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The Sintering Trajectory and Electrical Properties of Niobium‐Doped Titania Sputtering Targets

Ming‐Wei Wu、Yan‐Chi Chen2014-10-04Journal of the American Ceramic Society

Nb ‐doped TiO 2 ( TNO ) films, which are highly conductive and transparent, can be used as transparent conductive oxide ( TCO ) films. A predominant manufacturing method for TCO film is magnetron sputtering, and the material of the sputtering target affects the performance of the film. The objective of this study was…

ZnO doping and propertiesElectronic and Structural Properties of Oxides

Novel C o‐ M n‐ O nanosheet catalyst for CO preferential oxidation toward hydrogen purification

Zhongkui Zhao、Jin‐Han Lin、Guiru Wang 等 4 位作者2014-10-04AIChE Journal

Co‐Mn‐O composite oxide nanosheet catalyst was successfully prepared using a facile urea‐assisted one‐step hydrothermal method in the absence of organic or organic templating reagent. Co‐Mn‐O nanosheet catalyst was optimized by varying hydrothermal process parameters such as molar ratio of Co‐Mn to urea, hydrothermal…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Formation of self-organized Zircaloy-4 oxide nanotubes in organic viscous electrolyte via anodization

Ghafar Ali、Yang Jeong Park、Hyun Jin Kim 等 4 位作者2014-10-04Nanoscale Research Letters

This work reports the formation of self-organized Zircaloy-4 (Zr-4) oxide nanotubes in viscous organic ethylene glycol (EG) electrolyte containing a small amount of fluoride salt and deionized (DI) water via an electrochemical anodization. The structure, morphology, and composition of the Zr-4 oxide nanotubes were stu…

Fuel Cells and Related MaterialsAnodic Oxide Films and NanostructuresSmart Materials for Construction

p ‐Type Optoelectronic and Transparent Conducting Oxide Properties of Delafossite CuAl 1/2 Fe 1/2 O 2

Chesta Ruttanapun、Phumin Jindajitawat、Prathan Buranasiri 等 6 位作者2014-10-04Journal of the American Ceramic Society

CuAl 1/2 Fe 1/2 O 2 delafossite was prepared using a solid‐state reaction method to investigate its optical and electronic transport properties. CuAl 1/2 Fe 1/2 O 2 formed a hexagonal delafossite structure with an R m space group. The positive Seebeck coefficient and the direct optical gap of 3.6 eV confirmed that the…

ZnO doping and propertiesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Electrostatic deposition of silica nanoparticles between E ‐glass fibers and an epoxy resin

Benjamin H. Rutz、John C. Berg2014-10-04Journal of Applied Polymer Science

ABSTRACT The achievement of optimum adhesion between a thermoset and an inorganic material is an important goal for the composites and coatings industries. There is a growing interest in the use of structural surface modifiers, such as nanotubes, nanoparticles, and whiskers, to improve this adhesion. Here, a method fo…

Graphene research and applicationsSurface Modification and SuperhydrophobicityFiber-reinforced polymer composites

An approach for preparing an absorbable porous film of silk fibroin–rice starch modified with trisodium trimetaphosphate

Anucha Racksanti、Sorapong Janhom、Sittiporn Punyanitya 等 5 位作者2014-10-04Journal of Applied Polymer Science

ABSTRACT The absorbable porous material, especially gelatin porous film, is widely used for surgical use to stop bleeding, but its price is quite high. Thus, a new material at lower price with desirable properties is required. This article presents an approach to prepare a porous film of silk fibroin–rice starch (SF–R…

Electrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction StudiesSilk-based biomaterials and applications

Effects of mixing protocols on impact modified poly(lactic acid) layered silicate nanocomposites

Touffik Baouz、Eda Açık、Farouk Rezgui 等 4 位作者2014-10-04Journal of Applied Polymer Science

ABSTRACT Poly(lactic acid)/2 wt % organomodified montmorillonite (PLA/OMMT) was toughened by an ethylene‐methyl acrylate‐glycidyl methacrylate (E‐MA‐GMA) rubber. The ternary nanocomposites were prepared by melt compounding in a twin screw extruder using four different addition protocols of the components of the nanoco…

Polymer Nanocomposites and Propertiesbiodegradable polymer synthesis and propertiesSilicone and Siloxane Chemistry

Water‐blown polyurethane/polyisocyanurate foams made from recycled polyethylene terephthalate and liquefied wood‐based polyester polyol

Nataša Čuk、Ema Fabjan、Petra Grželj 等 4 位作者2014-10-04Journal of Applied Polymer Science

ABSTRACT Depolymerized polyethylene terephthalate and liquefied wood polyesters can be used as a polyol for the production of polyurethane/polyisocyanurate foams. In this research, liquefied wood was synthesized by using a combination of diethylene glycol and glycerol and due to the possibility of using glycerol that…

Polymer composites and self-healingLignin and Wood ChemistryFlame retardant materials and properties

Direct Synthesis of Graphene with Tunable Work Function on Insulators via In Situ Boron Doping by Nickel-Assisted Growth

Wen‐Chun Yen、Henry Medina、Jian‐Shiou Huang 等 9 位作者2014-10-04The Journal of Physical Chemistry C

Work function engineering, a precise tuning of the work function, is essential to achieve devices with the best performance. In this study, we demonstrate a simple technique to deposit graphene on insulators with in situ controlled boron doping to tune the work function. At a temperature higher than 1000 °C, the boron…

Graphene research and applicationsSemiconductor materials and devicesThermal properties of materials

Albendazole loaded albumin nanoparticles for ovarian cancer therapy

Lubna Noorani、Mohammad H. Pourgholami、Mingtao Liang 等 5 位作者2014-10-04European Journal of Nanomedicine

Abstract Albendazole (ABZ), a well-established antiparasitic drug, has been shown to suppress tumor growth in a number of preclinical models of cancer. However, the low solubility of ABZ limits its use as a systemic anticancer agent. To enable systemic administration, we have formulated ABZ into albumin nanoparticles…

Nanoparticle-Based Drug DeliveryPolymer Surface Interaction StudiesIntraperitoneal and Appendiceal Malignancies

Impact of Ralstonia eutropha's Poly(3-Hydroxybutyrate) (PHB) Depolymerases and Phasins on PHB Storage in Recombinant Escherichia coli

Jessica Eggers、Alexander Steinbüchel2014-10-04Applied and Environmental Microbiology

The model organism for polyhydroxybutyrate (PHB) biosynthesis, Ralstonia eutropha H16, possesses multiple isoenzymes of granules coating phasins as well as of PHB depolymerases, which degrade accumulated PHB under conditions of carbon limitation. In this study, recombinant Escherichia coli BL21(DE3) strains were used…

Enzyme Catalysis and Immobilizationbiodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

Crystallization Kinetics of Poly(1,4-butylene adipate) with Stereocomplexed Poly(lactic acid) Serving as a Nucleation Agent

Yi‐An Chen、Tzong‐Ming Wu2014-10-04Industrial & Engineering Chemistry Research

Poly(1,4-butylene adipate) (PBA), poly( l -lactic acid) (PLLA), and poly( d -lactic acid) (PDLA) are biodegradable and environmentally friendly polymers. PLLA- and PDLA-formed stereocomplex crystallites (SCs) by solvent-casting served as nucleating agents of PBA. The isothermal crystallization kinetics and morphology…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

Shrinkage of Tape Cast Products During Binder Burnout

Zongwen Fu、Andreas Roosen2014-10-04Journal of the American Ceramic Society

During sintering of tape cast products, anisotropic shrinkage occurs, which can be attributed to an anisotropic green tape structure concerning particle and pore orientation. Little is known about the shrinkage during binder burnout ( BBO ) and its relation to the microstructure of green tapes including the binder–pla…

Advanced ceramic materials synthesisInnovations in Concrete and Construction MaterialsMaterials Engineering and Processing

Processing‐Property Relationships in Electrospun Janus‐Type Biphasic Ceramic Nanofibers

Justin D. Starr、Maeve A. K. Budi、Jennifer S. Andrew2014-10-04Journal of the American Ceramic Society

Electrospinning provides a promising route to quickly produce high‐purity ceramic fibers from readily available sol–gel precursors. Recently, techniques have been developed to enable the production of biphasic nanocomposites on a single fiber, enabling the development of novel composites with connectivities that are d…

Ferroelectric and Piezoelectric MaterialsAdvanced Sensor and Energy Harvesting MaterialsMultiferroics and related materials

Photostimulated and Long Persistent Luminescence Properties from Different Crystallographic Sites of β‐Sr 2 SiO 4 : Eu 2+ , R 3+ (R = Tm, Gd)

Buhao Zhang、Xue Yu、Ting Wang 等 6 位作者2014-10-04Journal of the American Ceramic Society

Sintered ceramics of β‐ Sr 2 SiO 4 : Eu 2+ , R 3+ ( R = Tm , Gd ) were prepared and their spectroscopic properties were evaluated. A large enhancement of green photostimulated luminescence ( PSL ) was observed from β‐ Sr 2 SiO 4 : Eu 2+ codoping with Tm 3+ at a recognizable intensity level, and the most efficient PSL…

Luminescence Properties of Advanced MaterialsGlass properties and applications

The Temperature‐Dependent Ideal Tensile Strength of ZrB 2 , HfB 2 , and TiB 2

Tianbao Cheng、Weiguo Li2014-10-04Journal of the American Ceramic Society

This paper is aimed to fill the void in the literature regarding the temperature‐dependent ideal tensile strength of the AlB 2 ‐like diborides. To this end, two models of temperature‐dependent ideal tensile strength of hexagonal single crystals are developed based on the critical failure energy density principle and t…

Advanced ceramic materials synthesisBoron and Carbon Nanomaterials ResearchMXene and MAX Phase Materials

Determination of Retained B 2 O 3 Content in ZrB 2 ‐30 vol% SiC Oxide Scales

Kathleen Shugart、Siying Liu、Forrest Craven 等 4 位作者2014-10-04Journal of the American Ceramic Society

The composition of the borosilicate glass layer formed during oxidation of ZrB 2 ‐30 vol% SiC was determined to elucidate the extent of B 2 O 3 retention in the oxide during high‐temperature oxidation. Oxidation was conducted in stagnant air at 1300°C, 1400°C, and 1500°C for times between 100 and 221 min. Specimens we…

Advanced ceramic materials synthesisMXene and MAX Phase MaterialsAdvanced materials and composites

Lanthanoid “Bottlebrush” Clusters: Remarkably Elongated Metal–Oxo Core Structures with Controllable Lengths

Daniel D’Alessio、Alexandre N. Sobolev、Brian W. Skelton 等 9 位作者2014-10-04Journal of the American Chemical Society

Large metal-oxo clusters consistently assume spherical or regular polyhedral morphologies rather than high-aspect-ratio structures. Access to elongated core structures has now been achieved by the reaction of lanthanoid salts with a tetrazole-functionalized calixarene in the presence of a simple carboxylate co-ligand.…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesPolyoxometalates: Synthesis and Applications

Biodistribution of X‑Ray Iodinated Contrast Agent in Nano-Emulsions Is Controlled by the Chemical Nature of the Oily Core

Mohamed F. Attia、Nicolas Anton、Manuela Chiper 等 10 位作者2014-10-04ACS Nano

In this study, we investigated the role of the chemical nature of the oil droplet core of nano-emulsions used as contrast agents for X-ray imaging on their pharmacokinetics and biodistribution. To this end, we formulated PEGylated nano-emulsions with two iodinated oils (i.e., iodinated monoglyceride and iodinated cast…

Nanoparticle-Based Drug DeliveryLanthanide and Transition Metal ComplexesMRI in cancer diagnosis

Volume Expansion Caused by Water Penetration into Silica Glass

Sheldon M. Wiederhorn、Feng Yi、David A. LaVan 等 6 位作者2014-10-04Journal of the American Ceramic Society

By measuring the curvature of thin disks of vitreous silica that have been penetrated by water from one side only, we determined the volume expansion of the silica and the effect of this volume expansion on its strength. We found that the water‐strengthening process depended on crack‐size, temperature, and the amount…

Glass properties and applicationsStructural Analysis of Composite MaterialsSurface Roughness and Optical Measurements