Materials Literature
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Abstract Ultrasound‐assisted crystallization (sonocrystallization) was used to prepare a mixture of nano‐ and micrometer‐sized crystals of the monoclinic form of paracetamol—a widely used analgesic known for its particularly problematic mechanical behavior under compression (i.e. poor tabletability). The nano‐ and mic…
Dihydrodipicolinate synthase (DHDPS), an enzyme found in most bacteria and plants, controls a critical step in the biosynthesis of l-lysine and meso-diaminopimelate, necessary components for bacterial cell wall biosynthesis. DHDPS catalyzes the condensation of pyruvate and (S)-aspartate-β-semialdehyde, forming an unst…
Perovskite phase SnTiO3 was predicted to have a large spontaneous polarization of 1.1 C/m2, but its synthesis has been unsuccessful so far. Here, we calculated the ferroelectric properties of a series of Ruddleson-Popper (RP) phase SnO(SnTiO3)n (n = 1 ∼ 6), with perovskite SnTiO3 as the ending structure (n = ∞), using…
In this work, nickel-cobalt oxide (Ni (1-x) Co x O) thin films, where x = 0, 4, 6 and 8 % have been successfully deposited on glass substrates by chemical spray pyrolysis (CSP) technique at substrate temperature of (400 °C) and thickness of about 300 nm. The structural and optical properties of these films have been s…
Shape-memory alloys are active materials, their amazing thermo-electromechanical behavior is at the basis of a variety of innovative applications. Many models have been set forth in order to describe this complex behavior. Among these the so-called Souza-Auricchio model appears as remarkably simple in terms of mechani…
A series of PEI/PP blends were injection molded by conventional and microcellular methods. Polypropylene (PP) was selected as the disperse phase in order to improve the cell nucleation of poly(ether imide) (PEI)/PP blends. The effect of the PP content on the morphology of the PEI/PP blends or foams, the mechanical, th…
Carrier density $({n}_{\mathrm{s}})$ is a crucial parameter that governs the properties of correlated oxides, so the field-effect approach is an ideal tool to investigate the novel physics of the system. Here, the carrier-mediated transport of slightly doped anatase ${\mathrm{TiO}}_{2}$ epitaxial films were studied by…
A heterogeneous (DVB-resin-PPh 3 -Pd-dvds) catalyst presents high activity for the telomerization of isoprene with methanol with an unsusual regioselectivity towards tail-to-tail telomerization products.
Abstract The cubic fluorite structure Sm 0.2 Ce 0.8 O 1.9 (SDC) film was fabricated by pulsed laser deposition (PLD) to be used as electrolyte for solid oxide fuel cells (SOFCs). The SDC target was prepared by co‐precipitation process at a low sintering temperature (1,250 °C) with a relative density of 97 %. By insert…
Mössbauer studies of three two-coordinate linear high-spin Fe(2+) compounds, namely, Fe{N(SiMe3)(Dipp)}2 (1) (Dipp = C6H3-2,6-(i)Pr2), Fe(OAr')2 (2) [Ar' = C6H3-2,6-(C6H3-2,6-(i)Pr2)2], and Fe{C(SiMe3)3}2 (3), are presented. The complexes were characterized by zero- and applied-field Mössbauer spectroscopy (1-3), as w…
cis,trans- 1,3,5-Trihydroxy-1,3,5-triphenylcyclotrisiloxane was successfully isolated and fully characterized by spectroscopic methods and single-crystal X-ray diffraction. This compound was believed to be highly unstable and only exist as a transient species in low concentration during the condensation reaction of ph…
Explore the impact of the surface oxygen species of mesoporous metal oxides on propane oxidation reaction.
The effects of systematic change in the alkyl chain appended to the thiazole moiety on supramolecular gelation and nanoparticle synthesis were investigated.
A small-size metamaterial perfect absorber operating at low frequency is proposed. Due to the special design, the unit-cell dimension with respect to wavelength is very small, a/ λ ∼ 1/17, at the absorption frequency of 377 MHz. The absorption frequency is strongly dependent on the length of zigzag wire. In addition,…
Directional wettability, i.e. variation of wetting properties depending on the surface orientation, can be achieved by anisotropic surface texturing.A new high precision process can produce homogeneous sinusoidal surfaces (in particular parallel grooves) at the microscale, with a nano-scale residual roughness five ord…
Semiconducting nanowires made of discotic columnar liquid crystals can be obtained by impregnation into solid nanoporous templates, and provide new opportunities to tailor devices for organic electronics with promising charge carriers transport properties. These properties are tightly related to the self-assembly and…
Multifunctional nanoparticles (NPs) have been designed for a variety of cell imaging and therapeutic applications, and the study of their cellular interactions is crucial to the development of more efficient biomedical applications. Among current nanomaterials, concave core-shell NPs with complex angled geometries are…
We have investigated the dynamic behaviour of the magnetization of a hydrogen-bonding linked Co(II) 1D supramolecular coordination polymer. In the structure, two different mononuclear Co(II) species are linked by O–H···N hydrogen bonding through coordinated H2O and . Field-induced slow magnetic relaxation effect is ob…
Uptake of nanoparticles (NPs) affects cell migration but the mechanism remains poorly understood. In this study, the amphiphilic block PCL-PEG nano-micelles with well-controlled hydrophilic/hydrophobic chains were used to investigate the effect of internalized nano-micelles on cancer cell migration. Our results indica…
It is shown that the sensing performance of perylene sensors can be modulated by alkylsilane chains on the bay regions.