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ДЕЗАКТИВАЦИЯ ПРОМЫШЛЕННОГО АЛЮМООКСИДНОГО КАТАЛИЗАТОРА СКЕЛЕТНОЙ ИЗОМЕРИЗАЦИИ н-БУТЕНОВ

А. А. Ламберов、Ildar Mukhambetov、Р. Ф. Залялиев2014-11-27Катализ в промышленности

Causes of alumina catalyst deactivation in a process of skeletal n-butene isomerization, which leads to decreasing of the conversion from 31 to 26 % were examined. It is shown that contamination of Fe, Mg metal combination microimpurities reduces the conversion of n-butenes of about 2,5 %. The catalyst activity can be…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsThermal and Kinetic Analysis

How a charge conserving alternative to Maxwells displacement current entails a Darwin like approximation to the solutions of Maxwells equations

A.M. Wolsky2014-11-27arXiv (Cornell University)

Though sufficient for local conservation of charge, Maxwells displacement current is not necessary. An alternative to the Ampere-Maxwell equation is exhibited and the alternatives electric and magnetic fields and scalar and vector potentials are expressed in terms of the charge and current densities. The magnetic fiel…

Magnetic Properties and ApplicationsQuantum and Classical ElectrodynamicsControl and Stability of Dynamical Systems

CÔNG NGHỆ ĐIỆN HÓA VÀ BẢO VỆ KIM LOẠI

Nguyễn Đức Hùng2014-11-27Tạp chí Khoa học và Công Nghệ

Cong nghệ điện hoa được dựa tren cơ sở cac quy luật li thuyết về sự chuyển hoa nang lượng hoa học va điện với thong số đặc trưng la mật độ dong va điện thế cũng như được ứng dụng rộng rai trong cac nganh cong nghiệp nang lượng va pin nhien liệu, luyện kim mau va vật liệu chức nang, sản xuất hoa chất va thuốc, chống an…

Magnesium Oxide Properties and Applications

ВЛИЯНИЕ ХИМИЧЕСКОГО СОСТАВА И МЕТОДА ПРИГОТОВЛЕНИЯ НА ФИЗИКО-ХИМИЧЕСКИЕ СВОЙСТВА СИСТЕМЫ NiO/B2O3–Al2O3 И ЕЕ КАТАЛИТИЧЕСКУЮ АКТИВНОСТЬ В ПРОЦЕССЕ ОЛИГОМЕРИЗАЦИИ ЭТИЛЕНА

Т. Р. Карпова、А. В. Лавренов、Е. А. Булучевский 等 9 位作者2014-11-27Катализ в промышленности

Investigation of the influence of the chemical composition of support, substance and the method of nickel fixing on the physico-chemical and catalytic properties of the NiO/B2O3–Al2O3 system was conducted. Boron oxide content in the support was varied from 2 to 30 wt.% and a nickel content from 0,59 up to 3,18 wt.%. C…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesCatalysis and Oxidation Reactions

КАТАЛИТИЧЕСКОЕ ОКИСЛЕНИЕ САЖИ В УСЛОВИЯХ «СЛАБОГО» КОНТАКТА В ПРИСУТСТВИИ M/Ce0,72Zr0,18Pr0,1O2, ГДЕ М – ПЛАТИНА, ПАЛЛАДИЙ, РУТЕНИЙ

А. В. Малютин、Е. Ю. Либерман、А.И. Михайличенко 等 9 位作者2014-11-27Катализ в промышленности

Nanoparticulate catalysts M/Ce0,72Zr0,18Pr0,1O2, where M – Pt, Pd, Ru at 0,5; 1,0 and 2,0 wt.%, for diesel exhaust soot afterburning in a «weak» contact were synthesized. Structural, textural and catalytic properties of the samples were studied using EDX, X-ray synchrotron diffraction, XANES, EXAFS, TEM, low-temperatu…

Catalytic Processes in Materials ScienceBiodiesel Production and ApplicationsCatalysis and Oxidation Reactions

ВЛИЯНИЕ СОСТАВА ОКСИДНОГО ПОКРЫТИЯ И СПОСОБА ПРИГОТОВЛЕНИЯ БЛОЧНЫХ КАТАЛИЗАТОРОВ НА ИХ АКТИВНОСТЬ В РЕАКЦИИ ГЛУБОКОГО ОКИСЛЕНИЯ МЕТАНА

М. Р. Канцерова、С. Н. Орлик、А. В. Швец2014-11-27Катализ в промышленности

Catalysts for deep oxidation of methane were studied using the methods of X-ray diffraction, thermal desorption of nitrogen and temperature-programmed reduction with hydrogen. These catalysts comprise oxides of 3d-metals (Mn, Co), rare earth (La) and alkaline earth (Ba, Sr) elements in a porous matrix of secondary sup…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Oxidation Reactions

ВЛИЯНИЕ КИСЛОТНОЙ ОБРАБОТКИ НА СОСТАВ, СТРУКТУРУ И КАТАЛИТИЧЕСКИЕ СВОЙСТВА ПРИРОДНОГО АЛЮМОСИЛИКАТА В РЕАКЦИИ ИЗОМЕРИЗАЦИИ α-ПИНЕНА

A. I. Sidorenko、G SENKOV、В. Е. Агабеков2014-11-27Катализ в промышленности

The effect of modifying the conditions of the natural aluminosilicate catalyst by 10 % HCl solution on its chemical and phase composition, porous and crystalline structure, acidity and catalyst activity in the reaction of α-pinene isomerization. When aluminosilicate are treated by 10 % HCl in an amount of 25–250 ml pe…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisDiatoms and Algae Research

ChemInform Abstract: Triterpenoids from Gynocardia odorata and Their Antimicrobial Activity

Pranab Ghosh、Ashim K. Ghosh、Prasanta Chakraborty 等 4 位作者2014-11-27ChemInform

Abstract isolation, structure determination, and antimicrobial activity of two new friedelane‐type triterpenoids (I) and (II) along with five known triterpenoids

Natural product bioactivities and synthesisPharmacological Effects of Natural CompoundsPhytochemistry and Bioactive Compounds

ChemInform Abstract: Solvothermal Synthesis of Bi2O2CO3 Nanoplates for Efficient Photodegradation of RhB and Phenol under Simulated Solar Light Irradiation.

Shengpeng Hu、Cheng‐Yan Xu、Bao‐You Zhang 等 5 位作者2014-11-27ChemInform

Abstract The title nanoplates with an average width of 320 nm and thicknesses of 50—90 nm are solvothermally synthesized from mixtures of Bi(NO3)3, sodium dodecyl benzene sulfonate, polyethylene glycol, and H2O (autoclave, 180 °C, 20 h).

Advanced Photocatalysis TechniquesGas Sensing Nanomaterials and SensorsCopper-based nanomaterials and applications

AuCl3-CuCl2/γ-Al2O3乙炔氢氯化催化剂的失活原因分析及再生性能研究

程晓光、Jigang Zhao、王雷 等 4 位作者2014-11-27石油炼制与化工

采用γ﹣Al2 O3为载体通过浸渍法制备了 AuCl3﹣CuCl2∕γ﹣Al2 O3催化剂,考察其对乙炔氢氯化反应的催化性能,并用比表面积及孔径分析、扫描电镜、能谱仪、傅里叶变换红外光谱、电感耦合等离子体原子发射光谱等表征方法对催化剂的失活原因进行分析。结果表明:在温度150℃、压力0.1 MPa、空速120 h﹣1、V(HCl)∶V(C2 H2)=1.05的工艺条件下,乙炔转化率达到97%以上,氯乙烯选择性达到99%以上,但反应3 h后催化剂活性迅速降低;催化剂表面积炭为其失活的主要原因。将失活催化剂在空气氛围、500℃下焙烧1 h后,其活性基本能恢复至新鲜催化剂水平,说明该催化剂具有优异的再生性能。

Catalytic Processes in Materials ScienceMagnesium Oxide Properties and ApplicationsPigment Synthesis and Properties

Thermal management of power sources for mobile electronic devices based on micro-SOFC

Shoya Murayama、Fumitada Iguchi、Makoto Shimizu 等 4 位作者2014-11-27Journal of Physics Conference Series

Small power sources based on micro-SOFC for mobile electronic devices required two conditions, i,e, thermally compatibility and thermally self-sustain, because of high operating temperature over 300 o C. Moreover, high energy efficiency was also required. It meant that this system should be designed considering therma…

Advancements in Solid Oxide Fuel CellsFuel Cells and Related MaterialsGas Sensing Nanomaterials and Sensors

Fabrication of shape-controlled Au nanoparticle arrays for SERS substrates

Seon Mi Shin、Kyeong Woo Choi、Seong Ji Ye 等 5 位作者2014-11-27Advances in materials Research

Surface enhanced Raman Scattering (SERS) has attracted attention because the technique enables detection of various chemicals, even down to single molecular scale. Among the diverse candidates for SERS substrates, Au nanoparticles are considered promising due to their fine optical properties, chemical stability and ea…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanomaterials and Printing TechnologiesCopper-based nanomaterials and applications

A high Reliability Module with Thermoelectric Device by Molding Technology for M2M Wireless Sensor Network

Kanae Nakagawa、Tetsu Tanaka、Tomoo Suzuki2014-11-27Journal of Physics Conference Series

This paper presents the fabrication of a new energy harvesting module that used the thermoelectric device (TED) by using molding technology. The output voltage per heater temperature of the TED module at 20 °C ambient temperature is 8mV/K and similar to the result with the aluminium heat sink which is almost the same…

Advanced Thermoelectric Materials and DevicesInnovative Energy Harvesting TechnologiesThermal Radiation and Cooling Technologies

Post-Impact Investigation of CFRP Laminated Plate

Haris Ahmad Israr、N. Hongkarnjanakul、Samuel Rivallant 等 4 位作者2014-11-27Jurnal Teknologi

This paper deals with low-velocity impact and quasi-static indentation tests on carbon fibre reinforced plastic (CFRP) laminates that classically used in aeronautical applications. The aim is to carry out post-impact analysis using Vic 3-D digital image correlation to investigate the behaviour of permanent indentation…

Mechanical Behavior of CompositesElectronic Packaging and Soldering TechnologiesHigh-Velocity Impact and Material Behavior