Materials Literature
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This study demonstrates the unique capability of infrared near-field nanoscopy combined with Fourier transform infrared spectroscopy to map phase distributions in microcrystals of Li(x)FePO4, a positive electrode material for Li-ion batteries. Ex situ nanoscale IR imaging provides direct evidence for the coexistence o…
A label-free optical probe was developed for Ca(2+) detection based on the aggregation-induced emission property of Au(i)-thiolate complexes. Upon incubation with Ca(2+), the Au(I)-cysteine complexes rapidly aggregated through Cys-Ca(2+) interaction, resulting in a luminescent emission of the complexes. The label-free…
Preclinical research in the field of nanomedicine continues to produce a steady stream of new nanoparticles with unique capabilities and complex properties. With improvements come promising treatments for diseases, with the ultimate goal of clinical translation and better patient outcomes compared with current standar…
The precise organization of nano-objects into well-defined patterns at interfaces is an outstanding challenge in the field of nanocomposites toward technologically important materials and devices. Herein, by means of computer simulations we show novel mechanomutable nanocomposites designed by binary mixtures of tether…
A magnetic enzyme nanosystem have been designed and constructed by a polydopamine (PDA)-modification strategy. The magnetic enzyme nanosystem has well defined core-shell structure and a relatively high saturation magnetization (Ms) value of 48.3 emu g(-1). The magnetic enzyme system can realize rapid, efficient and re…
In this study, multifunctional and heparin-mimicking star-shaped supramolecules-deposited 3D porous multilayer films with improved biocompatibility were fabricated via a layer-by-layer (LbL) self-assembly method on polymeric membrane substrates. Star-shaped heparin-mimicking polyanions (including poly(styrenesulfonate…
The design of hybrid multipodal PMO (mp-PMO) nanoparticles with crystal-like architectures elaborated in a one-pot, two-step process, involving the preparation of a benzene-based spherical PMO core followed by the formation of ethylene-based rod-shaped PMO pods on these cores is described.
ADVERTISEMENT RETURN TO ISSUEPREVReviewNEXTRecent Advances in Optical Imaging with Anisotropic Plasmonic NanoparticlesYinhe Peng, Bin Xiong, Lan Peng, Hui Li, Yan He*, and Edward S. Yeung*View Author Information State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, C…
Low-power green-to-blue upconverting poly(vinyl alcohol)/DMF/DMSO-based organogels containing palladium( ii ) mesoporphyrin IX sensitizer and diphenylanthracene emitter are presented as a versatile new approach for efficient, self-standing solid-state upconverting materials.
The Berry phase on the Fermi surface and its influence on the conserved spin current in a two-dimensional system with generic $k$-linear spin-orbit interaction are investigated. We calculate the response of the effective conserved spin current to the applied electric field, which is composed of conventional and spin-t…
GaAs nanowires and GaAs-Fe3Si core-shell nanowire structures were grown by molecular-beam epitaxy on oxidized Si(111) substrates and characterized by transmission electron microscopy (TEM) and X-ray diffraction (XRD). Ga droplets were formed on the oxide surface, and the semiconducting GaAs nanowires grew epitaxially…
The results of XPS measurements (core levels and valence bands) of P+, Ca+, P+Ca+ and Ca+P+ ion implanted (E=30 keV, D=1x1017 cm-2) commercially pure titanium (cp-Ti) and first-principles density functional theory (DFT) calculations demonstrates formation of various structural defects in titanium dioxide films formed…
Industrial applications of aluminium and its alloys are restricted because of their poor tribological properties. Thermal spraying, laser surfacing, electron beam welding are the most widely used techniques to alter the surface morphology of base metal. Preliminary studies reveal that the coating and layering of alumi…
This work describes the fabrication of poly(4-styrenesulfonic acid)-doped polyaniline/graphene (PSS-doped PANI/graphene) nanocomposites and their use as sensing elements for hydrogen sulfide (H2S) detection. PSS with a weight-average molecular weight (Mw) of 1.96 × 10(6) was synthesized using low-temperature free-radi…
On the basis of group theory and first-principles calculations, we investigate high-rank multipole orderings in ${\mathrm{URu}}_{2}{\mathrm{Si}}_{2}$, which have been proposed as a genuine primary order parameter in the hidden-order phase below $17.5$ K. We apply Shubnikov group theory to the multipole ordered states…
Integration of quasi-two-dimensional (2D) films of metal-chalcogenides in optical microcavities permits new photonic applications of these materials. Here we present tunable microcavities with monolayer MoS2 or few monolayer GaSe films. We observe significant modification of spectral and temporal properties of photolu…
The concept of chemical bonding can ultimately be seen as a rationalization of the recurring structural patterns observed in molecules and solids. Chemical intuition is nothing but the ability to recognize and predict such patterns, and how they transform into one another. Here, we discuss how to use a computer to ide…
The photoexcited dynamics of the order parameter in a Peierls chain is investigated by using a microscopic quantum theory in the limit where the hot electrons may establish themselves into a quasi-equilibrium state described by an effective temperature. The optical phonon mode responsible for the Peierls instability i…
We have evaluated the successes and failures of the Hubbard-corrected density functional theory (DFT+U) approach to study Mg doping of LiCoO$_2$. We computed the effect of the U parameter on the energetic, geometric and electronic properties of two possible doping mechanisms: (1) substitution of Mg onto a Co (or Li) s…
We investigate the equation of states of the $β$-polymorph of cyclotetramethylene tetranitramine (HMX) energetic molecular crystal using DFT-D2, a first-principles calculation based on density functional theory (DFT) with van der Waals (vdW) corrections. The atomic structures and equation of states under hydrostatic c…