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Spectral diffusion of neutral and charged exciton transitions in single CdSe/ZnS nanocrystals due to quantum-confined Stark effect

Toshiyuki Ihara、Yoshihiko Kanemitsu2014-11-04Physical Review B

Photoluminescence (PL) fluctuations of single semiconductor nanocrystals (NCs), such as PL blinking and spectral diffusion (SD), reflect the quantum nature of charges in the NCs. Through simultaneous measurements of PL spectra and lifetimes on single CdSe/ZnS NCs, PL of neutral excitons is found to exhibit a unique be…

Semiconductor Quantum Structures and DevicesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Bifunctional Submicron Colloidosomes Coassembled from Fluorescent and Superparamagnetic Nanoparticles

Tobias Bollhorst、Shakiba Shahabi、Katharina Wörz 等 7 位作者2014-11-04Angewandte Chemie

Abstract Colloidosomes are microcapsules consisting of nanoparticle shells. These microcarriers can be self‐assembled from a wide range of colloidal particles with selective chemical, physical, and morphological properties and show promise for application in the field of theranostic nanomedicine. Previous studies have…

Surfactants and Colloidal SystemsPickering emulsions and particle stabilizationCharacterization and Applications of Magnetic Nanoparticles

Three-dimensionalization of ultrathin nanosheets in a two-dimensional nano-reactor: macroporous CuO microstructures with enhanced cycling performance

Chuan-Yin Jin、Ming Hu、Xunliang Cheng 等 7 位作者2014-11-04Chemical Communications

Three-dimensional (3D) macroporous CuO structures composed of ultrathin nanosheets were successfully synthesized by employing a liquid-liquid interface as a two-dimensional (2D) nano-reactor. The macroporous structure helped CuO to retain the exposed surface during reactions, thus significantly enhancing the long term…

ZnO doping and propertiesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Rheological behaviour of clay incorporated natural rubber and chlorobutyl rubber nanocomposites

Ajesh K. Zachariah、V. G. Geethamma、Arup K. Chandra 等 5 位作者2014-11-04RSC Advances

The rheological behaviour of organoclay nanocomposites based on natural rubber (NR) and chlorine substituted isobutyl-isoprene rubber (CIIR), was investigated separately. For the study, an organoclay Nanomer I.44P treated with a surfactant containing hydrogenated tallow, quaternary ammonium chloride, was used. The lin…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer composites and self-healing

Amphiphilic diselenide-containing supramolecular polymers

Xinxin Tan、Liulin Yang、Zehuan Huang 等 6 位作者2014-11-04Polymer Chemistry

This communication describes the fabrication of diselenide-containing supramolecular polymers.

Supramolecular Self-Assembly in MaterialsPhotochromic and Fluorescence ChemistryPolydiacetylene-based materials and applications

Spectrum imaging of complex nanostructures using DualEELS: I. digital extraction replicas

Joanna Bobynko、Ian MacLaren、Alan J. Craven2014-11-04Ultramicroscopy

This paper shows how it is possible to use Dual Electron Energy Loss Spectroscopy (DualEELS) to digitally extract spectrum images for one phase of interest in a complex nanostructured specimen. The specific cases studied here concern Nb or V precipitates, a few nanometres in size, in high manganese steels. The procedu…

Hydrogen embrittlement and corrosion behaviors in metalsElectron and X-Ray Spectroscopy TechniquesAdvanced Materials Characterization Techniques

Synthesis and in vitro Anticancer Activity of Zinc(II) Phthalocyanines Conjugated with Coumarin Derivatives for Dual Photodynamic and Chemotherapy

Xiaoqin Zhou、Lu‐Bo Meng、Qi Huang 等 8 位作者2014-11-04ChemMedChem

The combination of photodynamic therapy and chemotherapy is a promising strategy to overcome growing problems in contemporary medicine, such as low therapeutic efficacy and drug resistance. Four zinc(II) phthalocyanine-coumarin conjugates were synthesized and characterized. In these complexes, zinc(II) phthalocyanine…

Nanoplatforms for cancer theranosticsPorphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research Studies

Modulating the phase transition between metallic and semiconducting single-layer MoS 2 and WS 2 through size effects

Ziyu Hu、Shengli Zhang、Yanning Zhang 等 6 位作者2014-11-04Physical Chemistry Chemical Physics

The first-principles calculations are performed to investigate the electronic properties and the atomic mechanism of the single layer MoS2 or WS2 homo-junction structure. The results reveal that both the stability and electronic structure of the homo-junction structure are greatly affected by the type of boundaries, w…

Graphene research and applications2D Materials and ApplicationsMXene and MAX Phase Materials

Polymer Coating of Carbon Nanotube Fibers for Electric Microcables

Noe T. Alvarez、Timothy Ochmann、Nicholas Kienzle 等 10 位作者2014-11-04Nanomaterials

Carbon nanotubes (CNTs) are considered the most promising candidates to replace Cu and Al in a large number of electrical, mechanical and thermal applications. Although most CNT industrial applications require macro and micro size CNT fiber assemblies, several techniques to make conducting CNT fibers, threads, yarns a…

Carbon Nanotubes in CompositesAdvanced Sensor and Energy Harvesting MaterialsDielectric materials and actuators

Structural behavior and dynamics of an anomalous fluid between attractive and repulsive walls: Templating, molding, and superdiffusion

Fabio Leoni、Giancarlo Franzese2014-11-04The Journal of Chemical Physics

Confinement can modify the dynamics, the thermodynamics, and the structural properties of liquid water, the prototypical anomalous liquid. By considering a generic model for anomalous liquids, suitable for describing solutions of globular proteins, colloids, or liquid metals, we study by molecular dynamics simulations…

Material Dynamics and PropertiesTheoretical and Computational PhysicsSpectroscopy and Quantum Chemical Studies

Splitting, linking, knotting, and solitonic escape of topological defects in nematic drops with handles

Mykola Tasinkevych、Michael G. Campbell、Ivan I. Smalyukh2014-11-04Proceedings of the National Academy of Sciences

Topologically nontrivial field excitations, including solitonic, linked, and knotted structures, play important roles in physical systems ranging from classical fluids and liquid crystals, to electromagnetism, classic, and quantum field theories. These excitations can appear spontaneously during symmetry-breaking phas…

Liquid Crystal Research AdvancementsOrbital Angular Momentum in OpticsAdvanced Materials and Mechanics

Conducting Leathers for Smart Product Applications

Wegene Demisie Jima、P. Thanikaivelan2014-11-04Industrial & Engineering Chemistry Research

Leather is a unique consumer material possessing a variety of properties such as strength, viscoelasticity, flexibility, and longevity. However, the use of leather for smart product applications is a challenge since it is an electrically insulating material. Here, we report a simple method to produce conducting leathe…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsAnalytical Chemistry and Sensors

Interlayer dependent polarity of magnetoresistance in graphene spin valves

Muhammad Zahir Iqbal、Muhammad Waqas Iqbal、Xiaozhan Jin 等 5 位作者2014-11-04Journal of Materials Chemistry C

We have studied the polarity of magnetoresistance (MR) in three types of magnetic junctions. While the NiFe/single layer graphene (SLG)/Co and NiFe/Al 2 O 3 /Co junctions showed spin valve signals with positive MR, the NiFe/Al 2 O 3 /SLG/Co junction revealed negative MR values.

Advancements in Battery MaterialsMagnetic properties of thin filmsGraphene research and applications

Direct low temperature hydrothermal synthesis of YFeO3 microcrystals

Andrei Racu、Daniel Ursu、O.V. Kuliukova 等 6 位作者2014-11-04Materials Letters

In this work, we present a new, fast and high yield synthesis method for obtaining microcrystalline yttrium orthoferrite YFeO3, based on hydrothermal technique. The advantage of the method consists in the direct crystallization of the material without the necessity of the calcination. The quality of the so-obtained co…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Adsorption of organic chemicals on graphene coated biochars and its environmental implications

Abdul Ghaffar、Muhammad Naeem Younis2014-11-04Green Processing and Synthesis

Abstract Biochar is a stabilized carbon-rich product, and has drawn scientists’ interest because of its specific properties and potential use in many environmental areas. It is emphasized that innovative technologies comprised of engineered nanoparticles in conventional biochar systems could ameliorate the functions o…

Graphene research and applicationsCarbon and Quantum Dots ApplicationsGraphene and Nanomaterials Applications

147% improved efficiency of dye synthesized solar cells by using CdS QDs, Au nanorods and Au nanoparticles

Omid Amiri、Masoud Salavati‐Niasari、Ali Rafiei 等 4 位作者2014-11-04RSC Advances

This work describes a cooperative quantum dot and plasmonic effect on improving the performance of dye synthesized solar cells, in which CdS QDs, gold nanoparticles (GNPs), and gold nanorods (GNRs) are incorporated into the active layer. The cooperative nanoparticles show a superior behavior on enhancing light absorpt…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesQuantum Dots Synthesis And Properties

Synthesis and magnetic properties of tartrate-bridging rare-earth-containing polytungstoarsenate aggregates from an adaptive precursor [As 2 W 19 O 67 (H 2 O)] 14−

Yuan Wang、Xiaopeng Sun、Suzhi Li 等 6 位作者2014-11-04Dalton Transactions

Six tartrate-bridging rare-earth-substituted polytungstoarsenates [RE2(C4H4O6)(C4H2O6)(As W9O33)]2(18-) (Ho(III) (1), Er(III) (2), Tm(III) (3), Yb(III) (4), Lu(III) (5), and Y(III) (6)) have been synthesized under conventional solution conditions. They have been further characterized by elemental analyses, X-ray powde…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Fabrication and characterization of nano-structured ZnS thin films as the buffer layers in solar cells

Alireza Goudarzi、Azimeh Dorbeygi Namghi、Chang‐Sik Ha2014-11-04RSC Advances

High quality nanocrystalline ZnS thin films were deposited on glass substrates by a chemical bath deposition (CBD) method from an aqueous solution containing triethylamine, as a nontoxic complexing agent for zinc ions, at temperatures ranging from 50 to 90 °C. The effects of the deposition time and temperature on thic…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Superhydrophobic Analyte Concentration Utilizing Colloid-Pillar Array SERS Substrates

Ryan A. Wallace、Jennifer J. Charlton、Teresa B. Kirchner 等 6 位作者2014-11-04Analytical Chemistry

The ability to detect a few molecules present in a large sample is of great interest for the detection of trace components in both medicinal and environmental samples. Surface enhanced Raman spectroscopy (SERS) is a technique that can be utilized to detect molecules at very low absolute numbers. However, detection at…

Gold and Silver Nanoparticles Synthesis and ApplicationsBiosensors and Analytical DetectionNanomaterials and Printing Technologies