Materials Literature
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2,3-Di-n-alkoxyphenazines were shown to act as acid-sensitive organogelators at ambient temperature in acetonitrile; the protonated yellow species formed in the presence of acid displays stronger aggregative properties and higher temperature resistance than the colourless neutral phenazine; the protonation/deprotonati…
Hexagonal CdS nanocrystallites have been easily prepared by reacting Cd2+ and S2- (H2S or Na2S) in N,N-dimethylformamide (DMF) without adding any surface stabilizers. The mean diameter of the nanocrystallites can be rigorously controlled over the range 1.8–4.2 nm with keeping the hexagonal crystalline structure by var…
A new method to determine directly and rapidly the degree of acetylation of chitin/chitosan was developed based on reactive pyrolysis-gas chromatography in the presence of an oxalic acid aqueous solution. The degree of acetylation was precisely evaluated on the basis of peak intensities of the characteristic products…
The XPS spectra of gamma-alumina were collected with a VSW HA150 using monochromatic Al Kα x-radiation. Monochromatic radiation provides a distinct clarity to the peak structure in the valence band of gamma-alumina due to the absence of interfering x-ray satellites from the intense O 2s region. Variations in the inten…
The principles of both pulsed electro acoustic (PEA) and pressure wave propagation (PWP) methods for measuring the space charge distributions in solid dielectrics are summarized. The relationship between the charge distribution in a specimen and voltage signal of the PEA method or the current signal of the PWP method…
The synthesis and characterisation of a homologous series of liquid crystal trimers, the 4,4′-bis[ω-(4-cyanobiphenyl-4′-yloxy)alkoxy]biphenyls, is reported in which the length of the flexible spacers is varied from 3 to 12 methylene units. All the members of the series exhibit enantiotropic nematic behaviour and, in a…
PTFE (polytetrafluoroethylene) membrane filters were tested for preparing corn oil emulsions by the membrane emulsification method using a pre-emulsified emulsion. A hydrophilic PTFE membrane was used to prepare an O/W emulsion without any disturbance of the continuous phase. A W/O emulsion was prepared with a hydroph…
I. STRUCTURES AND PROPERTIES. 1. Atomic Structure and Bonding in Solids. 2. Crystalline Structures - Ideal and Actual. 3. Electrical Properties of Materials. 4. Materials Properties for Design of Structures and Components. II. PROCESSING. 5. Equilibrium Phase Diagrams. 6. Diffusion in Solids. 7. Melting, Solidificatio…
The structure, dynamics, and strength of aqueous boehmite gels were studied by yield stress measurements and light scattering as a function of the particle aspect ratio and ionic strength. The yield stress was found to be a strongly varying function of the salt concentration. At low ionic strength, yield stress result…
The crystal structure of the non-stoichiometric Na x Si 136 silicon clathrate has been refined using the Rietveld method, in order to determine accurately the distribution of the sodium atoms within the two available sites. In agreement with the previous data, it was found that for x≤8, the alkali atoms occupy exclusi…
A dioxoruthenium(VI) complex with a D4-chiral porphyrin ligand has been prepared and characterized by spectroscopic methods and X-ray crystal analysis; the complex exhibits catalytic activity towards aerobic enantioselective epoxidation of prochiral alkenes with enantioselectivity up to 73% ee at an oxygen pressure of…
This paper analyzes the strengxth and failure behavior of plain weave composites. First, the geometrical characteristics of yarn shape, laminate stacking configuration, fiber volume fraction, and yarn packing fraction are investigated using three-dimensional geometrical models. Based on the geometrical characteristics…
Several possibilities are presented to deal with nonlinearity in ferromagnetic media in the case of time harmonic excitation in steady state, without losing simplicity in describing the potentials by means of complex peak values. The main idea is to introduce a fictitious time independent and inhomogeneous material to…
The efficiency of the H2O2 oxidation of 2,4,6-trichlorophenol (TCP) catalyzed by iron tetrasulfophthalocyanine (FePcS) is highly dependent on the pH value of the reaction mixture, the local hydrogen peroxide concentration and the organization of FePcS molecules in solution. Among the several forms of FePcS in aqueous…
The properties of complexes of five spiropyran-derived merocyanines with MgII, PbII, transition and rare-earth metal ions (Mn+, n = 2, 3) have been studied in acetone by steady-state and time-resolved techniques. Within nanoseconds, excitation of the spiropyran (Sp) form of 1′,3′,3′-trimethyl-6-nitro-8-methoxy-spiro[2…
The heat capacity of poly-p-dioxanone (PPDX), (CH2‒CH2‒O‒CH2‒COO‒)x, was determined using both differential scanning calorimetry (DSC) and temperature-modulated DSC (TMDSC) from 200 K to 430 K. Based on the new data and literature data, the heat capacity of the solid state was analyzed using an approximate group vibra…
We discuss the method for measuring surface charge density accumulated on the surface of a solid dielectric (insulating specimen) such as a supporting spacer in gas and vacuum insulated equipment. For such thick specimens, the probe response does not correspond to the charge density directly below the probe, so the me…
This paper presents a review of the theories based on wetting measurements/interfacial thermodynamics most frequently used to explain bacterial adhesion to solid surfaces. The physical meaning of data stemming from the application of the different theories is discussed and compared with current knowledge on interactio…
Local spin-density calculations are used to investigate the relationship between lattice distortions, magnetic ordering, and electronic properties in manganite perovskites. Lattice distortions are found to open pseudogaps at the middle of the majority spin ${e}_{g}$ manifold, which are more directly related to rotatio…
Calmodulin (CaM) is a primary Ca2+-binding protein found in all eukaryotic cells. It couples the intracellular Ca2+ signal to many essential cellular events by binding and regulating the activities of more than 40 different proteins and enzymes in a Ca2+-dependent manner. CaM contains two structurally similar domains…