Materials Literature
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Core-shell carbon-coated LiFePO4 nanoparticles were hybridized with reduced graphene (rGO) for high-power lithium-ion battery cathodes. Spontaneous aggregation of hydrophobic graphene in aqueous solutions during the formation of composite materials was precluded by employing hydrophilic graphene oxide (GO) as starting…
Stable and easily synthesized metal–organic framework MIL-88B-NH 2 represents an attractive support for catalysts employed in oxidation reactions, which are typically performed under relatively harsh conditions. However, MIL-88B-NH 2, the thermodynamic polymorph of the more popular MIL-101-NH 2, has been rarely employ…
A new heteroleptic ruthenium complex containing 2-thiophenyl benzimidazole ligands was synthesized using a microwave technique and was immobilized to graphene oxide via covalent attachment.
In this paper, the influence of foam filling of aluminum honeycomb core on its in-plane crushing properties is investigated. An aluminum honeycomb core and a polyurethane foam with densities of 65, 90, and 145 kg/m 3 were used to produce foam filled honeycomb panels, and then experimental quasi-static compression test…
National policies for long-term management of radioactive waste have for decades been driven by technical experts. The pursuit of these technocratic policies led in many countries to conflict with affected communities. Since the late 1990s, however, there has been a turn to more participatory approaches. This particip…
This perspective highlights the catalytic characteristics and future prospects of nano-/hierarchical zeolites in gaseous phase and liquid phase reactions.
Reducing the oxidative capacity of holes (h(+)) in the valence band (VB) of ZnS is one of the most effective ways to prevent the photocatalyst from photocorrosion. In this work, ZnS doped only with nitrogen was prepared for the first time by nitriding ZnS powder in an NH3 atmosphere. We demonstrate theoretically and e…
Based on a triboelectric nanogenerator (TENG), the first active micro-actuator for optical modulation driven by mechanical energy without external power or mechanical joint is presented. This demonstrates the enormous potential of TENGs for independent and sustainable self-powered micro/nano electromechanical systems,…
A porous highly stable MOF luminescent switch exhibits significant fluorescence enhancement and quenching responses for benzene and nitrobenzene vapors, respectively.
The macrocycle p-sulfonatocalix[4]arene (CX4) and the fluorescent dye lucigenin (LCG) form a stable host-guest complex, in which the dye fluorescence is quenched. Incubation of live V79 and CHO cells with the CX4/LCG chemosensing ensemble resulted in its spontaneous uptake. Subsequent addition of choline, acetylcholin…
Experimental studies of compressed matter are now routinely conducted at pressures exceeding 1 mln atm (100 GPa) and occasionally at pressures greater than 10 mln atm (1 TPa). The structure and properties of solids that have been so significantly squeezed differ considerably from those of solids at ambient pressure (1…
Chitosan, the only alkaline polysaccharide in nature with rich nitrogen content, is used as the sole precursor to obtain N-doped graphitic carbon-based ORR electrocatalysts. The findings of this work demonstrate that cheap, plentiful and renewable biomasses can be transformed into high value functional carbon material…
Aerobic epoxidation of olefins at a mild reaction temperature has been carried out by using nanomorphology of [Cu3(BTC)2] (BTC = 1,3,5-benzenetricarboxylate) as a high-performance catalyst through a simple synthetic strategy. An aromatic carboxylate ligand was employed to furnish a heterogeneous copper catalyst and al…
The deposition of material by cold spray is a relatively new technology. It is often applied to coating applications but can be used for the repair of defects in and damage to metal structures. The use of cold spray for repair is often favoured because, unlike thermal spray methods, cold spray does not bring about hea…
Three environmentally friendly MOF-based HEDMs with high-nitrogen ligands present superior detonation properties, thermostability and insensitivity.
New high temperature thermosetting resins and a thermoplastic polycarbonate have been synthesized from the renewable phenol vanillin.
A high molecular weight donor-acceptor conjugated polymer is synthesized using the Suzuki polycondensation method. Using this polymer, a single-junction bulk-heterojunction solar cell is fabricated giving a power conversion efficiency of 9.4% using a fullerene-modified ZnO interlayer at the cathode contact.
A new perovskite-like coordination polymer [(CH3)2NH2][Cd(N3)3] is reported which undergoes a reversible ferroelastic phase transition. This transition is due to varied modes of motion of the [(CH3)2NH2](+) guest accompanied by a synergistic deformation of the [Cd(N3)3](-) framework. The unusual two-staged switchable…
A luminescent cadmium-pamoate metal-organic framework, [Cd2 (PAM)2 (dpe)2 (H2 O)2 ]⋅0.5(dpe) (1), has been synthesized under hydrothermal conditions by using π-electron-rich ligands 4,4'-methylenebis(3-hydroxy-2-naphthalenecarboxylic acid) (H2 PAM) and 1,2-di(4-pyridyl)ethylene (dpe). Its structure is composed of both…
The structural development of a calcium (sodium) aluminosilicate hydrate (C–(N‐)A–S–H) gel system, obtained through the reaction of sodium metasilicate and ground granulated blast furnace slag, is assessed by high‐resolution 29 Si and 27 Al MAS NMR spectroscopy during the first 2 yr after mixing. The cements formed pr…