd rich in the shell as mother clusters. The catalytic activity of the top Au atoms for aerobic glucose oxidation of the trimetallic nanocluster…

Gold and Silver Nanoparticles Synthesis and ApplicationsCatalytic Processes in Materials ScienceNanocluster Synthesis and Applications

Differences in physicochemical properties to consider in the design, evaluation and choice between microparticles and nanoparticles for drug delivery

Daniel P. Otto、Anja Otto、Melgardt M. de Villiers2014-12-16Expert Opinion on Drug Delivery

INTRODUCTION: The increase in the development of novel nanoparticle drug delivery systems makes the choice between micro- and nanoscale drug delivery systems ubiquitous. Changes in physical and chemical properties between micro- to nanosized particles give them different properties that influence their physiological,…

Nanoparticle-Based Drug DeliveryDrug Solubulity and Delivery SystemsAdvanced Drug Delivery Systems

Facile method of preparation of PbS films for NO 2 detection

S.T. Navale、D.K. Bandgar、M. A. Chougule 等 4 位作者2014-12-16RSC Advances

A simple and inexpensive chemical bath deposition method was employed for the preparation of lead sulfide (PbS) thin films.

Quantum Dots Synthesis And PropertiesGas Sensing Nanomaterials and SensorsChalcogenide Semiconductor Thin Films

Stability of BN/metal interfaces in gaseous atmosphere

Yang Yang、Qiang Fu、Mingming Wei 等 5 位作者2014-12-16Nano Research

Hexagonal boron nitride (h-BN) is often prepared by epitaxial growth on metals, and stability of the formed BN/metal interfaces in gaseous environment is a key issue for physicochemical properties of the BN overlayers. As an illustration here, the structural change of a BN/Ru(0001) interface upon exposure to O2 has be…

Graphene research and applications2D Materials and ApplicationsDiamond and Carbon-based Materials Research

Conducting Polymer Transistors Making Use of Activated Carbon Gate Electrodes

Hao Tang、Prajwal Kumar、Shiming Zhang 等 8 位作者2014-12-16ACS Applied Materials & Interfaces

The characteristics of the gate electrode have significant effects on the behavior of organic electrochemical transistors (OECTs), which are intensively investigated for applications in the booming field of organic bioelectronics. In this work, high specific surface area activated carbon (AC) was used as gate electrod…

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

Photoluminescent carbon–nitrogen quantum dots as efficient electrocatalysts for oxygen reduction

Jianhua Shen、Yunfeng Li、Yunhe Su 等 7 位作者2014-12-16Nanoscale

Here, we demonstrate novel carbon-nitrogen quantum dots (CNQDs) by the hydrothermal method using melamine and glutaraldehyde. CNQDs are uniformly dispersed with particle diameters of 3-8 nm. These prepared CNQDs show excellent luminescence properties and the photoluminescent quantum yields of CNQDs with 365 nm emissio…

Electrocatalysts for Energy ConversionAdvanced Photocatalysis TechniquesCarbon and Quantum Dots Applications

Textural and Chemical Properties of Activated Carbon Prepared from Tropical Peat Soil by Chemical Activation Method

Tumirah Khadiran、Mohd Zobir Hussein、Zulkarnain Zainal 等 4 位作者2014-12-16BioResources

Activated carbon (AC) was produced via phosphoric acid (H3PO4) and zinc chloride (ZnCl2) chemical activation methods at 500 °C for 3 h. Tropical peat soil was used as a carbon precursor. The effects of activating agent concentrations on the microstructure and chemical properties of activated carbon were studied. Activ…

Adsorption and biosorption for pollutant removalSupercapacitor Materials and FabricationClay minerals and soil interactions