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Elemental Solvothermal Reaction To Produce Ternary Semiconductor CuInE2 (E = S, Se) Nanorods

Yang Jiang、Yue Wu、Xiao Mo 等 6 位作者2000-06-21Inorganic Chemistry

A simple and convenient solvothermal process has been developed for the preparation of CuInE2 (E = S, Se) nanorods from the elements in ethylenediamine at 280 °C. Liquid In and the strong capacity of ethylenediamine were found to play important roles in the nanorod growth and electron-transfer process.

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Unexpected properties of the first excited state of non-bipartite Heisenberg spin rings

J. Schnack2000-06-21arXiv

Systematic properties of the first excited state are presented for various ring sizes and spin quantum numbers which are only partly covered by the theorem of Lieb, Schultz and Mattis. For odd ring sizes the first excited energy eigenvalue shows unexpected degeneracy and related shift quantum numbers. As a byproduct t…

Materials Science

Structure and Photophysics of Semiconductor Nanocrystals

Alexander Eychmüller2000-06-21OpenAlex

Nanoparticle research is still a rapidly growing field of science. Semiconductor nanocrystals of a large variety of compositions have been prepared in exceedingly good quality. State-of-the-art preparations and standard characterization methods are discussed. The build-up of more complex nanoheterostructures is report…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

A Copper Germanate Containing Potassium in Its Two-Dimensional Channel Network

Ángeles Monge、Enrique Gutiérrez‐Puebla、C. Cascales 等 4 位作者2000-06-20Chemistry of Materials

Single crystals of the new copper(II) germanate K 2 Cu 3 Ge 5 O 14 have been grown. Conditions for the synthesis are reported. The crystal structure of this material has been established by single-crystal X-ray diffraction: triclinic, space group P 1̄ a = 6.1859(4) Å, b = 7.1484(5) Å, c = 7.8491(5) Å, α = 82.150(1)°,…

Zeolite Catalysis and SynthesisCrystal Structures and PropertiesChemical Synthesis and Characterization

Ternary blends of high-density polyethylene-polystyrene-poly(ethylene/butylene-b-styrene) copolymers: Properties and orientation behavior in plane-strain compression

Z. Bartczak、Andrzej Gałęski、M. Pluta2000-06-20Journal of Applied Polymer Science

Ternary blends of high-density polyethylene (HDPE) with atactic polystyrene (PS) and styrene–ethylene/butylene–styrene block copolymer (SEBS) were deformed by plane–strain compression in a channel die. The samples were deformed up to the true strain of 1.8 (compression ratio of 6) at 100°C. Thermal and mechanical prop…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesComposite Material Mechanics

A semiempirical model for predicting biodegradation profiles of individual polymers in starch-poly- (?-hydroxybutyrate-co-?-hydroxyvalerate) bioplastic

Sherald H. Gordon、S. H. Imam、Randal L. Shogren 等 5 位作者2000-06-20Journal of Applied Polymer Science

Plastic prepared from formulations of cornstarch and poly(β-hydroxybutyrate-co-β-hydroxyvalerate) (PHBV) biodegraded in tropical coastal waters. Biodegradation was monitored for 1 year. Starch—PHBV bioplastic appeared to lose weight in two overlapping phases until both biopolymers were entirely consumed. To examine th…

Nanocomposite Films for Food Packagingbiodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

Investigating the effects of polymer chemistry on activity of biocatalytic plastic materials

Scott J. Novick、Jonathan S. Dordick2000-06-20Biotechnology and Bioengineering

The affects of polymer chemistry on the organic solvent activity of alpha-chymotrypsin-containing biocatalytic plastic materials are investigated in this study. To incorporate alpha-chymotrypsin into the polymer, the enzyme is first acryloylated, then solubilized into organic solvents via hydrophobic ion paring with s…

Enzyme Catalysis and Immobilizationbiodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

Effective thermal conductivity of three-phase styrene butadiene composites

Richa Agrawal、N. S. Saxena、George Mathew 等 5 位作者2000-06-20Journal of Applied Polymer Science

Transient plane source technique was used for the simultaneous measurement of thermal conductivity and thermal diffisivity of three-phase styrene butadiene rubber composites. Two series of styrene butadiene rubber composites were studied, having natural rubber as a variable filler in both the composites along with 10…

Nanofluid Flow and Heat TransferPhase Change Materials ResearchThermal properties of materials

Study on in situ reinforcing and toughening of a semiflexible thermotropic copolyesteramide in PBT/PA66 blends

Xiaolin Xie、S. C. Tjong、Robert K.Y. Li2000-06-20Journal of Applied Polymer Science

Ternary in situ composites based on poly(butylene terephthalate) (PBT), polyamide 66 (PA66), and semixflexible liquid crystalline polymer (LCP) were systematically investigated. The LCP used was an ABA30/PET liquid crystalline copolyesteramide based on 30 mol % of p-aminobenzoic acid (ABA) and 70 mol % of poly(ethylen…

Liquid Crystal Research AdvancementsPolymer crystallization and propertiesSynthesis and properties of polymers

Trivalent Ion Conduction in Molybdates Having Sc2(WO4)3-Type Structure

Nobuhito Imanaka、Tomohiro Ueda、Yusuke Okazaki 等 5 位作者2000-06-20Chemistry of Materials

A molybdate series with Sc 2 (WO 4 ) 3 -type structure, which has been demonstrated to be suitable for trivalent ion conduction, was prepared, and the trivalent ion conducting characteristics of this series were compared with those of the tungstate series. The ionic conductivities of the molybdate series become consid…

Advanced Battery Materials and TechnologiesAdvancements in Solid Oxide Fuel CellsThermal Expansion and Ionic Conductivity

Structure−Property Correlations in Lithium Phosphate Glasses: New Insights from 31P ↔ 7Li Double-Resonance NMR

Leo van Wüllen、Hellmut Eckert、Georg Schwering2000-06-20Chemistry of Materials

The macroscopic properties of binary alkali phosphate glasses are characterized by the presence of unexpected minima in the glass transition temperatures at alkali concentrations near 20−25 mol %. In the present study, the structural origin of this behavior is explored on the basis of multinuclear single- and double-r…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsLanthanide and Transition Metal Complexes

Supramolecular Photophysics of Self-Assembled Block Copolymers Containing Luminescent Conjugated Polymers

Samson A. Jenekhe、X. Linda Chen2000-06-20The Journal of Physical Chemistry B

Luminescent micellar aggregates and spherical vesicles self-assembled from polyquinoline−polystyrene diblock and polyquinoline−polystyrene−polyquinoline triblock copolymers were investigated by photoluminescence excitation and emission spectroscopies and fluorescence microscopy. In both the diblock micelles and triblo…

Supramolecular Chemistry and ComplexesLuminescence and Fluorescent MaterialsSynthesis and Properties of Aromatic Compounds

Quantitative characterization of interfaces in rubber-rubber blends by means of modulated-temperature DSC

D. J. Hourston、Mo Song2000-06-20Journal of Applied Polymer Science

Rubber–rubber blends are used widely in industry, for example, in tire manufacture. It is often difficult to characterize interfaces in such rubber–rubber blends quantitatively because of the similarity in the chemical structure of the component rubbers. Here, a new method was suggested for the measurement of the weig…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesRheology and Fluid Dynamics Studies

Mg–Mn–Al FERRITES FOR HIGH FREQUENCY APPLICATIONS

M. Singh、S.P. Sud2000-06-20Modern Physics Letters B

The effect of substitution of nonmagnetic Al 3+ ions on the electrical and magnetic properties of Mg–Mn ferrites was studied in the ferrite series Mg 0.9 Mn 0.1 Al x Fe 2-x O 4 where x varied from 0–0.5 in steps of 0.1. The incorporation of Al 3+ ions in place of Fe 3+ ions results in a decrease of the lattice paramet…

Multiferroics and related materialsMagnetic Properties and Synthesis of FerritesElectromagnetic wave absorption materials

Physical Characterization of Electrochemically and Chemically Synthesized Polypyrroles

Jin Joo、J. K. Lee、Sang‐Yun Lee 等 6 位作者2000-06-20Macromolecules

The results of temperature-dependent dc conductivity, EPR magnetic susceptibility, and X-ray photoelectron spectroscopy (XPS) experiments are compared for electrochemically and chemically synthesized polypyrrole (PPy) samples. For chemically synthesized PPy samples soluble in organic solvent with large size dopants su…

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

Macroscopic quantum coherence in antiferromagnetic molecular magnets

Hui Hu、Rong Lü、Jia-Ling Zhu 等 4 位作者2000-06-20arXiv

The macroscopic quantum coherence in a biaxial antiferromagnetic molecular magnet in the presence of magnetic field acting parallel to its hard anisotropy axis is studied within the two-sublattice model. On the basis of instanton technique in the spin-coherent-state path-integral representation, both the rigorous Went…

Mesoscale and Nanoscale PhysicsMaterials Science

The Revised Quantum Mechanical Theory of the Optical Activity of Crystals

I. Vysin、J. Riha2000-06-20arXiv

In this paper we present the revised view on the optical activity of crystals based on the model of two dumped coupled oscillators. The results are compared with the results of the same problem solved before and it is presented that the results of the quantum mechanical model are the generalization of the classical mo…

Materials Science

Distance-depending electron-phonon interactions

Marcello Acquarone、Canio Noce2000-06-20arXiv

For a dimer with a non-degenerate orbital built from atomic wave functions of Gaussian shape we evaluate all the electron-phonon couplings derived from the one-body and two-body electronic interactions, considering both the adiabatic and extreme non-adiabatic limit. Not only the values of the coupling parameters in th…

Materials ScienceStrongly Correlated Electrons

Surface modification of poly(tetrafluoroethylene) film by chemical etching, plasma, and ion beam treatments

Sung Reul Kim2000-06-20Journal of Applied Polymer Science

Chemical etching, plasma, and ion beam treatments were used to modify the surface of Polytetrafluoroethylene (PTFE). Each surface treatment method developed different surface characteristics. In addition to morphological observation, contact angle, atomic chemical composition, and adhesion strength were measured after…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchPolymer Nanocomposite Synthesis and Irradiation

Field induced long-range-ordering in an S=1 quasi-one-dimensional Heisenberg antiferromagnet

Z. Honda、K. Katsumata、Y. Nishiyama 等 4 位作者2000-06-20arXiv

We have measured the heat capacity and magnetization of the spin one one-dimensional Heisenberg antiferromagnet NDMAP and constructed a magnetic field versus temperature phase diagram. We found a field induced long-range magnetic ordering. We have been successful in explaining the phase diagram theoretically.

Materials Science