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Classical and fluctuation‐induced electromagnetic interactions in micron‐scale systems: designer bonding, antibonding, and Casimir forces

Alejandro W. Rodriguez、Pui‐Chuen Hui、David P. Woolf 等 6 位作者2014-11-06Annalen der Physik

Whether intentionally introduced to exert control over particles and macroscopic objects, such as for trapping or cooling, or whether arising from the quantum and thermal fluctuations of charges in otherwise neutral bodies, leading to unwanted stiction between nearby mechanical parts, electromagnetic interactions play…

Mechanical and Optical ResonatorsNonlocal and gradient elasticity in micro/nano structuresQuantum Electrodynamics and Casimir Effect

Fe ion-implanted TiO2 thin film for efficient visible-light photocatalysis

G. Impellizzeri、Viviana Scuderi、Lucia Romano 等 12 位作者2014-11-06Journal of Applied Physics

This work shows the application of metal ion-implantation to realize an efficient second-generation TiO2 photocatalyst. High fluence Fe+ ions were implanted into thin TiO2 films and subsequently annealed up to 550 °C. The ion-implantation process modified the TiO2 pure film, locally lowering its band-gap energy from 3…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesCopper-based nanomaterials and applications

Cell-penetrating poly(disulfide)s: the dependence of activity, depolymerization kinetics and intracellular localization on their length

Nicolas Chuard、Giulio Gasparini、Aurélien Roux 等 5 位作者2014-11-06Organic & Biomolecular Chemistry

We report that the depolymerization kinetics of cell-penetrating poly(disulfide)s depend exclusively on their length and propose a kinetic uptake model to explain why their intracellular destination changes with the increasing length from the endosomes over the cytosol to the nucleoli.

RNA Interference and Gene DeliveryPolymer Surface Interaction StudiesSilk-based biomaterials and applications

Bilayer Molecular Assembly at a Solid/Liquid Interface as Triggered by a Mild Electric Field

Qing‐Na Zheng、Xuan‐He Liu、Xingrui Liu 等 8 位作者2014-11-06Angewandte Chemie International Edition

The construction of a spatially defined assembly of molecular building blocks, especially in the vertical direction, presents a great challenge for surface molecular engineering. Herein, we demonstrate that an electric field applied between an STM tip and a substrate triggered the formation of a bilayer structure at t…

Block Copolymer Self-AssemblyPickering emulsions and particle stabilizationSurface Chemistry and Catalysis

Magnetic cellulose–TiO 2 nanocomposite microspheres for highly selective enrichment of phosphopeptides

Jiangjiang Duan、Xiao‐Mei He、Lina Zhang2014-11-06Chemical Communications

Novel magnetic cellulose–TiO 2 nanocomposite microspheres were prepared successfully by in situ synthesis of TiO 2 nanoparticles in the micro/nanopores of cellulose–Fe 3 O 4 microsphere, which exhibited highly selective enrichment of trace phosphopeptides, as a result of the high-efficiency Lewis acid–base reaction.

Nanoparticle-Based Drug DeliveryAdvanced biosensing and bioanalysis techniquesAdvanced Proteomics Techniques and Applications

Graphene-Based Transparent Electrodes for Hybrid Solar Cells

Pengfei Li、Caiyun Chen、Jie Zhang 等 6 位作者2014-11-06Frontiers in Materials

The graphene-based transparent and conductive films were demonstrated to be cost-effective electrodes working in organic-inorganic hybrid Schottky solar cells. Large area graphene films were produced by chemical vapor deposition (CVD) on copper foils and transferred onto glass as transparent electrodes. The hybrid sol…

Graphene research and applicationsSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Simultaneous Quantification of Hg2+ and MeHg+ in Aqueous Media with a Single Fluorescent Probe by Multiplexing in the Time Domain

Ziqian Zhang、Baoyan Zhang、Xuhong Qian 等 6 位作者2014-11-06Analytical Chemistry

Development of a molecular probe for selective detection of MeHg(+) in the presence of Hg(2+) is a mission impossible to accomplish. Speciation analysis of two substrates with a single kinetic trace exploiting their differential reactivity toward a single probe, i.e., multiplexing in the time domain, is a cost-effecti…

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsSulfur Compounds in Biology

Integration of 2D and 3D Thin Film Glassy Carbon Electrode Arrays for Electrochemical Dopamine Sensing in Flexible Neuroelectronic Implants

Jules J. VanDersarl、André Mercanzini、Philippe Renaud2014-11-06Advanced Functional Materials

Here we present the development and characterization of a flexible implantable neural probe with glassy carbon electrode arrays. The use of carbon electrodes allows for these devices to be used as chemical sensors, in addition to their typical use as electrical sensors and stimulators. The devices are fabricated out o…

EEG and Brain-Computer InterfacesConducting polymers and applicationsNeuroscience and Neural Engineering

Direct steam reforming of diesel and diesel–biodiesel blends for distributed hydrogen generation

Stefan Martin、Gerard Kraaij、Torsten Ascher 等 7 位作者2014-11-06International Journal of Hydrogen Energy

Distributed hydrogen generation from liquid fuels has attracted increasing attention in the past years. Petroleum-derived fuels with already existing infrastructure benefit from high volumetric and gravimetric energy densities, making them an interesting option for cost competitive decentralized hydrogen production. I…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Hydrodesulfurization Studies

High impact biowastes from South European agro-industries as feedstock for second-generation biorefineries

Alberto Scoma、Stefano Rebecchi、Lorenzo Bertin 等 4 位作者2014-11-06Critical Reviews in Biotechnology

Availability of bio-based chemicals, materials and energy at reasonable cost will be one of the forthcoming issues for the EU economy. In particular, the development of technologies making use of alternative resources to fossil fuels is encouraged by the current European research and innovation strategy to face the so…

Biofuel production and bioconversionbiodegradable polymer synthesis and propertiesBioeconomy and Sustainability Development

Assessing the Impacts of Ethanol and Isobutanol on Gaseous and Particulate Emissions from Flexible Fuel Vehicles

Georgios Karavalakis、Daniel Short、Robert Russell 等 7 位作者2014-11-06Environmental Science & Technology

This study investigated the effects of higher ethanol blends and an isobutanol blend on the criteria emissions, fuel economy, gaseous toxic pollutants, and particulate emissions from two flexible-fuel vehicles equipped with spark ignition engines, with one wall-guided direct injection and one port fuel injection confi…

Advanced Combustion Engine TechnologiesCatalytic Processes in Materials ScienceVehicle emissions and performance

High nitrogen-content carbon nanosheets formed using the Schiff-base reaction in a molten salt medium as efficient anode materials for lithium-ion batteries

Bin He、Wen‐Cui Li、An‐Hui Lu2014-11-06Journal of Materials Chemistry A

A series of porous carbon nanosheet materials with a high nitrogen content have been prepared using melamine and terephthalaldehyde as carbon precursors through the Schiff-base reaction in a molten salt medium.

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

NGF-conjugated iron oxide nanoparticles promote differentiation and outgrowth of PC12 cells

Michal Marcus、Hadas Skaat、Noa Alon 等 5 位作者2014-11-06Nanoscale

The search for regenerative agents that promote neuronal differentiation and repair is of great importance. Nerve growth factor (NGF) which is an essential contributor to neuronal differentiation has shown high pharmacological potential for the treatment of central neurodegenerative diseases such as Alzheimer's and Pa…

Nanoparticle-Based Drug DeliveryNerve injury and regenerationPhagocytosis and Immune Regulation

Torsion, parity-odd response, and anomalies in topological states

Onkar Parrikar、Taylor L. Hughes、Robert G. Leigh2014-11-06Physical review. D. Particles, fields, gravitation, and cosmology/Physical review. D. Particles and fields

We study the response of a class of topological systems to electromagnetic and gravitational sources, including torsion and curvature. By using the technology of anomaly polynomials, we derive the parity-odd response of a massive Dirac fermion in $d=2+1$ and $d=4+1$, which provides a simple model for a topological ins…

Graphene research and applicationsTopological Materials and PhenomenaQuantum Mechanics and Non-Hermitian Physics

Iodine Treatment of Lignin?Cellulose Acetate Electrospun Fibers: Enhancement of Green Fiber Carbonization

Makoto Schreiber、Singaravelu Vivekanandhan、Amar K. Mohanty 等 4 位作者2014-11-06ACS Sustainable Chemistry & Engineering

Abstract Pure biopolymer-based electrospun precursor carbon fibers are fabricated using an abundant and inexpensive biopolymer lignin blended with renewable resource-based cellulose acetate (CA). Iodine treatment on the fabricated green fiber was successfully performed in order to enhance the carbonization process as…

Natural Fiber Reinforced CompositesElectrospun Nanofibers in Biomedical ApplicationsFiber-reinforced polymer composites

UV-Absorption—The Primary Process in Photocatalysis and Some Practical Consequences

Terry A. Egerton2014-11-06Molecules

TiO2 photochemistry studies generally address reactions of photogenerated charge-carriers at the oxide surface or the recombination reactions which control the proportion of charge carriers that reach the surface. By contrast, this review focuses on UV absorption, the first photochemical step in semiconductor photocat…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesCatalytic Processes in Materials Science

Gelation: The Role of Sugars and Polyols on Gelatin and Agarose

Seishi Shimizu、Nobuyuki Matubayasi2014-11-06The Journal of Physical Chemistry B

Gelation is enhanced by the addition of sugars and polyols. How, at a microscopic level, do such cosolvents enhance gelation? The following two different hypotheses have been proposed so far to answer this question: (i) enhancement of water structure around the biopolymer induced by cosolvents; (ii) exclusion of cosol…

Proteins in Food SystemsCalcium Carbonate Crystallization and InhibitionPolysaccharides Composition and Applications

Differential Effects of Tissue Culture Coating Substrates on Prostate Cancer Cell Adherence, Morphology and Behavior

Michelle S. Libério、Martin C. Sadowski、Carolina Soekmadji 等 5 位作者2014-11-06PLoS ONE

Weak cell-surface adhesion of cell lines to tissue culture surfaces is a common problem and presents technical limitations to the design of experiments. To overcome this problem, various surface coating protocols have been developed. However, a comparative and precise real-time measurement of their impact on cell beha…

Cellular Mechanics and InteractionsCell Adhesion Molecules ResearchPolymer Surface Interaction Studies

Atomic Layer Deposition and in Situ Characterization of Ultraclean Lithium Oxide and Lithium Hydroxide

Alexander C. Kozen、Alexander J Pearse、Chuan‐Fu Lin 等 7 位作者2014-11-06The Journal of Physical Chemistry C

We demonstrate the ultraclean atomic layer deposition (ALD) of Li 2 O and LiOH using lithium tert -butoxide (LiO t Bu) precursor with H 2 O and plasma O 2 as oxidants, along with conversion of Li 2 O and LiOH products to Li 2 CO 3 upon CO 2 dosing. Using LiO t Bu and H 2 O results in LiOH below 240 °C and Li 2 O above…

Catalytic Processes in Materials ScienceSemiconductor materials and devicesElectronic and Structural Properties of Oxides

Comparison of Inhibitory Effect of 17-DMAG Nanoparticles and Free 17-DMAG in HSP90 Gene Expression in Lung Cancer

Hassan Mellatyar、Abolfazl Akbarzadeh、Mohammad Rahmati 等 8 位作者2014-11-06Asian Pacific Journal of Cancer Prevention

BACKGROUND: Up-regulation of hsp90 gene expression occurs in numerous cancers such as lung cancer. D,L-lactic-co-glycolic acid-poly ethylene glycol-17-dimethylaminoethylamino-17-demethoxy geldanamycin (PLGA-PEG-17DMAG) complexes and free 17-DMAG may inhibit the expression. The purpose of this study was to examine whet…

Nanoparticle-Based Drug DeliveryHeat shock proteins researchAndrographolide Research and Applications