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Noncoplanar and Counterrotating Incommensurate Magnetic Order Stabilized by Kitaev Interactions in γ−Li2IrO3

Alun Biffin、Roger D. Johnson、Itamar Kimchi 等 8 位作者2014-11-06Physical Review Letters

Materials that realize Kitaev spin models with bond-dependent anisotropic interactions have long been searched for, as the resulting frustration effects are predicted to stabilize novel forms of magnetic order or quantum spin liquids. Here, we explore the magnetism of γ-Li(2)IrO(3), which has the topology of a three-d…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Flow‐Driven Triboelectric Generator for Directly Powering a Wireless Sensor Node

Shuhua Wang、Xiaojing Mu、Ya Yang 等 6 位作者2014-11-06Advanced Materials

A triboelectric generator (TEG) for scavenging flow-driven mechanical -energy to directly power a wireless sensor node is demonstrated for the first time. The output performances of TEGs with different dimensions are systematically investigated, indicating that a largest output power of about 3.7 mW for one TEG can be…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsInnovative Energy Harvesting Technologies

Enhanced Hole Extraction in Perovskite Solar Cells Through Carbon Nanotubes

Severin N. Habisreutinger、Tomas Leijtens、Giles E. Eperon 等 6 位作者2014-11-06The Journal of Physical Chemistry Letters

Here, we report the use of polymer-wrapped carbon nanotubes as a means to enhance charge extraction through undoped spiro-OMeTAD. With this approach a good solar cell performance is achieved without the implementation of conventional doping methods. We demonstrate that a stratified two-layer architecture of sequential…

Perovskite Materials and ApplicationsConducting polymers and applicationsAdvanced battery technologies research

Photoelectronic Responses in Solution-Processed Perovskite CH $_{\bf 3}$ NH $_{\bf 3}$ PbI $_{\bf 3}$ Solar Cells Studied by Photoluminescence and Photoabsorption Spectroscopy

Yasuhiro Yamada、Toru Nakamura、Masaru Endo 等 5 位作者2014-11-06IEEE Journal of Photovoltaics

Photoelectronic responses of organic-inorganic hybrid perovskite CH3NH3PbI3on mesoporous TiO2electrodes are investigated. On the basis of near-band-edge optical absorption and photoluminescence spectra, the bandgap energy and exciton binding energy as a function of temperature are obtained. The exciton binding energy…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Carbon Quantum Dots/Cu2O Heterostructures for Solar‐Light‐Driven Conversion of CO2 to Methanol

Haitao Li、Xinyi Zhang、Douglas R. MacFarlane2014-11-06Advanced Energy Materials

A carbon quantum dots (CQDs)/Cu2O heterostructure with a protruding structure is synthesized and found to offer highly efficient photocatalytic conversion of CO2 to methanol under solar-light irradiation. The CQDs/Cu2O photocatalyst exhibits excellent stability during the conversion process, which is attributed to the…

Advanced Photocatalysis TechniquesZnO doping and propertiesCopper-based nanomaterials and applications

Processable conducting graphene/chitosan hydrogels for tissue engineering

Sepidar Sayyar、Éamonn Murray、Brianna C. Thompson 等 8 位作者2014-11-06Journal of Materials Chemistry B

Composites of graphene in a chitosan-lactic acid matrix were prepared to create conductive hydrogels that are processable, exhibit tunable swelling properties and show excellent biocompatibility. The addition of graphene to the polymer matrix also resulted in significant improvements to the mechanical strength of the…

Graphene research and applicationsSupercapacitor Materials and FabricationGraphene and Nanomaterials Applications

Detection Beyond Debye's Length with an Electrolyte‐Gated Organic Field‐Effect Transistor

Gerardo Palazzo、Donato De Tullio、Maria Magliulo 等 9 位作者2014-11-06Advanced Materials

Electrolyte-gated organic field-effect transistors are successfully used as biosensors to detect binding events occurring at distances from the transistor electronic channel that are much larger than the Debye length in highly concentrated solutions. The sensing mechanism is mainly capacitive and is due to the formati…

Conducting polymers and applicationsMolecular Junctions and NanostructuresAnalytical Chemistry and Sensors

Localized Electric Field of Plasmonic Nanoplatform Enhanced Photodynamic Tumor Therapy

Yiye Li、Tao Wen、Ruifang Zhao 等 12 位作者2014-11-06ACS Nano

Near-infrared plasmonic nanoparticles demonstrate great potential in disease theranostic applications. Herein a nanoplatform, composed of mesoporous silica-coated gold nanorods (AuNRs), is tailor-designed to optimize the photodynamic therapy (PDT) for tumor based on the plasmonic effect. The surface plasmon resonance…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanoplatforms for cancer theranosticsPhotodynamic Therapy Research Studies

Chemically exfoliated metallic MoS2 nanosheets: A promising supporting co-catalyst for enhancing the photocatalytic performance of TiO2 nanocrystals

Song Bai、Limin Wang、Xiaoyi Chen 等 5 位作者2014-11-06Nano Research

Electron-hole separation is a critical step to achieving efficient photocatalysis, towards which use of co-catalysts has become a widely used strategy. Despite the tremendous efforts and demonstrated functions of noble metal co-catalysts, seeking noble metal-free co-catalysts will always be the goal when designing cos…

Advanced Photocatalysis Techniques2D Materials and ApplicationsMXene and MAX Phase Materials

Band gap-tunable potassium doped graphitic carbon nitride with enhanced mineralization ability

Shaozheng Hu、Fayun Li、Zhiping Fan 等 6 位作者2014-11-06Dalton Transactions

Band gap-tunable potassium doped graphitic carbon nitride with enhanced mineralization ability was prepared using dicyandiamide monomer and potassium hydrate as precursors. X-ray diffraction (XRD), N2 adsorption, UV-Vis spectroscopy, Fourier transform infrared (FT-IR) spectroscopy, scanning electron microscopy (SEM),…

Advanced Photocatalysis TechniquesGa2O3 and related materialsElectronic and Structural Properties of Oxides

Controllable Perovskite Crystallization at a Gas–Solid Interface for Hole Conductor-Free Solar Cells with Steady Power Conversion Efficiency over 10%

Feng Hao、Constantinos C. Stoumpos、Zhao Liu 等 5 位作者2014-11-06Journal of the American Chemical Society

Depositing a pinhole-free perovskite film is of paramount importance to achieve high performance perovskite solar cells, especially in a heterojunction device format that is free of hole transport material (HTM). Here, we report that high-quality pinhole-free CH3NH3PbI3 perovskite film can be controllably deposited vi…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Toughening modification of (Acrylonitrile‐styrene‐acrylic copolymer)/(α‐Methylstyrene‐acrylonitrile copolymer) binary blend via using different impact modifiers

Wenqiang Zhu、Bo Xiang、Jun Zhang2014-11-06Journal of Vinyl and Additive Technology

In this work, different impact modifiers such as acrylic resin impact modifier, chlorinated polyethylene (CPE), nitrile rubber, powdered nitrile rubber, and hydrogenated nitrile rubber, were chosen to improve the toughness of (acrylonitrile‐styrene‐acrylic copolymer)/(α‐methylstyrene‐acrylonitrile copolymer) (ASA/α‐MS…

Polymer crystallization and propertiesNatural Fiber Reinforced CompositesPolymer Science and PVC

Synthesis of tyrosine-involved corrole Cu(III), Mn(IV), and Mn(III) complexes as biomimetic models of oxygen evolving complex in photosystem II

Ming Xia、Yan Gao2014-11-06Russian Journal of Physical Chemistry A

Boc-protected tyrosine-attached corrole ligand on the “ ortho ” position compound 3 , its corresponding copper (III) 4a , manganese (IV) 4b , and manganese (III) 4c complexes have been designed and synthesized based on the structures of active-centers of related biological systems. 1 H NMR and electronic absorption sp…

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

Polyurethanes from the crystalline prepolymers resistant to abrasive wear

Agata Domańska、Anna Boczkowska、Marta Izydorzak-Woźniak 等 5 位作者2014-11-06Green Sciences

Abstract The research aimed at the selection of polyurethanes synthesized from poly(tetramethylene ether) glycol (PTMEG), as well as from two different isocyanates 4,4′-methylenebis(cyclohexyl)isocyanate (HMDI) and 4.4′-methylenebis(phenyl isocyanate) (MDI) in order to obtain polyurethane with increased resistance to…

Orthopaedic implants and arthroplastybiodegradable polymer synthesis and propertiesTribology and Wear Analysis

Morphing for faster computations in transformation optics

Ronald Aznavourian、Sébastien Guenneau2014-11-06Optics Express

We propose to use morphing algorithms to deduce some approximate wave pictures of scattering by cylindrical invisibility cloaks of various shapes deduced from the exact computation (e.g. using a finite element method) of scattering by cloaks of two given shapes, say circular and elliptic ones, thereafter called the so…

Magnetic properties of thin filmsMetamaterials and Metasurfaces ApplicationsAdvanced Optical Imaging Technologies

Influence of laser irradiation on the optical properties of nano-sized powder of metal oxide

W.A. Farooq、Syed Mansoor Ali、Walid Tawfik 等 7 位作者2014-11-06Russian Journal of Physical Chemistry A

ZnO Nano powders were prepared by co-precipitation method which includes post-oxidation and annealing in air. Influence of laser irradiation was carried out using 355 nm laser on the physical properties of ZnO nanoparticles. SEM studies reveal agglomeration of grains resulting into enlargement and deformation of the n…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsLaser-Ablation Synthesis of Nanoparticles

Spectrum of edge states in the ν=0 quantum Hall phases in graphene

P. K. Pyatkovskiy、V. A. Miransky2014-11-06Physical Review B

Edge excitations of the $\ensuremath{\nu}=0$ quantum Hall state in monolayer graphene are studied within the mean-field theory with different symmetry-breaking terms. The analytical expressions for the continuum (Dirac) model wave functions are obtained for the charge density wave, Kekul\'e distortion, ferromagnetic,…

Graphene research and applicationsQuantum and electron transport phenomenaTopological Materials and Phenomena

Molecular dynamics simulations of the interfacial characteristics of polypropylene/single-walled carbon nanotubes

S. Rouhi、Y. Alizadeh、R. Ansari2014-11-06Proceedings of the Institution of Mechanical Engineers Part L Journal of Materials Design and Applications

Using molecular dynamics simulations, the interfacial characteristics of polypropylene chains with single-walled carbon nanotubes are studied. The effects of different parameters (including initial orientation of polypropylene chain relative to nanotube, temperature, nanotube chirality and radius, and chain length) on…

Carbon Nanotubes in CompositesConducting polymers and applicationsNanopore and Nanochannel Transport Studies

Novel nanocomposites obtained by dispersion of LDH modified with N ‐tetrabromophthaloyl‐glutamic in poly(amide‐imide) having N ‐trimellitylimido‐ l ‐leucine and 4,4′‐diaminodiphenylether units

Shadpour Mallakpour、Mohammad Dinari、Meysam Talebi2014-11-06Polymer Composites

Layered double hydroxides (LDHs) have attracted much attention as nanofillers in polymer nanocomposites (NCs) due to their particular surface structural, positively charged layer and so on. In this study, a chiral diacid was synthesized by the reaction of tetrabromophthalic anhydride and glutamic acid. LDH was modifie…

biodegradable polymer synthesis and propertiesLayered Double Hydroxides Synthesis and ApplicationsSynthesis and properties of polymers