Materials Literature
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The reaction between the [Mn(BS)(H 2 O)] + monomeric and [Mn 2 (μ-BS) 2 (H 2 O) 2 ] 2+ dimeric cations and [Fe(CN) 6 ] 3 - gave rise to cation−anion interaction via the formation of [Fe C⋮N Mn] bridges. Depending on the nature of the Schiff base and regardless of the stoichiometry used, either the trimeric anion [{Mn(…
Films of copper(I) oxide can be electrodeposited by reduction of copper(II) lactate in alkaline solution. Rietveld analysis of electrochemically grown films reveals pure copper(I) oxide with no copper(II) oxide or copper metal present in the films and a lattice parameter of a = 0.4266 nm. The cathodic deposition curre…
Strategies for the preparation of zeolite molecular sieve membranes and layers on different substrates are reviewed. Membranes (and continuous thin films) have been synthesized with ZSM-5 (MFI) type molecular sieves and other zeolites, either as free-standing specimens, grown on various supports according to several s…
Covalent attachment of nanometer-scale colloidal Au particles to organosilane-coated substrates is a flexible and general approach to formation of macroscopic Au surfaces that have well-defined nanostructure. Variations in substrate (glass, metal, Al 2 O 3 ), geometry (planar, cylindrical), functional group (−SH, −P(C…
The crystal chemistry of hydrotalcite-like compounds is investigated by powder diffraction methods such as Rietveld structure refinement, radial distribution function analysis, atom-specific radial distribution analysis obtained from anomalous diffraction data, and EXAFS spectroscopy. The topology of the brucite-type…
Poly(methyl methacrylate) (PMMA) was melt mixed 30:70 into polystyrene (PS) with and without symmetric P(S- b -MMA) diblock copolymers. The molecular weight of the components was varied. After 5 min of shear mixing, the PMMA was dispersed into roughly spherical, submicron particles. Particle size was measured by light…
ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTScattering Form Factor of Block Copolymer MicellesJan Skov Pedersen and Michael C. GerstenbergView Author Information Department of Solid State Physics, Risø National Laboratory, DK-4000 Roskilde, DenmarkCite this: Macromolecules 19…
A disordered mesoporous silica material has been prepared using polymerization of silicate anions surrounding surfactant micelles in the presence of organic salts. The local structure of the material has been investigated using a transmission electron micrograph image of platinum wire grown inside the mesopores. This…
Twelve superparamagnetic Magnetite-Dextran (MD) nanoparticles potentially useful as contrast agents for Magnetic Resonance Imaging (MRI), with different sizes, charges and surface natures, were produced and internally labelled with (59)Fe in order to investigate the effect of their physicochemical properties on their…
Temperature-programmed desorption (TPD) and oxygen isotopic labeling studies were used to probe the dissociation of water on the (100) and (110) surfaces of TiO 2 (rutile). Water TPD spectra from these two surfaces were distinctive. Three monolayer desorption states were observed for the (100) surface (at 205, 250, an…
ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTSynthesis of Branched and Hyperbranched PolystyrenesScott G. Gaynor, Shane Edelman, and Krzysztof MatyjaszewskiView Author Information Department of Chemistry, Carnegie Mellon University, Mellon Institute, 4400 Fifth Avenue, Pittsbu…
A series of amorphous azobenzene-containing polymers were cast as thin films and shown to produce both reversible volume diffraction gratings and high-efficiency surface gratings by laser irradiation at an absorbing wavelength. The latter process involves localized mass transport of the polymer chains to a high degree…
ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorHybrid Organic−Inorganic Thermoplastics: Styryl-Based Polyhedral Oligomeric Silsesquioxane PolymersTimothy S. Haddad and Joseph D. LichtenhanView Author Information Hughes STX Corporation, Phillips Laboratory, OLAC PL/RKS Edwards AFB, C…
ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTWater-Soluble Knedel-like Structures: The Preparation of Shell-Cross-Linked Small ParticlesK. Bruce Thurmond, Tomasz Kowalewski, and Karen L. WooleyView Author Information Department of Chemistry, Washington University St. Louis, Missouri 63130 Cite this: J. Am. Chem.…
A series of novel monomers and polymers containing aromatic-donor and o -quinoid-acceptor units was prepared, and the relationship between their spectral and electrochemical properties and their structures was investigated. X-ray structure analyses of the monomers possessing thiophene units revealed coplanar conformat…
A large basis set of α-oligothiophenes with two to seven rings (α2−α7), also including thiophene, α1, have been investigated in five solvents regarding absorption, fluorescence and phosphorescence, quantum yields of fluorescence (φ F ) and triplet formation (φ T ), lifetimes of fluorescence and the triplet state, quan…
The microstructure of various (ordered and disordered) polymer−organically modified layered silicate hybrids, synthesized via static polymer melt intercalation, is examined with X-ray diffraction and transmission electron microscopy. The ordered intercalates exhibit microstructures very similar to the unintercalated o…
ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTMonolayers in Three Dimensions: Synthesis and Electrochemistry of ω-Functionalized Alkanethiolate-Stabilized Gold Cluster CompoundsMichael J. Hostetler, Stephen J. Green, Jennifer J. Stokes, and Royce W. MurrayView Author Information Kenan Laboratories of Chemistry Uni…
Quantum-confined InP nanocrystals from 20 to 50 Å in diameter have been synthesized via the reaction of InCl 3 and P(Si(CH 3 ) 3 ) 3 in trioctylphosphine oxide (TOPO) at elevated temperatures. The nanocrystals are highly crystalline, monodisperse, and soluble in various organic solvents. Improved size distributions ha…
A new simulation code for modelling extended defects e.g. linear (dislocations) and planar (surfaces and grain boundaries) at the atomistic level is introduced. One of the key components is the ability to calculate the Coulombic potential of a solid with one-dimensional periodicity. This approach has been applied to s…