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Observation of metal–insulator transition in Al–Pd–Re quasicrystals by x-ray absorption and photoemission spectroscopy

Y. Y. Lay、J. C. Jan、J. W. Chiou 等 12 位作者2003-03-27Applied Physics Letters

Using x-ray absorption and valence-band photoelectron spectroscopy (PES) we investigated the electronic structures of icosahedral (i)-Al70Pd22.5Re7.5 quasicrystals (QCs) with a 4.2 K/300 K resistivity ratio, r, ranging from 8.3 to 107 obtained under various annealing conditions. Our Al K- and Pd L3-edge x-ray absorpti…

Quasicrystal Structures and PropertiesX-ray Diffraction in CrystallographyMineralogy and Gemology Studies

Coalescence Extraction – A Benign Extraction Tool

Achim Schaadt、H.‐J. Bart2003-03-27Chemical Engineering & Technology

Abstract This paper deals with ‘Coalescence Extraction’, in which no intensive mixing is required. It is based on the use of a primary solvent, which, in combination with the feed, forms a homogeneous solution. This homogeneous phase has enormous potential for the treatment of cell fragments and other highly viscous m…

Aluminum Alloy Microstructure PropertiesSolidification and crystal growth phenomenaCrystallization and Solubility Studies

Catalytic Oxidation of Liquid Methanol as a Heat Source for an Automotive Reformer

Bârd Lindström、Lars J. Pettersson2003-03-27Chemical Engineering & Technology

Abstract A reactor for catalytically oxidizing liquid methanol has been developed for supplying heat to an automotive reformer. In the tests presented in this paper we show that it is possible to catalytically combust liquid methanol by dispersing the methanol and air by a nebulizer over the catalysts. In the experime…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingHydrogen Storage and Materials

The effect of common gases on nucleation of metal islands: The role of oxygen in Ag(100) homoepitaxy

A. R. Layson、James W. Evans、V. Fournée 等 4 位作者2003-03-27The Journal of Chemical Physics

Preexposure to molecular oxygen gas, O2,g, can have a strong effect on the nucleation and growth of Ag islands on Ag(100) at 250 K. At this temperature, molecular oxygen dissociates efficiently at kink sites on steps. Subsequent deposition of Ag produces a far lower density of Agad islands than without oxygen. There i…

ZnO doping and propertiesCatalytic Processes in Materials Sciencenanoparticles nucleation surface interactions

Novel Synthetic Approach to the 8,10-Dimethyl anti-syn-anti-Perhydrophenanthrene Skeleton

Don M. Coltart、Samuel J. Danishefsky2003-03-27Organic Letters

[reaction: see text] An efficient and highly stereocontrolled approach to the 8,10-dimethyl anti-syn-anti-perhydrophenanthrene carbon skeleton starting with the Wieland-Miescher ketone is described. The approach centers on a Diels-Alder-angular methylation-deoxygenation sequence.

Chemical synthesis and alkaloidsPhytochemistry and Bioactive CompoundsAdvanced Synthetic Organic Chemistry

Dielectric relaxation of shallow donor in polycrystalline Mn-doped ZnO

Jiaping Han、A.M.R. Senos、P.Q. Mantas 等 4 位作者2003-03-27Journal of Applied Physics

The dielectric properties of Mn-doped ZnO ceramics with electrically active grain boundaries at low temperatures of 10–70 K were investigated by admittance spectroscopy. It was observed that the dielectric relaxation of the main shallow donors, zinc interstitial, in these samples occurred in the temperature range of 2…

ZnO doping and propertiesMicrowave Dielectric Ceramics SynthesisDielectric properties of ceramics

Cathodoluminescence and Hall-effect measurements in sulfur-doped chemical-vapor-deposited diamond

Kazushi Nakazawa、M. Tachiki、Hiroshi Kawarada 等 6 位作者2003-03-27Applied Physics Letters

Dominant n-type conductivity in sulfur-doped chemical-vapor-deposited diamond is observed by Hall-effect measurement. The activation energy is estimated at 0.5–0.75 eV above 600 K. Below 600 K, the carrier concentration deviates from the activation energy, and Hall mobility decreases in comparison with that above 600…

Semiconductor materials and devicesDiamond and Carbon-based Materials ResearchElectronic and Structural Properties of Oxides

Optical properties of Bi3.25La0.75Ti3O12 thin films using spectroscopic ellipsometry

Zhigao Hu、Genshui Wang、Zhiming Huang 等 4 位作者2003-03-27Journal of Applied Physics

Using spectroscopic ellipsometry, the optical properties of the Bi3.25La0.75Ti3O12 (BLT) thin films with different film thicknesses on platinized silicon substrates prepared by chemical solution methods have been investigated in the 400–1700 nm wavelength range. By fitting the measured ellipsometric parameter (Ψ and Δ…

Ferroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear OpticsMicrowave Dielectric Ceramics Synthesis

Processing of Y2BaCuO5foams

E. Sudhakar Reddy、M. Herweg、Georg J. Schmitz2003-03-27Superconductor Science and Technology

Foams of conventional ceramics are attractive for a wide range of industrial applications such as filters, insulators, heat exchangers and others. Advanced functional ceramics, e.g., superconductors or piezoceramics profit from a foam structure for a variety of applications. Foams of Y 2 BaCuO 5 —being the properitect…

Advanced ceramic materials synthesisCellular and Composite StructuresAluminum Alloys Composites Properties

Influence of temperature on the ultrasonic degradation of poly(vinyl acetate) and poly(vinyl chloride)

Sujay Chattopadhyay、Giridhar Madras2003-03-27Journal of Applied Polymer Science

Abstract This study investigates the effect of temperature on the ultrasonic degradation of polyvinyl acetate and polyvinyl chloride in chlorobenzene. The time evolution of molecular weight distribution was determined using gel permeation chromatography. Continuous distribution kinetics was used to obtain the degradat…

Ultrasound and Cavitation PhenomenaThermal and Kinetic AnalysisPolymer Science and PVC

The electronic structure of n- and p-doped phenyl-capped 3,4-ethylenedioxythiophene trimer

M. P. de Jong、A. W. Denier van der Gon、Xavier Crispin 等 6 位作者2003-03-27The Journal of Chemical Physics

The phenyl-capped 3,4-ethylenedioxythiophene (EDOT) trimer is a well-defined oligomer of the related poly(3,4-ethylenedioxythiophene), the conjugated polymer that forms the basis of the commercialized conducting polymer “PEDOT-PSS.” EDOT-based oligomers are themselves potential candidates for applications in molecular…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsAnalytical Chemistry and Sensors

Polarization behavior of ferroelectric multilayered composite structures

Y. T. Or、Chau-Wai Wong、B. Ploss 等 4 位作者2003-03-27Journal of Applied Physics

We model the polarization behavior of ferroelectric multilayered composite structures including the double layer and the triple layer under the action of variable fields. The model takes into consideration the ceramic/polymer interfacial charge and the nonlinear hysteresis nature of the ferroelectric constituent mater…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesDielectric materials and actuators

Dynamics of nanoscale polarization backswitching in tetragonal lead zirconate titanate thin film

Desheng Fu、Kazuyuki Suzuki、Kazumi Kato 等 4 位作者2003-03-27Applied Physics Letters

The dynamics of polarization backswitching in highly oriented Pb(Zr0.3Ti0.7)O3 (PZT) thin films has been studied in nanoscale using piezoresponse scanning force microscopy (SFM). Our measurements reveal that a SFM-written domain with diameter about 200 nm in PZT films loses its polarization through both the sidewise a…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesElectronic and Structural Properties of Oxides

Electronic and chemical properties of mixed-metal oxides: Adsorption and reaction of NO on SrTiO3(100)

JoséA. Rodriguez、Samina Azad、L.-Q. Wang 等 6 位作者2003-03-27The Journal of Chemical Physics

The interaction of NO with SrTiO3(100) surfaces was investigated using thermal desorption, photoemission, and first-principles density-functional calculations. The crystals used in the experiments exposed mainly (>80%) the TiO2-terminated face of SrTiO3(100). On the stoichiometric surfaces, the adsorption of NO…

Advanced Photocatalysis TechniquesCatalytic Processes in Materials ScienceElectronic and Structural Properties of Oxides

Short-time piezoelectric measurements in ferroelectric thin films using a double-beam laser interferometer

Peter Arne Gerber、Andreas Roelofs、O. Lohse 等 7 位作者2003-03-27Review of Scientific Instruments

An evolution of the double-beam laser interferometer used for piezoelectric measurements in ferroelectric thin films is reported. Measuring the d33 hysteresis of a ferroelectric material using lock-in technique with large time constants requires a varying bias field to be applied to the sample over a long period of ti…

Ferroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear OpticsAcoustic Wave Resonator Technologies

Monolayer, Bilayer, Multilayers: Evolving Magnetic Behavior in Langmuir−Blodgett Films Containing a Two-Dimensional Iron−Nickel Cyanide Square Grid Network

Jeffrey T. Culp、Ju‐Hyun Park、Mark W. Meisel 等 4 位作者2003-03-27Inorganic Chemistry

The assembly of two-dimensional cyanide-bridged Fe(III)-Ni(II) square grid networks at the air-water interface and subsequent transfer of these networks as isolated monolayer, isolated bilayer, and multiple bilayer (multilayer) films via the Langmuir-Blodgett technique results in novel low-dimensional systems in which…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesOrganic and Molecular Conductors Research

Damping as a function of pulsed field amplitude and bias field in thin film Permalloy

J. P. Nibarger、R. Lopušnı́k、T. J. Silva2003-03-27Applied Physics Letters

We have measured the step response in thin film Permalloy as a function of both a hard-axis pulsed field amplitude and an easy-axis longitudinal magnetic bias field using a pulsed inductive microwave magnetometer. The bias field ranged from 0 to 8000 A/m (0 to 100 Oe) and the pulsed field varied from 0.32 to 320 A/m (…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagneto-Optical Properties and Applications

Textural and shape memory characteristics of Fe 29.9 at. Pd melt-spun ribbons

David Vokoun、Tomasz Goryczka、C.T. Hu2003-03-27Smart Materials and Structures

Fe–29.9 at.% Pd shape memory ribbons have been manufactured by means of the free jet melt-spinning method. The microstructure, the shape memory effect and the texture of the manufactured melt-spun ribbons have been studied. Some of the results are compared with those obtained in similar studies on Fe–Pd shape memory m…

Metallic Glasses and Amorphous AlloysShape Memory Alloy TransformationsCultural Heritage Materials Analysis

Dimeric liquid‐crystalline epoxyimine monomers: Influence of dipolar moments on mesomorphic behavior and the formation of liquid‐crystalline thermosets

David Ribera、Àngels Serra、Ana Mantecón2003-03-27Journal of Polymer Science Part A Polymer Chemistry

Abstract We examine some of the structural aspects that influence the mesomorphic behavior of liquid‐crystalline dimeric epoxy resins with imine groups in the mesogens. We synthesized two new series of monomers and compared them with previously synthesized monomers. Compared with previously studied series, the imine g…

Liquid Crystal Research AdvancementsEpoxy Resin Curing ProcessesSynthesis and properties of polymers

Electrical transport through crossed carbon nanotube junctions

J. W. Park、Jinhee Kim、Kyung‐Hwa Yoo2003-03-27Journal of Applied Physics

We have investigated the electrical transport properties through crossed nanotube junction between two metallic single-walled carbon nanotubes. Depending on the temperature range, the crossed junction exhibits different behaviors. At high temperatures, the crossed junction acts as a tunneling junction and its conducta…

Carbon Nanotubes in CompositesGraphene research and applicationsForce Microscopy Techniques and Applications