Materials Literature
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Stress development and fracture of isolated cristobalite spherulites in amorphous silica matrix were observed. High purity bulk silica was annealed to produce partial surface crystallization consisting of isolated and impinged spherulites in an amorphous matrix. The stress state of the amorphous silica surrounding cri…
Grain boundary and triple junction diffusion in nanocrystalline Cu samples with grain sizes, 〈d〉, of ∼35 and ∼44 nm produced by spark plasma sintering were investigated by the radiotracer method using the 63Ni isotope. The measured diffusivities, Deff, are comparable with those determined previously for Ni grain bound…
We present a first-principles investigation of the electronic structure and physical properties of doped lithium nitridometalates ${\mathrm{Li}}_{2}$(${\mathrm{Li}}_{1\ensuremath{-}x}{\mathrm{M}}_{x}$)N (LiMN) with M = Cr, Mn, Fe, Co, and Ni. The diverse properties include the equilibrium magnetic moments, magneto-cry…
The 3d transition metal (M) perovskite oxides exhibit a remarkable array of properties, including novel forms of superconductivity, magnetism and multiferroicity. Strain can have a profound effect on many of these properties. This is due to the localized nature of the M 3d orbitals, where even small changes in the M–O…
The present article reports the development of soft nanohybrids comprising of single walled carbon nanotube (SWCNT) included silver nanoparticles (AgNPs) having superior antibacterial property. In this regard aqueous dispersing agent of carbon nanotube (CNT) containing a silver ion reducing unit was synthesised by the…
This study aims to produce reducing sugar hydrolyzed from substrate, coconut coir dust pretreated by recycled ionic liquid and its combination with alkaline. The 1H NMR and FTIR were performed to ver-ify the synthesized ionic liquid methylmethylimidazolium dimethyl phosphate ([mmim][dmp]). The structure of pretreated…
In this work, a new model was suggested to simulate the paste boriding process. This model was based on the numerical solving of the diffusion equations in both boride layer and substrate by taking into account the displacement of (Fe2B/substrate) interface. This diffusion problem with moving boundary was solved via a…
The n-ZnO/p-Si heterojunction with an ultrathin Al₂O₃ buffer layer was prepared by atomic layer deposition. X-ray diffraction revealed that the crystalline quality of (100)-oriented ZnO films was improved with an Al₂O₃ buffer layer. The n-ZnO/p-Si heterojunction with 5 nm inserted Al₂O₃ layer shows the best electrical…
Purpose: To encapsulate paclitaxel into nanoliposomes, followed by pegylatation, in order to improve its therapeutic index and reduce side effects in breast cancer.Methods: In order to prepare nanoliposomal paclitaxel, varying ratios of phosphatidylcholine, cholesterol and paclitaxel were mixed and the formulations pe…
An aminohydroxylated polyester fabric with durable antibacterial activity, enhanced hydrophilicity and improved mechanical properties was prepared in one single step process. In the proposed method, synthesis of silver nanoparticles was carried out along with the aminohydrolysis of polyester fabric using triethanolami…
In recent years, poly (amido amine) (PAMAM) dendrimers have become a research focus in biomineralization fields. In this study, polyhydroxy-terminated PAMAM dendrimers (PAMAM-OH) were used to induce dentinal tubule occlusion. Demineralized dentin samples were coated with the second generation or the fourth generation…
Creating a facile and efficient method that can provide large-scale, highly aligned, and high strength nanofibers has proved extremely challenging. This work responds to these challenges by designing and evaluating poly(m-phenylene isophthalamide) (PMIA) nanofibrous materials with robust mechanical strength, which can…
Lactic acid is one of the top 30 potential building-block chemicals from biomass, of which the most extensive use is in the polymerization of lactic acid to poly-lactic-acid (PLA). To reduce the cost of PLA, the search for cheap raw materials and low-cost process for lactic acid production is highly desired. In this s…
Two new Geissleria species from Siberian mountain lakes Baikal and Frolikha are described based on molecular and morphological data. The two new species are Geissleria baicalosimilis Kulikovskiy, Gusev, Andreeva & Annenkova sp. nov. and G. frolikhiensis Kulikovskiy, Gusev, Andreeva & Annenkova sp. nov. According to pa…
This communication reports the development of a unique gel-based adsorbent for wastewater treatment using a new low molecular weight gelator. The most interesting aspect of this technique is that the ligand not only gelled potentially toxic metals, like lead and cadmium, but that it also simultaneously adsorbed toxic…
We have carried out thickness dependent first-principles electronic structure calculations on ultra-thin films of transition-metal dichalcogenides MX2 (M = Mo or W; X = S, Se, or Te). When spin-orbit coupling (SOC) is included in the computations, monolayer MX2 thin films display spin-split states around the valence b…
The development of a simple yet novel aqueous solution based ‘one-pot’ method has been reported for the preparation of nanocomposites composed of soft ferrite (Mn0.2Ni0.4Zn0.4Fe2O4) and hard ferrite (BaFe12O19) phases. A physical mixing method has also been employed to prepare nanocomposites having the same compositio…
Global optimization is used to study the structure of the polar KTaO3 (001) surface. It is found that cation exchange near the surface leads to the most stable structure. This mechanism is likely to be general to metal oxides containing cations of differing charge.
Nanostructuring of graphene is in part motivated by the requirement to open a gap in the electronic band structure. In particular, a periodically perforated graphene sheet in the form of an antidot lattice may have such a gap. Such systems have been investigated with a view towards application in transistor or wavegui…
In this paper, we numerically demonstrate the advantage of utilizing continuous amplitude and phase modulation in super-oscillation focusing lens design. Numerical results show that compared with simple binary amplitude modulation, continuous amplitude and phase modulation can greatly improve the super-oscillation foc…