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Crystal Structure Modeling of a Highly Disordered Potassium Birnessite

Kerry L. Holland、J.R. Walker1996-12-01Clays and Clay Minerals

Abstract The structure of a highly disordered synthetic birnessite was studied by comparing powder X-ray diffraction (XRD) data with calculated patterns generated by BIRNDIF and WILDFIRE© in an attempt to describe the nature of disorder and to estimate the size of the coherent diffracting domains. The material has a t…

Crystal Structures and PropertiesAdvanced Condensed Matter PhysicsX-ray Diffraction in Crystallography

Structure and dynamics of primary hydration shell of phosphatidylcholine bilayers at subzero temperatures

Chen-Hsi Hsieh、Wenzhi Wu1996-12-01Biophysical Journal

Deuterium NMR relaxation and intensity measurements of the 2H-labeled H2O/dimyristoyl phosphatidylcholine bilayer were performed to understand the molecular origin of the freezing event of phospholipid headgroup and the structure and dynamics of unfrozen water molecules in the interbilayer space at subzero temperature…

Lipid Membrane Structure and BehaviorMaterial Dynamics and PropertiesSpectroscopy and Quantum Chemical Studies

X‐ray Photoelectron Spectroscopy Investigation on the Low‐Temperature Degradation of 2 mol% Y 2 O 3 ‐ZrO 2 Ceramics

Jing‐Feng Li、Ryuzo Watanabe、Bo‐Ping Zhang 等 5 位作者1996-12-01Journal of the American Ceramic Society

2 mol% Y 2 O 3 ‐ZrO 2 polycrystals were annealed in water and under vacuum to highlight the effect of the presence of H 2 O on the low‐temperature degradation transformation. The specimen surfaces with monoclinic phases transformed during annealing in the different environments were analyzed by X‐ray photoelectron spe…

Advanced ceramic materials synthesisAdvanced materials and compositesNuclear materials and radiation effects

Composite polyaniline/calixarene Langmuir - Blodgett films for gas sensing

Nickolay V. Lavrik、Danilo De Rossi、Z.I. Kazantseva 等 9 位作者1996-12-01Nanotechnology

Mixtures of the polyaniline (emeraldine base) and phosphorylated calix[4]resorcinolarene derivative (CA) are proposed to prepare LB films for conductometric gas sensors. They are quite stable at the air - water interface and give LB films of high quality. The average thickness of the mixed monolayers is found to be 1.…

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

Freshwater diatom communities of the Strømness Bay area, South Georgia

Bart Van de Vijver、Louis Beyens1996-12-01Antarctic Science

Modern diatom samples were collected from 43 sites across the Strømness Bay area of South Georgia. From 115 taxa belonging to 22 six diatom assemblages were distinguished. A CCA-analysis indicated that the assemblages are linked to pH and conductivity ranges, and habitat structure. The Eunotia paludosa var. paludosa -…

Marine Biology and Ecology ResearchDiatoms and Algae ResearchMarine and environmental studies

Effects of Grain Morphology and Texture on High Temperature Deformation in Oxide Dispersion Strengthened Ferritic Steels

Hirokazu Okada、Shigeharu Ukai、Masakí Inoue1996-12-01Journal of Nuclear Science and Technology

Oxide Dispersion Strengthened (ODs) ferritic steel is the promising candidate alloy for long-life core materials of fast reactor. A series of experiments, such as tensile tests, creep rupture tests, texture measurements and microstructure observations, are performed for the fabricated sheets of ODs ferritic steel with…

Fusion materials and technologiesHigh Temperature Alloys and CreepNuclear Materials and Properties

NMR in the 2D Organic Superconductors

P. Wzietek、H. Mayaffre、D. Jérôme 等 4 位作者1996-12-01Journal de Physique I

We review recent NMR studies of the layered organic superconductors of the (BEDT)2X family. First the normal state properties discussed. The central issue is the importance of the interplay between antiferromagnetism and superconductivity in these materials demonstrated by the observation of a pseudogap developing pri…

Quantum and electron transport phenomenaMolecular Junctions and NanostructuresOrganic and Molecular Conductors Research

Combined Cycle Gas Turbine Power Plant With Coal Gasification and Solid Oxide Fuel Cell

Kirill V. Lobachyov、H.J. Richter1996-12-01Journal of Energy Resources Technology

The United States has extensive coal resources; thus, it is important to consider coal as a fuel for electric power production. This work presents a theoretical study of a novel high-efficiency coal-fired power plant. In the proposed combined cycle power plant, the Conoco coal gasification process is linked with solid…

Catalytic Processes in Materials ScienceAdvancements in Solid Oxide Fuel CellsCatalysts for Methane Reforming

Evidence for Surface Changes During Ennoblement of Type 316L Stainless Steel: Dissolved Oxidant and Capacitance Measurements

Wayne Dickinson、Zbigniew Lewandowski、Richard D. Geer1996-12-01CORROSION

Ennobled open-circuit potential (Ecorr) for type 316L stainless steel (SS [UNS S31603]) exposed to fresh river water was investigated using microelectrodes to measure dissolved oxygen (DO), hydrogen peroxide (H2O2), and local Ecorr within biofouling deposits. Galvanostatic techniques were used to measure capacitance (…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsNon-Destructive Testing Techniques

A novel treatment process for dairy wastewater with chitosan produced from shrimp-shell waste

E. Selmer-Olsen、Harsha Ratnaweera、R. Pehrson1996-12-01Water Science & Technology

Recovery of proteins and fats from dairy wastewater has two advantages: the recovery process results in a pretreatment of wastewater prior to discharge to municipal sewers; and the recovered sludge can be used as a food additive. Carboxy Methyl Cellulose (CMC) is commonly used for the treatment of dairy wastewater aft…

Nanocomposite Films for Food PackagingFood and Agricultural Sciences

Immunoelectron microscopic localization of vimentin in sustentacular cells of the carotid body and the adrenal medulla of guinea pigs.

Yoko Kameda1996-12-01Journal of Histochemistry & Cytochemistry

The sustentacular cells of the carotid body and the adrenal medulla of guinea pigs were studied by light and electron microscopic immunohistochemistry and compared with the Schwann or satellite cells of the peripheral nervous system. In the peripheral nervous system, neurons were immunoreactive for protein gene produc…

Supramolecular Self-Assembly in Materials

Switching and dielectric nonlinearity of ferroelectric ceramics

G. Arlt1996-12-01Ferroelectrics

The switching of the polarization in tetragonal ferroelectric ceramics can be achieved by the generation of one new 90° domain wall at the boundary of every grain and a transit of it through the grain driven by the electric field. This transient domain wall is perpendicular to the regular 90° domain walls. In any doma…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesDielectric materials and actuators

Elastomeric diffraction gratings as photothermal detectors

John A. Rogers、Rebecca J. Jackman、Olivier Schueller 等 4 位作者1996-12-01Applied Optics

A photothermal detector consisting of a relief grating on the surface of an elastomer was fabricated and characterized. The detector has a sensitivity of the order of microwatts per square millimeter and has rise and fall times of the order of tens of seconds. Numerical and analytical modeling account for the behavior…

Advanced Fiber Optic SensorsOptical Coatings and GratingsAdvanced Sensor Technologies Research

The coordination numbers of Na and K atoms in low albite and microcline as determined from a procrystal electron-density distribution

Robert T. Downs、Aaron S. Andalman、Marc Hudacsko1996-12-01American Mineralogist

Other| December 01, 1996 The coordination numbers of Na and K atoms in low albite and microcline as determined from a procrystal electron-density distribution Robert T. Downs; Robert T. Downs Carnegie Institution of Washington, Geophysical Laboratory, Washington, DC, United States Search for other works by this author…

Crystal Structures and PropertiesClay minerals and soil interactionsX-ray Diffraction in Crystallography

Synthesis, characterization and properties of a soluble polymer with a poly(phenylenevinylene) structure

Francesco Babudri、Stefania R. Cicco、Gianluca M. Farinola 等 6 位作者1996-12-01Macromolecular Rapid Communications

Abstract Soluble poly(2,5‐dialkoxy‐1,4‐phenylenevinylene) has been prepared via Stille coupling reaction between 2,5‐dialkoxy‐1,4‐diiodobenzene and E ‐1,2‐bis(tributylstannyl)‐ethene in the presence of palladium complexes. Characterization of this material by means of 1 H and 13 C nuclear magnetic resonance (NMR), ult…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsPorphyrin and Phthalocyanine Chemistry

Organic matter retention in an upland humic podzol; the effects of pH and solute type

Jane Kennedy、M. F. Billett、D. M. L. Duthie 等 5 位作者1996-12-01European Journal of Soil Science

Summary This paper discusses the effects of different horizons and soil solution compositions on dissolved organic matter retention in a moorland podzol and compares the results with previous studies of forest podzols. Adsorption isotherms were constructed for each of the major horizons of a freely draining, upland, m…

Heavy metals in environmentSoil and Water Nutrient DynamicsClay minerals and soil interactions

Photocatalysis of H3PW12O40 for 4-Chlorophenol Decomposition in Aqueous Media

Hisahiro Einaga、Makoto Misono1996-12-01Bulletin of the Chemical Society of Japan

Abstract Photocatalytic properties of PW12O403− (abbreviated as PW123−) for the 4-chlorophenol (4-CP) decomposition was investigated by using a 300 W Xe lamp at 35 °C in aqueous media. The rate of the 4-CP decomposition was not influenced by pH in the range from 1.0 to 2.0, where PW123− is stable. In the dark, no reac…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Reactions

A new method for the preparation of conductive polyaniline solutions: Application to liquid crystal devices

Eli Harlev、Tamila Gulakhmedova、I. M. Rubinovich 等 4 位作者1996-12-01Advanced Materials

Transparent “all‐polymer” electrodes are promising candidates for applications in LCDs and LEDs and LEDs. A novel approach for making a new polyaniline‐based polymer is described, efficient solubilization of the conductive from of polyaniline is reported, and use of the resulting conductive polymer solutions for LCDs…

Organic Electronics and PhotovoltaicsAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Novel vitrifiable liquid crystals as optical materials

Shaw H. Chen、Hongqin Shi、Brooke M. Conger 等 5 位作者1996-12-01Advanced Materials

Vitrifiable liquid crystals (VLCs) have several advantages in optical applications: long‐term mesomorphic stability, environmental durability, ease of processing into thin films, and the capability of large aperture. A generic approach is demonstrated for the molecular design of VLCs with an elevated glass‐transition…

Liquid Crystal Research AdvancementsNonlinear Dynamics and Pattern FormationAdvanced Materials and Mechanics

Anaerobic Crystallisation of an Isopenicillin N Synthase · Fe(II) · Substrate Complex Demonstrated by X‐Ray Studies

Peter L. Roach、I.J. Clifton、Charles M. H. Hensgens 等 10 位作者1996-12-01European Journal of Biochemistry

Isopenicillin N synthase (IPNS) was cocrystallised with ferrous sulphate and its substrate, delta-(L-alpha-aminoadipoyl)-L-cysteinyl-D-valine (Aad-Cys-Val). Vital to the successful procedure was the maintenance of a rigorously anaerobic environment. Hanging-drop vapour-diffusion crystallisation experiments, using lith…

Antibiotic Resistance in BacteriaEnzyme Structure and FunctionBiochemical and Molecular Research