Materials Literature
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A triazole-linked hydroxyethylimino conjugate of calix[4]arene () and its cadmium complex have been synthesized and characterized, and their structures have been established. In the complex, both the Cd(2+) centers are bound by an N2O4 core, and one of it is a distorted octahedral, whereas the other is a trigonal anti…
Surface glycan switching is often observed when micro-organisms transition between different biotic and abiotic niches, including biofilms, although the advantages of this switching to the organism are not well understood. Bacillus cereus grown in a biofilm-inducing medium has been shown to synthesize an unusual cell…
We have extensively investigated the crystal structures of N 2 CO under high pressure using the swarm structure searching technique in combination with density functional theory. Three single-bonded 3-dimensional structures with space groups of P 4 3, P 4 3 2 1 2, and P 2 1 2 1 2 are discovered. We show that the P 4 3…
We derive the effective charge- and current-density operators for the strong-coupling limit of a single-band Mott insulator in the presence of spin-orbit coupling and show that the spin-orbit contribution to the effective charge density leads to novel mechanisms for multiferroic behavior. In some sense, these mechanis…
One approach for the enhancement of oral drug bioavailability is the technique of nanoparticle preparation. Risedronate sodium (Biopharmaceutical Classification System Class III) was chosen as a model compound with high water solubility and low intestinal permeability. Eighteen samples of risedronate sodium were prepa…
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Lyophilisomes are a novel class of biodegradable proteinaceous nano/micrometer capsules with potential use as drug delivery carrier. Cell-penetrating peptides (CPPs) including the TAT peptide have been successfully implemented for intracellular delivery of a broad variety of cargos including various nanoparticulate ph…
How evolution has affected enzyme function is a topic of great interest in the field of biophysical chemistry. Evolutionary changes from Escherichia coli dihydrofolate reductase (ecDHFR) to human dihydrofolate reductase (hsDHFR) have resulted in increased catalytic efficiency and an altered dynamic landscape in the hu…
The photoisomerization dynamics of trans-stilbene have been well studied in the lowest excited state, but much less is known about the behavior following excitation to higher-lying electronically excited states. This contribution reports a combined study of the spectroscopy and dynamics of two-photon accessible states…
This paper develops the solution for the generalized thermoelastic vibration of an axially moving microbeam resonator induced by sinusoidal pulse heating. The system of governing equations is reduced to a novel six-order thermoelastic differential equation in terms of either deflection or temperature. The Laplace tran…
We present a unified description for time-resolved electron and photon scattering spectroscopies from molecules prepared in nonstationary states. Signals are expressed in terms of superoperator Green's functions and a systematic procedure for treating various degrees of freedom consistently at different levels of theo…
The self-assembly process from a 1 : 1 to a 1 : 2 complex, facilitated by para-sulfonatocalix[6]arenes (SC6) as host and methyl viologen (MV(2+)) as guest, was analyzed at the single-molecule level through an α-hemolysin nanopore. Especially, the assembled complex structures were discriminated in real time in the mixt…
Multigas sensing is highly demanded in the fields of environmental monitoring, industrial production, and coal mine security. Three near-infrared emission wavelengths from PbSe quantum dots (QDs) were used to analyze the concentration of three gases simultaneously through direct absorption spectroscopy, including acet…
We recently introduced ENCoM, an elastic network atomic contact model, as the first coarse-grained normal mode analysis method that accounts for the nature of amino acids and can predict the effect of mutations on thermostability based on changes vibrational entropy. In this proof-of-concept article, we use pairs of m…
We report for the first time how electrophoretic migration of ions and charged nanoparticles (NPs) in low electrolyte concentration solutions affects positive feedback in scanning electrochemical microscopy (SECM). The strength of the electric field in the gap between either the tip and the substrate, or the tip and c…
This study is focused on thermoresponsive glycogen-graft-poly(2-alkyl-2-oxazolines), a new group of nanostructured hybrid dendrimeric stimuli-responsive polymers connecting the body’s own biodegradable polysaccharidic dendrimer glycogen with the widely tuneable thermoresponsive behavior of polypeptide-analogic poly(2-…
Enhanced Corrosion Resistance of Co-Sn Alloy Coating with a Self-Organized Layered Structure Electrodeposited from Deep Eutectic Solvent, Zhang, J. L., Gu, C. D., Fashu, S., Tong, Y. Y., Huang, M. L., Wang, X. L., Tu, J. P.
Abstract Decreases of up to 50% in the moisture uptake of polycyanurate networks based on 2,2-bis(4-cyanatophenyl)propane (BADCy) and 1,1-bis(4-cyanatophenyl)ethane (LECy) were observed when analogous networks containing a single methyl group ortho- to each aryl?cyanurate linkage were prepared by reduction and acid-ca…
To investigate the effect of metal implants in proton radiotherapy, dose distributions of different, clinically relevant treatment plans have been measured in an anthropomorphic phantom and compared to treatment planning predictions. The anthropomorphic phantom, which is sliced into four segments in the cranio-caudal…
In this study, photocatalytic reduction of hexavalent chromium [Cr(VI)] by amorphous FeOOH was investigated with variations in FeOOH dosage, pH, initial Cr(VI) concentration, purging gas, organic compounds and initial hydrogen peroxide concentration. Reduction and adsorption were identified as important processes for…