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Structure‐properties relationship in resol/montmorillonite nanocomposites

Liliana B. Manfredi、Débora Puglia、J. M. Kenny 等 4 位作者2007-03-05Journal of Applied Polymer Science

Abstract Polymer/layered silicate nanocomposites were prepared, adding modified, and nonmodified montmorillonites to a resol resin. It was observed that the composites exhibited an intercalated disordered structure by means of X‐ray diffraction (XRD) and transmission electronic microscopy. The crosslinking density of…

Polymer Nanocomposites and PropertiesSynthesis and properties of polymersSilicone and Siloxane Chemistry

Hydrogen‐bond acidic polyhedral oligosilsesquioxane filled polymer coatings for surface acoustic wave sensors

Claire Hartmann‐Thompson、Douglas L. Keeley、Petar R. Dvornić 等 5 位作者2007-03-05Journal of Applied Polymer Science

Abstract A series of novel polyhedral oligosilsesquioxane nanofiller compounds functionalized with hydrogen‐bond acidic sensor groups was prepared, characterized by IR, 1 H‐, 13 C‐ and 29 Si‐NMR, and MALDI‐TOF MS, and formulated into polymer coatings for 500 MHz surface acoustic wave sensor platforms. Sensor responses…

Analytical Chemistry and SensorsMarine Biology and Environmental ChemistrySilicone and Siloxane Chemistry

Direct evidence on magnetic-field-induced phase transition in a NiCoMnIn ferromagnetic shape memory alloy under a stress field

Yandong Wang、Yang Ren、E‐Wen Huang 等 11 位作者2007-03-05Applied Physics Letters

The magnetoelasticity and magnetoplasticity behaviors of a Ni–Co–Mn–In ferromagnetic shape memory alloy (FSMA) induced by the reverse phase transformation interplayed under multiple (temperature, magnetic, and stress) fields were captured directly by high-energy synchrotron x-ray diffraction technique. The experiments…

Shape Memory Alloy Transformations

Dual-mode switching of a liquid crystal panel for viewing angle control

Jong‐In Baek、Yong‐Hoan Kwon、Jae Chang Kim 等 4 位作者2007-03-05Applied Physics Letters

The authors propose a method to control the viewing angle of a liquid crystal (LC) panel using dual-mode switching. To realize both wide viewing angle (WVA) characteristics and narrow viewing angle (NVA) characteristics with a single LC panel, the authors use two different dark states. The LC layer can be aligned homo…

Liquid Crystal Research AdvancementsAdvanced Optical Imaging TechnologiesOptical Polarization and Ellipsometry

The response to antioxidants in base oils of different degrees of refining

Per Wiklund2007-03-05Lubrication Science

Abstract Base oils with different compositions and different degrees of refining have been subjected to three types of oxidation stability tests in the presence of antioxidants. A higher degree of refining of base oils depletes the natural antioxidants present in oils of lower degree of refining. However, the results…

Thermal and Kinetic AnalysisChemical Thermodynamics and Molecular StructureFree Radicals and Antioxidants

Nanocomposites based on poly(ϵ‐caprolactone) and the montmorillonite treated with dibutylamine‐terminated ϵ‐caprolactone oligomer

Mitsuhiro Shibata、Naozumi Teramoto、Yoshihiro Someya 等 4 位作者2007-03-05Journal of Applied Polymer Science

Abstract Dibutylamine‐terminated ε‐caprolactone oligomers (CLOs: CLOL, CLOM, and CLOH) with number–averaged molecular weight ( M n ), 500, 1300, and 2200, respectively, were synthesized by the ring‐opening polymerization of ε‐caprolactone initiated by 2‐(dibutylamino)ethanol in the presence of tin(II) 2‐ethylhexanoate…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Crystallinity variations in the double yield region of polyethylene

A. Manzur、J. I. Rivas2007-03-05Journal of Applied Polymer Science

Abstract Numerous specimens of a linear low density polyethylene sample were uniaxially deformed up to different elongations to study the double yield phenomenon. Extruded samples were analyzed to calculate the crystallinity and to estimate the mean crystal size, under stressed state and released state (after removal…

Mechanical Behavior of CompositesPolymer crystallization and propertiesNatural Fiber Reinforced Composites

Poly(methyl methacrylate) toughened by ethylene‐vinyl acetate copolymer: Physico‐mechanical, thermal, and chemical properties

P. Poomalai、B. Ramaraj、Siddaramaiah2007-03-05Journal of Applied Polymer Science

Abstract Blends of poly(methyl methacrylate) (PMMA) with different composition viz., 5, 10, 15, and 20 wt % of ethylene‐vinyl acetate (EVA) copolymer were prepared by extrusion in a corotating twin screw extruder. These prepared PMMA/EVA blends have been characterized for physicomechanical properties such as density,…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Properties of anionic polymerized ε‐caprolactam in the presence of carbon nanotubes

K. Kelar、B. Jurkowski2007-03-05Journal of Applied Polymer Science

Abstract The results of the investigations of the relations between structure, physical and usage properties of polyamide 6 (PA6) reinforced with multiwall carbon nanotubes (MWNTs) are presented. A method of in situ anionic bulk polymerization of ε‐caprolactam in the presence of MWNTs was used for the preparation of r…

Carbon Nanotubes in CompositesPolymer Nanocomposites and PropertiesConducting polymers and applications

Aging in attraction-driven colloidal glasses

Antonio M. Puertas、Matthias Fuchs、Michael E. Cates2007-03-05Physical Review E

Aging in an attraction-driven colloidal glass is studied by computer simulations. The system is equilibrated without attraction and instantaneously "quenched," at constant colloid volume fraction, to one of two states beyond the glass transition; one is close to the transition, and the other one deep in the glass. The…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesTheoretical and Computational Physics

Origins of shallow level and hole mobility in codoped p-type ZnO thin films

H. B. Ye、Jinzhen Kong、Wenzhong Shen 等 5 位作者2007-03-05Applied Physics Letters

A combination study of structural, optical, and electrical properties has been carried out on N–In codoped p-type ZnO thin films for the origins of shallow level and hole mobility. The observed small activation energy of ∼20meV for the hole concentration corresponds well to the results from photoluminescence and condu…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsCopper-based nanomaterials and applications

Formation of poly‐vinyl‐alcohol structures by supercritical CO2

Ernesto Reverchon、Stefano Cardea、Christopher J. Rapuano2007-03-05Journal of Applied Polymer Science

Abstract Poly‐vinyl‐alcohol (PVA) porous structures have been prepared using a supercritical phase inversion process in which supercritical carbon dioxide (SC‐CO 2 ) acts as the nonsolvent. First, we tested the versatility of the SC‐CO 2 phase inversion process, forming PVA/dimethylsulfoxide (DMSO) solutions with poly…

Phase Equilibria and ThermodynamicsInjection Molding Process and PropertiesPolymer Foaming and Composites

Identification of Mn site in Pb(Zr,Ti)O3 by synchrotron x-ray absorption near-edge structure: Theory and experiment

Sukit Limpijumnong、Saroj Rujirawat、Adisak Boonchun 等 5 位作者2007-03-05Applied Physics Letters

Synchrotron x-ray absorption near-edge structure (XANES) experiments are performed on Mn-doped PbZr1−xTixO3 samples (PZT) and compared with first-principles XANES simulations. The features of the measured Mn K-edge XANES are consistent with the first-principles XANES of Mn on the Ti∕Zr site and inconsistent with Mn on…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Effect of poly(ethylene‐ co ‐glycidyl methacrylate) compatibilizer content on the morphology and physical properties of ethylene vinyl acetate–wood fiber composites

D. G. Dikobe、A. S. Luyt2007-03-05Journal of Applied Polymer Science

Abstract In this study, ethylene vinyl acetate (EVA)–wood fiber (WF) (uncompatibilized) and EVA/poly(ethylene‐ co ‐glycidyl methacrylate) (EGMA)‐WF (compatibilized) were blended, and their morphology as well as mechanical, thermal, O 2 permeability, and water absorption properties were investigated. It is shown that t…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research Studiesbiodegradable polymer synthesis and properties

Angle-resolved x-ray absorption near edge structure study of vertically aligned single-walled carbon nanotubes

Zhongrui Li、Liang Zhang、Daniel E. Resasco 等 5 位作者2007-03-05Applied Physics Letters

Vertically aligned single-walled carbon nanotube (SWNT) forest was studied by using angular-dependent C K-edge x-ray absorption near edge structure (XANES) with linearly polarized x-ray beam. The XANES analysis found a crust of entangled nanotubes on top of the forest formed at the first stage of the forest growth, wh…

Carbon Nanotubes in CompositesGraphene research and applicationsCrystallography and Radiation Phenomena

Ultra‐thin SiO 2 on Si VIII. Accuracy of method, linearity and attenuation lengths for XPS

Kyung Joong Kim、M. P. Seah2007-03-05Surface and Interface Analysis

Abstract In the study of ultra‐thin films (<10‐nm thick), there is a range of methods that can provide accurate measurements of differences in thickness. However, in a pilot study under the auspices of the Consultative Committee for Amount of Substance (CCQM), results for the archetypal system of SiO 2 on Si show t…

Advancements in Photolithography TechniquesX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques

Electron inelastic mean free paths: influence of the modelling energy‐loss function

W. De la Cruz、F. Yubero2007-03-05Surface and Interface Analysis

Abstract Accurate quantitative surface analysis using electron spectroscopies is of paramount importance in nanoscale‐based technology of today. In this context, an appropriate description of the electron inelastic mean free paths (IMFP) is mandatory. We have studied the influence of several model dielectric descripti…

Semiconductor materials and devicesElectron and X-Ray Spectroscopy TechniquesSurface and Thin Film Phenomena

Computational tool to model the packing of polycyclic chains: Structural analysis of amorphous polythiophene

David Curcó、Carlos Alemán2007-03-05Journal of Computational Chemistry

A very efficient computational procedure, which was previously developed to generate and relax atomistic models of linear and comb-like amorphous polymers, has been adapted to model the amorphous phase of polycyclic systems. The strategy, which is a based in a generation algorithm that eliminates the torsion strain an…

Organic Electronics and PhotovoltaicsPolymer Nanocomposites and PropertiesConducting polymers and applications

Flexible field emitter made of carbon nanotubes microwave welded onto polymer substrates

C. Y. Wang、T. H. Chen、Shih-Chin Chang 等 5 位作者2007-03-05Applied Physics Letters

The drastic temperature rise of multiwall carbon nanotubes (MWCNTs) in response to microwave irradiation was applied to weld a MWCNT paste on a polymer substrate within a few seconds. It provides a strong bonding between the MWCNT and polymer without thermal damage to the substrate. A flexible field emitter was made f…

Carbon Nanotubes in CompositesGraphene research and applicationsMolecular Junctions and Nanostructures

Hyperbranched Polyesters with Carboxylic or Sulfonic Acid Functional Groups for Crystallization Modification of Calcium Carbonate

Qingwei Meng、Dongzhong Chen、Tianchun Ye 等 6 位作者2007-03-05Macromolecular Chemistry and Physics

Abstract Hyperbranched aliphatic polyesters functionalized with carboxylic or sulfonic acid groups have been synthesized and employed as crystallization modifiers for calcium carbonate. The functionalized polyesters exhibit remarkable polymorph selectivity and morphology control. Stable spherical vaterite particles of…

Polymer Surface Interaction StudiesSynthetic Organic Chemistry MethodsDendrimers and Hyperbranched Polymers