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Synthesis of N-Doped meso-macroporous carbon and its application to SO2 absorption

Chao Liu、Lei Zhang、Yongqi Hu 等 5 位作者2014-11-06Russian Journal of Physical Chemistry A

N-Doped meso-macroporous carbon materials were synthesized using melamine-formaldehyde resin as carbon precursor and silica spheres as a removable template. The as-synthesized carbon materials with a bimodal pores structure (about 3.9 and ∼50–200 nm) display a high surface nitrogen content of 30 wt %. The macropores o…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisCovalent Organic Framework Applications

Bulk, surfaces and interfaces half-metallicity for zinc blende NiO: Modified Becke–Johnson potential investigation

Hongbin Xu、Shuaiwei Fan、Xiongbo Yang 等 5 位作者2014-11-06Japanese Journal of Applied Physics

The half-metallicity and electronic structures for the bulk, surfaces and interfaces of zinc blende (ZB) NiO are investigated by using full potential linearized augment plane wave method with the modified Becke and Johnson potential. Obtained results reveal ZB NiO is half-metallic ferromagnet with half-metallic gap 0.…

ZnO doping and propertiesMultiferroics and related materialsHeusler alloys: electronic and magnetic properties

Na2(smbipy) – A Bipyridine‐Derived Ligand with Chelating Sulfonate Tags and Its 3d Metal Complexes

Benjamin Oelkers2014-11-06European Journal of Inorganic Chemistry

Abstract The sulfonated bipyridine derivative disodium 6,6′‐bis(sulfonatomethyl)‐2,2′‐bipyridine [Na2(smbipy)] was synthesized, and its complexation behaviour towards divalent 3d metals in aqueous solution was explored. The complexes of late 3d metals [M(smbipy)(H2O)2]·H2O (M = Co, Ni, Zn) and [Cu(smbipy)(H2O)] are sp…

Metal complexes synthesis and propertiesMagnetism in coordination complexesFerrocene Chemistry and Applications

The phase equilibriums in the NH4Cl-CaCl2-H2O system at 50 and 75°C and their Pitzer model representations

Runzhi Zhang、Ji‐Min Yang、Li Zhang 等 4 位作者2014-11-06Russian Journal of Physical Chemistry A

The solubilities and refractive indexes in the NH4Cl-CaCl2-H2O system were measured at 50 and 75°C and the phase diagrams were constructed on the basis of the experimental data. The mixing parameters and equilibrium constant K sp were evaluated using the Pitzer ion-interaction model representations. The results obtain…

Calcium Carbonate Crystallization and InhibitionCrystallization and Solubility StudiesChemical and Physical Properties in Aqueous Solutions

Neutron and X-ray Scattering Studies of Rb2CoCl4 and Successive Phase Transition in A2BX4-type Crystals

Hirotake Shigematsu、Katsura Nishiyama、Yukihiko Kawamura 等 4 位作者2014-11-06Journal of the Physical Society of Japan

Soft phonon modes, which are related to the normal–incommensurate phase transition at Ti = 294 K and the lowest-temperature phase transition at T3 = 66 K in Rb2CoCl4, have been measured by inelastic neutron scattering. For the normal–incommensurate phase transition, phonon dispersion curves have been determined in the…

Perovskite Materials and ApplicationsGlass properties and applicationsSolid-state spectroscopy and crystallography

Experimental study of carbon dioxide separation with nanoporous ceramic membranes

Mohammed Nasir Kajama、Ngozi Claribelle Nwogu、Edward Gobina2014-11-06WIT transactions on ecology and the environment

This paper examines carbon dioxide (CO 2 ) separation from natural gas, mainly methane, through a 15 nm alumina tubular ceramic membrane before and after silica modification. A laboratory scale of tubular silica membrane with a permeable length of 348 mm, I.D and O.D of 7 and 10 mm respectively was used in this experi…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingMembrane Separation and Gas Transport

Radiation protection culture: a global challenge

R. Michel、Karl Klaus Henrichs、C. Wernli2014-11-06Radiation Protection Dosimetry

The central motto 'Radiation Protection Culture-A Global Challenge' of the fourth European IRPA Congress is discussed on the basis of the IRPA Guiding Principles Establishing a Radiation Protection Culture and the contributions presented in the plenary sessions of the conference.

Graphite, nuclear technology, radiation studiesNuclear and radioactivity studies

A fluorescence turn-on probe for selective detection of nitrogen dioxide

Biplab Mondal、Vikash Kumar2014-11-06RSC Advances

Two copper(II) complexes, 1 and 2, of two ligands, L1 and L2 [L1 = 2-{[anthracen-9-ylmethyl-(2-dimethylamino-ethyl)-amino]-methyl}-4,6-di-tert-butyl-phenol; L2 = 5-dimethylamino-naphthalene-1-sulfonic acid (3,5-di-tert-butyl-2-hydroxy-benzyl)-(2-dimethylamino-ethyl)-amide, were synthesized and characterized. In methan…

Molecular Sensors and Ion DetectionPorphyrin and Phthalocyanine ChemistryAnalytical Chemistry and Sensors

IR and Py-GC/MS spectral simulation of polymer film by quantum chemical and quantum molecular dynamics calculations using the polymer models

Kazunaka Endo、Kôichirô Hayashi、Tomonori Ida 等 4 位作者2014-11-06Russian Journal of Physical Chemistry A

We have simulated IR and pyrolysis gas chromatography mass spectrometry (Py-GCMS) spectra of six polymers (PE, PP, PS, PET, N6, PVDF) with the density-functional theory and quantum molecular dynamics calculations on model oligomers. In the former calculations, experimental harmonic frequencies of the polymers have bee…

Mass Spectrometry Techniques and ApplicationsIon-surface interactions and analysisThermal and Kinetic Analysis

The possibilities of the application of ion-plasma technologies to improve the wear resistance of the functional surfaces of power equipment elements

Г. В. Качалин、А. Ф. Медников、А. Ф. Медников 等 4 位作者2014-11-06WIT transactions on ecology and the environment

The reliability and efficiency of power equipment is largely depend on the degree of wear in its most loaded elements, which during operation undergo the cumulative effects of various factors. The mutual manifestation of several kinds of wear leads to the intensification of the destruction processes that will reduce e…

Industrial Engineering and TechnologiesMaterial Properties and ApplicationsSurface Treatment and Coatings

Low‐Temperature Magnetic and Dielectric Anomalies in Rare‐Earth‐Substituted BiFeO 3 Ceramics

Vladimı́r Koval、I. Škorvánek、Haixue Yan2014-11-06Journal of the American Ceramic Society

In this work, we report on the magnetic and dielectric anomalies observed in dense Bi 1– x RE x FeO 3 ceramics ( RE = Dy , Tb ; 0 ≤ x ≤ 0.3) at cryogenic temperatures. For compositions with a high content of rare‐earth ions, thermomagnetic experiments revealed a distinct anomaly in the magnetization curves at temperat…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMagneto-Optical Properties and Applications

Screening effect on the exciton mediated nonlinear optical susceptibility of semiconductor quantum dots

Jessica E. Q. Bautista、M. L. Lyra、R. P. A. Lima2014-11-06Optics Express

We study the exciton contribution to the third-order optical susceptibility of one-dimensional semiconductor quantum dots and show that the screening of the electron-hole interaction has a strong influence on the nonlinear optical properties in the weak confinement regime. Based on a density matrix formulation, we est…

Semiconductor Quantum Structures and DevicesQuantum Dots Synthesis And PropertiesMolecular Junctions and Nanostructures

Controlling the wave propagation through the medium designed by linear coordinate transformation

Yicheng Wu、Chengdong He、Yuzhuo Wang 等 5 位作者2014-11-06European Journal of Physics

Based on the principle of transformation optics, we propose to control the wave propagating direction through the homogenous anisotropic medium designed by linear coordinate transformation. The material parameters of the medium are derived from the linear coordinate transformation applied. Keeping the space area uncha…

Metamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface TechnologiesRadio Wave Propagation Studies

Insight into a molecular interaction force supporting peptide backbones and its implication to protein loops and folding

Qi-Shi Du、Dong Chen、Nengzhong Xie 等 5 位作者2014-11-06Journal of Biomolecular Structure and Dynamics

Although not being classified as the most fundamental protein structural elements like α-helices and β-strands, the loop segment may play considerable roles for protein stability, flexibility, and dynamic activity. Meanwhile, the protein loop is also quite elusive; i.e. its interactions with the other parts of protein…

Protein Structure and DynamicsRNA and protein synthesis mechanismsEnzyme Structure and Function

Experimental study of energy transport between two granular gas thermostats

Charles-Édouard Lecomte、Antoine Naert2014-11-06Journal of Statistical Mechanics Theory and Experiment

We report on the energy transport between two coupled probes in contact with granular thermostats at different temperatures. In our experiment, two identical blades, which are electromechanically coupled, are immersed in two granular gases maintained in different non-equilibrium stationary states, characterized by dif…

Material Dynamics and PropertiesAdvanced Thermodynamics and Statistical MechanicsQuantum Electrodynamics and Casimir Effect

Measurement of energy flux to a substrate by thermal and Langmuir probes during inductively coupled plasma assisted DC magnetron sputtering

Yoshinobu Matsuda、Kenji Mine、Shintaro Wakiyama 等 4 位作者2014-11-06Japanese Journal of Applied Physics

Measurement of energy flux to a substrate by thermal and Langmuir probes during inductively coupled plasma assisted DC magnetron sputtering, Matsuda, Yoshinobu, Mine, Kenji, Wakiyama, Shintaro, Shinohara, Masanori

ZnO doping and propertiesMetal and Thin Film MechanicsPlasma Diagnostics and Applications

Tailoring the Inherent Optical and Electrical Properties of Nanostructures

Masaru Kuno2014-11-06The Journal of Physical Chemistry Letters

ADVERTISEMENT RETURN TO ISSUEPREVGuest CommentaryNEXTTailoring the Inherent Optical and Electrical Properties of NanostructuresMasaru Kuno*View Author Information Department of Chemistry and Biochemistry, University of Notre Dame, 251 Nieuwland Science Hall, Notre Dame, Indiana 46556, United States*E-mail: [email prot…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanowire Synthesis and Applications

A proposed Australian transition to an anhydrous ammonia fuel transport economy to replace liquid petroleum fuels

R. G. Boothroyd2014-11-06WIT transactions on ecology and the environment

Synthetically-manufactured ammonia fuel is proposed for distribution throughout Australia when we need to replace future diminishing petroleum resources. In the interim this would be derived from natural gas resources using the Haber Bosch process, leading to a progressive transition to 100% energy resourcing from sus…

Advancements in Solid Oxide Fuel CellsHybrid Renewable Energy SystemsAmmonia Synthesis and Nitrogen Reduction