Materials Literature
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The development of a descriptor or descriptors that can relate the activity of catalysts to their physical properties is a major objective of catalysis research. In this study, we have found that the apparent activation energy for propene oxidation to acrolein over scheelite-structured, multicomponent, mixed metal oxi…
Through periodic density functional theory (DFT) calculations we have investigated the catalytic mechanism of CO oxidation on an Ir 1 /FeO x single-atom catalyst (SAC). The rate-determining step in the catalytic cycle of CO oxidation is shown to be the formation of the second CO 2 between the adsorbed CO on the surfac…
The first bulk electron-transfer photochromic compound with intrinsic second-order nonlinear optical (NLO) photoswitching properties has been synthesized. This system employs an electron-transfer photoactive asymmetric viologen ligand coordinated to a zinc(II) center.
Uniquely in Cu2OSeO3, the Skyrmions, which are topologically protected magnetic spin vortexlike objects, display a magnetoelectric coupling and can be manipulated by externally applied electric (E) fields. Here, we explore the E-field coupling to the magnetoelectric Skyrmion lattice phase, and study the response using…
During the last several years, various chemical methods have been used for synthesis of a variety of metal nanoparticles. Most of these methods pose severe environmental problems and biological risks; therefore the present study reports a biological route for synthesis of zinc oxide nanoparticles using Pseudomonas aer…
It is commonly observed that hydrophobic molecules alone cannot self-assemble into stable nanoparticles, requiring amphiphilic or ionic materials to support nanoparticle stability and function in vivo. We report herein newly self-assembled nanomedicines through entirely different mechanisms. We present proof-of-concep…
The pyrochlore solid solution (Na(0.33)Ce(0.67))2(Ir(1-x)Ru(x))2O7 (0≤x≤1), containing B-site Ru(IV) and Ir(IV) is prepared by hydrothermal synthesis and used as a catalyst layer for electrochemical oxygen evolution from water at pH<7. The materials have atomically mixed Ru and Ir and their nanocrystalline form allows…
Novel β-NaGdF4/Na(Gd,Yb)F4:Er/NaYF4:Yb/NaNdF4:Yb core/shell 1/shell 2/shell 3 (C/S1/S2/S3) multi-shell nanocrystals (NCs) have been synthesized and used as probes for in vivo imaging. They can be excited by near-infrared (800 nm) radiation and emit short-wavelength infrared (SWIR, 1525 nm) radiation. Excitation at 800…
Black phosphorus exhibits a high degree of band anisotropy. However, we find that its in-plane static screening remains relatively isotropic for momenta relevant to elastic long-range scattering processes. On the other hand, the collective electronic excitations in the system exhibit a strong anisotropy. Band nonparab…
Phosphorene is a new family member of two-dimensional materials. We observed strong and highly layer-dependent photoluminescence in few-layer phosphorene (two to five layers). The results confirmed the theoretical prediction that few-layer phosphorene has a direct and layer-sensitive band gap. We also demonstrated tha…
Large differences in the refractive index between semiconductors (Si, GaAs, etc.) and air produces considerable Fresnel loss, which can seriously hinder the absorption of sunlight by photovoltaic solar cells. This study presents a cost-effective roller nanoimprinting technique for the fabrication of sub-wavelength str…
Electrospinning is a fascinating technique to fabricate micro- to nano-scale fibers from a wide variety of materials. For biopolymers, molecular entanglement of the constituent polymers in the spinning dope was found to be an essential prerequisite for successful electrospinning. Rheology is a powerful tool to probe t…
In the present study, sulfide glass xNa2S-(100–x)P2S5, 35 ≤ x ≤ 55 has been synthesized by the melt quenched technique. All the glass samples are characterized by x-ray diffraction (XRD), differential thermal analysis (DTA), dilatometery, and impedance spectroscopy. The XRD pattern of a sample showing a broad halo ind…
The present investigation demonstrates the formation of silver nanoparticles by the reduction of the aqueous silver metal ions during exposure to the Lagenaria siceraria leaf extract. The synthesized AgNPs have characterized by UV-visible spectroscopy, X-ray diffraction (XRD) and Fourier transform infrared spectroscop…
The present paper reports the oxidative etching of Au nanospheres by an oxidant, KMnO4, which resulted in the formation of new particles of different reduced sizes from single starting nanoparticles. The significant blue-shifting (536 → 527 nm) of the surface plasmon band for Au nanospheres was observed due to their s…
Packing frustration for confined fluids, i.e., the incompatibility between the preferred packing of the fluid particles and the packing constraints imposed by the confining surfaces, is studied for a dense hard-sphere fluid confined between planar hard surfaces at short separations. The detailed mechanism for the frus…
The interactions of various acyclic and cyclic hydrocarbons in both saturated and unsaturated forms with the carbon nanostructures (CNSs) have been explored by using density functional theory (DFT) calculations. Model systems representing armchair and zigzag carbon nanotubes (CNTs) and graphene have been considered to…
The large-scale production of high-quality carbon nanomaterials is highly desirable for a variety of applications. We demonstrate a novel synthetic route to the production of fluorescent carbon nanoparticles (CNPs) in large quantities via a single-step reaction. The simple heating of a mixture of benzaldehyde, ethanol…
The plasmon–exciton couplings in a Ag nanoshell with a semiconductor CuCl core (CuCl–Ag) have been studied theoretically. By changing the geometry of the CuCl–Ag nanoshell, the antisymmetric dipole mode (ω+|1) in the outer Ag shell can be tuned through the exciton resonance (ωe) of the…
The calibration of high-energy X-ray diffraction setups using an area detector and a rotation axis is discussed. The characterization of the tilt and spatial distortions of an area detector was discussed in part one of this series [Borbély, Renversade, Kenesei & Wright (2014). J. Appl. Cryst. 47 , 1042–1053]. Part…