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Tautomeric state and pKa of the phosphorylated active site histidine in the N‐terminal domain of enzyme I of the Escherichia coli phosphoenolpyruvate: Sugar phosphotransferase system

Daniel S. Garrett、G. Marius Clore、Angela M. Gronenborn 等 5 位作者1998-03-01Protein Science

The phosphorylated form of the N-terminal domain of enzyme I of the phosphoenolpyruvate:sugar phosphotransferase system of Escherichia coli has been investigated by one-bond and long-range 1H-15N correlation spectroscopy. The active site His 189 is phosphorylated at the Nepsilon2 position and has a pKa of 7.3, which i…

Protein Structure and DynamicsRNA and protein synthesis mechanismsEnzyme Structure and Function

Relationship between Intracellular Phosphate, Proton Motive Force, and Rate of Nongrowth Energy Dissipation (Energy Spilling) in Streptococcus bovis JB1

Daniel R. Bond、James B. Russell1998-03-01Applied and Environmental Microbiology

When the rate of glucose addition to nongrowing Streptococcus bovis cell suspensions was increased, the fermentation was homolactic, fructose-1,6-diphosphate (FDP) increased, intracellular inorganic phosphate (P(i)) declined, and the energy-spilling rate increased. ATP and ADP were not significantly affected by glucos…

Protein purification and stabilityEnzyme Structure and FunctionBiochemical and Molecular Research

Silica Supported Methyltrioxorhenium Complex of γ-(2,2′-Dipyridyl)-aminopropylpolysiloxane as a Novel Catalyst for Epoxidation of Alkenes

Tao Wang、D. C. Li、Jing Bai 等 5 位作者1998-03-01Journal of Macromolecular Science Part A

Silica supported methyltrioxorhenium complex of γ-(2,2′-dipyridyl)-aminopropyl polysiloxane (III) has been synthesized and demonstrated as a novel catalyst of high activity, stability and improved selectivity for epoxidation of alkenes with hydrogen peroxide at room temperature. The catalyst can be recycled at least f…

Metal-Organic Frameworks: Synthesis and ApplicationsPorphyrin and Phthalocyanine ChemistryPolyoxometalates: Synthesis and Applications

Effect of Ag or Cu doping on erasable phase-change Sb-Te thin films

Yi-Ming Chen、Pei-Wen Kuo1998-03-01IEEE Transactions on Magnetics

The crystallization process of the Ag or Cu doped Sb/sub 2/Te/sub 3/ amorphous film was investigated by isothermal treatment for one hour at 100/spl deg/C, 200/spl deg/C and 300/spl deg/C respectively. The crystallization temperatures of Ag/sub 8.3/Sb/sub 34.9/Te/sub 56.8/ and Cu/sub 8.4/Sb/sub 35.1/Te/sub 56.5/ films…

Chalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenidesOptical and Acousto-Optic Technologies

Enhanced Co orbital moments in Co–rare-earth permanent-magnet films

D. J. Keavney、Eric E. Fullerton、Dongqi Li 等 8 位作者1998-03-01Physical review. B, Condensed matter

Soft x-ray magnetic circular dichroism (MCD) data were collected at the Co $L$ edges from a series of epitaxial $R\ensuremath{-}\mathrm{Co}$ ($R=\mathrm{P}\mathrm{r},\phantom{\rule{0ex}{0ex}}\mathrm{N}\mathrm{d},\phantom{\rule{0ex}{0ex}}\mathrm{S}\mathrm{m},\phantom{\rule{0ex}{0ex}}\mathrm{D}\mathrm{y},\phantom{\rule{…

Magnetic properties of thin filmsRare-earth and actinide compoundsMagnetic Properties of Alloys

Atmospheric Corrosion of Copper in the Presence of Acid Ammonium Sulfate Particles

R. E. Lobnig、C. A. Jankoski1998-03-01Journal of The Electrochemical Society

Basic copper sulfates, , and cuprite, , are the major corrosion products found during field exposure of copper. The active species of the atmosphere which lead to formation of these corrosion products are, however, still uncertain. In this study, we investigated whether submicron acid ammonium sulfate particles, , can…

Corrosion Behavior and InhibitionConcrete Corrosion and DurabilitySmart Materials for Construction

Dynamic model of magnetic materials applied on soft ferrites

P. Tenant、Jean Jacques Rousseau1998-03-01IEEE Transactions on Power Electronics

A behavioral model of magnetic materials is presented. This model takes into account both hysteresis and dynamic phenomena. It predicts B(H), /spl phi/(t) and d/spl phi/(t)/dt characteristics, and a few pieces of experimental data are needed to identify its parameters. In this paper, the authors propose to validate th…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsNon-Destructive Testing Techniques

Axial Ligand Effects in Sterically Strained Porphyrins: A Crystallographic Study of Five- and Six-coordinated Metal Complexes of 2,3,7,8,12,13,17,18-Octaethyl-5,10,15,20-tetranitroporphyrin

Mathias O. Senge1998-03-01Journal of Porphyrins and Phthalocyanines

Porphyrins with steric hindrance at the periphery are known to exhibit severely non-planar macrocycle conformations. Among other dodecasubstituted porphyrins, the title compound has been studied widely and shows a typical saddle-distorted macrocycle. The specific conformation of the porphyrin leads to the formation of…

Porphyrin and Phthalocyanine ChemistryNeonatal Health and BiochemistryPorphyrin Metabolism and Disorders

Volume-Phase Holographic Gratings and their Potential for Astronomical Applications

Samuel C. Barden、James A. Arns、W. S. Colburn1998-03-01OpenAlex

A diffraction grating technology based upon volume-phase holograms shows promise of enhanced performance for many applications in astronomical spectroscopy over classical surface-relief grating technology. We present a discussion of the underlying physics of a volume-phase grating, give some theoretical performance ch…

Photorefractive and Nonlinear OpticsAdaptive optics and wavefront sensingOptical Coatings and Gratings

The effect of block braking on the residual stress state of a solid railway wheel

Giorgio Donzella、M Scepi、Luigi Solazzi 等 4 位作者1998-03-01Proceedings of the Institution of Mechanical Engineers Part F Journal of Rail and Rapid Transit

A finite element, numerical model of a solid railway wheel was perfected permitting the simulation of a block braking operation. The analyses performed, backed by experimental tests, permitted the degree of variation in the residual stress state (induced by differential quenching heat treatment and successive temperin…

Railway Engineering and DynamicsMechanical stress and fatigue analysisMetal Alloys Wear and Properties

Time-Resolved Small-Angle Static Light Scattering on Lysozyme during Nucleation and Growth

Patrick Umbach、Yannis Georgalis、Wolfram Saenger1998-03-01Journal of the American Chemical Society

Hen egg white lysozyme was employed for studying aggregation and nucleation events induced by simple electrolytes such as NaCl while the process was monitored by time-resolved, small-angle static light scattering. The fractal dimension, the weight-average molecular weight, the mean radius of gyration and the homogenei…

Spectroscopy and Quantum Chemical StudiesCrystallization and Solubility StudiesProtein Interaction Studies and Fluorescence Analysis

Corrosion Consequences of Secondary Oxidation of Microbial Corrosion

T. R. Jack、M. Wilmott、J. Stockdale 等 6 位作者1998-03-01CORROSION

Microbial corrosion scenarios based on the action of sulfate-reducing bacteria (SRB) under disbonded tape coatings on the outside of gas pipelines have been described previously. Secondary oxidation of these sites leads to formation of unique corrosion products. These have been associated with serious corrosion damage…

Corrosion Behavior and InhibitionOdor and Emission Control TechnologiesConcrete Corrosion and Durability

On the consideration of climb in discrete dislocation dynamics

Dierk Raabe1998-03-01Philosophical magazine. A/Philosophical magazine. A. Physics of condensed matter. Structure, defects and mechanical properties

A concept is outlined to incorporate dislocation climb in a discrete three-dimensional model of dislocation dynamics. Each dislocation line consists of a sequence of interconnected piecewise straight segments which are embedded in a homogeneous linear elastic medium. The dynamics are described by solving Newton's equa…

Microstructure and mechanical propertiesAluminum Alloy Microstructure PropertiesHigh Temperature Alloys and Creep

In Situ Study of Single Aqueous Droplet Solidification of Ceramic Precursors Used for Spray Pyrolysis

Chak K. Chan、Richard C. Flagan、John H. Seinfeld1998-03-01Journal of the American Ceramic Society

The electrodynamic balance (EDB) is demonstrated to be useful for the in situ study of aqueous droplet solidification. We have used an EDB to study the solidification of solution droplets used for ceramic powder synthesis by spray pyrolysis. The mass change and the elastic light scattering of the drying 20 μm solution…

Calcium Carbonate Crystallization and InhibitionChemical Looping and Thermochemical ProcessesThermal and Kinetic Analysis

Effect of Various Treatments on Carbon Fiber Surfaces Studied by Raman Microprobe Spectrometry

Ana Cuesta、P. Dhamelincourt、J. Laureyns 等 5 位作者1998-03-01Applied Spectroscopy

High-modulus and high-strength carbon fibers were submitted to oxidation plus sizing and grinding treatments. Subsequent changes at the fiber surfaces were studied by Raman spectrometry. X-ray diffractograms and Raman spectra of the fresh fibers were compared with those of other carbon materials with different graphit…

Carbon Nanotubes in CompositesGraphene research and applicationsDiamond and Carbon-based Materials Research

Sol–gel synthesis of ceramic matrix composites

Eric D. Rodeghiero、C. J. Moore、B.S Wolkenberg 等 6 位作者1998-03-01Materials Science and Engineering A

Sol–gel techniques have been used to produce various high temperature ceramic matrix composites including Ni/α-Al2O3, Fe/α-Al2O3, Ni/ZrO2, SiC(whisker)/α-Al2O3, and SiC(platelet)/α-Al2O3, as well as chemically modified versions of some of these systems. In all cases, the composites have displayed uniform microstructur…

Advanced ceramic materials synthesisAdvanced materials and compositesNuclear materials and radiation effects

The cytoplasmic fine structure of the diatom Haslea ostrearia (Bacillariophyceae) in relation to marennine production

Youssef Nassiri、Jean‐Michel Robert、Yves Rincé 等 4 位作者1998-03-01Phycologia

The fine structure of Haslea ostrearia Simonsen, a diatom that is able to synthesize a blue pigment (marennine), is described. Ultrastructurally, this microalga has a typical naviculoid organization, but marked changes occur depending on the stage of cell blueing by accumulation of marennine. A comparison of the ultra…

Algal biology and biofuel productionMass Spectrometry Techniques and ApplicationsDiatoms and Algae Research

Method For Studying Surface Topography and Roughness of Onion and Garlic Skins For Coating Purposes

V. Hershko、David W. Weisman、A. Nussinovitch1998-03-01Journal of Food Science

ABSTRACT Surface topography and roughness of garlic and onion skins were studied by atomic force microscopy in order to estimate the surface area. Image‐processing and Arc/Info software were used to interpret the data. The calculated ratio between apparent and measured surfaces (roughness factor) deviated from 1.11 to…

Surface Modification and SuperhydrophobicityPhotonic Crystals and ApplicationsDyeing and Modifying Textile Fibers

Study of additive compatibility with poly(vinyl chloride) (PVC). 2: Dynamic mechanical analysis of PVC lubrication by stearic acid and its derivatives

Michael H. Fisch、Radu Bacaloglu1998-03-01Journal of Vinyl and Additive Technology

Abstract The glass transition temperatures of PVC containing stearic acid derivatives as lubricants have been used to define two new parameters of lubrication: the saturation concentration and the efficiency constant . The saturation concentration represents the maximum amount of lubricant compatible with PVC in a spe…

Advanced Polymer Synthesis and CharacterizationPolymer Nanocomposites and PropertiesPolymer Science and PVC

Quantitative Comparison of Transmission Electron Microscopy Techniques for the Study of Localized Ordering on a Nanoscale

Xiaoqing Pan、Wayne D. Kaplan、M. Rühle 等 4 位作者1998-03-01Journal of the American Ceramic Society

Different transmission electron microscopy techniques have been compared for the detection and size measurements of ordered regions on a nanometer scale in a disordered matrix phase. As a model system, the perovskite lead magnesium niobate doped with varying amounts of La has been chosen for the present study. While s…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsElectronic and Structural Properties of Oxides