Materials Literature
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The kinetics of formation and structural evolution of novel polyelectrolyte complex materials formed by the assembly of water-soluble di- and triblock copolymers, with one neutral block and one (or two) cationic or anionic blocks, have been investigated. Comparison was made between the assembly of ABA and AB′ copolyme…
Embedding endohdedral metallofullerenes (EMFs) into electron donor-acceptor systems is still a challenging task owing to their limited quantities and their still largely unexplored chemical properties. In this study, we have performed a 1,3-dipolar cycloaddition reaction of a corrole-based precursor with Sc3 N@C80 to…
Three-dimensional (3 D) nanoporous SnO2 -Mx Oy (M=Fe, Co, Ni, Cu, etc.) hybrid networks possess unique compositional and structural features that are beneficial to lithium storage and are thus anticipated to meet the performance requirements of advanced lithium-ion batteries for transportation and stationary energy st…
A ternary blend polymer solar cell (PSC) comprising a semicrystalline polymer and two fullerene derivatives (C60, C70) shows a substantial increase in energy conversion efficiency as compared to that of corresponding binary blend PSCs. The enhancement in device efficiency results from an increase in short-circuit curr…
Novel imaging approaches have recently helped to clarify the properties of 'microbial nanowires'. Geobacter sulfurreducens pili are actual wires. They possess metallic-like conductivity, which can be attributed to overlapping pi-pi orbitals of key aromatic amino acids. Electrostatic force microscopy recently confirmed…
We recently proposed the ammonia heat of adsorption as a reactivity descriptor in solid acid catalysis, using it to predict the activity of zeotype catalysts in the propene–methanol reaction ( J. Phys. Chem. Lett. 2014, 5, 1516–1521). Here we extend the approach to a series of alkene reactants, establishing transition…
Soluble porous coordination polymers from mechanochemical synthesis are presented through a coordination polymerization between highly contorted, rigid tetraphenol and a broad variety of transition metal ions. These polymers can be easily cast as metal-containing films or freestanding membranes. Importantly, as-made c…
High-efficiency bulk heterojunction (BHJ) organic solar cells with power conversion efficiencies of more than 5 % can be fabricated using the green solvent 2-MeTHF. The active layers comprise a blend of a molecular semiconductor donor with intermediate dimensions (X2) and the soluble fullerene derivative [6,6]-phenyl-…
Umbrella hybrid (Bi 2 S 3 /rGO) 5 /TiO 2 nanorod arrays with high light absorption and stepwise band-edge structure accomplish high conversion efficiency under visible light.
anions in aqueous solvent mixtures, whilst the lateral size of the clathrochelate significantly affects their guest encapsulation behavior.
Oxygen functional groups play a key role in vanadium redox reactions. To identify the effective location of oxygen functionalities in graphene‐based nanomaterials, a selectively edge‐functionalized graphene nanoplatelet (E‐GnP) with a crystalline basal plane is produced by a ball‐milling process in the presence of dry…
A new series of conjugated random terpolymers (PDPP2T-Se-Th) was synthesized from an electron-deficient diketopyrrolopyrrole (DPP)-based unit in conjugation with two electron-rich selenophene (Se) and thiophene (Th) species, with a view to inducing different crystalline behaviors of the polymers. The crystallinity of…
An all-solid-state Z-scheme system array consisting of an Fe2V4O13 nanoribbon (NR)/reduced graphene oxide (RGO)/CdS nanoparticle grown on the stainless-steel mesh was rationally designed for photoconversion of gaseous CO2 into renewable hydrocarbon fuels (methane: CH4).
Cardiovascular diseases are the leading cause of deaths throughout the world. Vascular diseases are mostly treated with autografts and blood vessel transplantations. However, traditional grafting methods have several problems including lack of suitable harvest sites, additional surgical costs for harvesting procedure,…
Bacteria in natural and artificial environments often reside in self-organized, integrated communities known as biofilms. Biofilms are highly structured entities consisting of bacterial cells embedded in a matrix of self-produced extracellular polymeric substances (EPS). The EPS matrix acts like a biological 'glue' en…
The phase transformation of a zinc-2-methylimidazole-based zeolitic-imidazolate framework (ZIF), from a recently discovered ZIF-L to ZIF-8, was reported. ZIF-L is made up of the same building blocks as ZIF-8, having two-dimensional crystal lattices stacked layer-by-layer. Results indicated that the phase transformatio…
Schematic diagrams of the fabrication of composites.
With the rapid development of nanotechnology, nanoparticles have been widely used in many applications such as phototherapy, cell imaging, and drug/gene delivery. A better understanding of how nanoparticles interact with bio-system (especially cells) is of great importance for their potential biomedical applications.…
A highly defective CeO 2 supported RuO 2 as an electrocatalyst shows improved OER activity and stability in alkaline media. This improvement likely originates from the highly oxidative oxygen species O 2 2− /O − formed in the defective CeO 2 , which can easily migrate from CeO 2 and “spillover” to the surface of RuO 2…
This review summarizes the current progress toward the synthesis of three dimensional graphene-based composites and their application in lithium ion batteries.