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Aminosilanes in organic synthesis. Preparation of new expanded porphyrin ligands and bimetallic transition-metal complexes. Crystal structure of a tetrapyrrole macrocycle dirhodium complex

Françis Carré、Robert J. P. Corriu、Geng Bolin 等 5 位作者1993-07-01Organometallics

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAminosilanes in organic synthesis. Preparation of new expanded porphyrin ligands and bimetallic transition-metal complexes. Crystal structure of a tetrapyrrole macrocycle dirhodium complexF. H. Carre, R. J. P. Corriu, Geng Bolin, J. J. E. Moreau, and C. VernhetCite this: Org…

Porphyrin and Phthalocyanine ChemistryMolecular Junctions and NanostructuresFerrocene Chemistry and Applications

The ferroelectric behavior of odd-numbered nylons

Bin Mei、J. I. Scheinbeim、B. A. Newman1993-07-01Ferroelectrics

The combined results of the present investigation of Nylon 5 and Nylon 9 and the previous investigation of Nylon 11 and Nylon 7 reveal that the odd-numbered nylons exhibit classic ferroelectric J-E and D-E hysteresis behavior at room temperature. In addition, the remanent polarization, P r, of Nylon 5 and Nylon 9 is f…

Advanced Sensor and Energy Harvesting MaterialsPolymer Nanocomposites and PropertiesDielectric materials and actuators

Double‐Layered 1,4‐Distyrylbenzene Chromophores–Synthesis, UV and Fluorescene Spectra

Burkhard König、Burkhard Knieriem、Armin de Meijere1993-07-01Chemische Berichte

Abstract The reaction of [2.2]paracyclophane ( 1 ) with liquid bromine affords a 1:1 mixture of only two isomeric products, the pseudo‐para 2 and pseudo‐ortho tetrabromide 3 . The structure of the pseudo‐para isomer 2 has been determined by X‐ray structure analysis. Fourfold palladium‐catalyzed coupling with styrenes…

Catalytic Cross-Coupling ReactionsLuminescence and Fluorescent MaterialsPhotochromic and Fluorescence Chemistry

Hexaalkoxytricycloquinazolines: new discotic liquid crystals

Sandeep Kumar、Ellen Wachtel、Ehud Keinan1993-07-01The Journal of Organic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHexaalkoxytricycloquinazolines: new discotic liquid crystalsSandeep Kumar, Ellen J. Wachtel, and Ehud KeinanCite this: J. Org. Chem. 1993, 58, 15, 3821–3827Publication Date (Print):July 1, 1993Publication History Published online1 May 2002Published inissue 1 July 1993https:/…

Liquid Crystal Research AdvancementsNonlinear Optical Materials ResearchNonlinear Dynamics and Pattern Formation

Recover VOCs via adsorption on activated carbon

M.J. Ruhl1993-07-01Chemical engineering progress

One of the most effective methods of controlling emissions of volatile organic compounds (VOCs) is also one of the most economical--adsorption, usually using activated carbon as the adsorbent. This process is cost-effective because it is typically able to recover many VOCs for reuse. A particularly common application…

Catalytic Processes in Materials ScienceVehicle emissions and performanceAir Quality Monitoring and Forecasting

Unit Cell Geometry of 3-D Braided Structures

Guang-Wu Du、Frank Ko1993-07-01Journal of Reinforced Plastics and Composites

The traditional approach used in modeling of composites reinforced by three-dimensional (3-D) braids is to assume a simple unit cell geometry of a 3-D braided structure with known fiber volume fraction and orientation. In this article, we first ex amine 3-D braiding methods in the light of braid structures, followed b…

Mechanical Behavior of CompositesTextile materials and evaluationsStructural Analysis and Optimization

Suspension, dispersion, and interfacial polycondensation: A methodological survey

Reza Arshady、M. H. George1993-07-01Polymer Engineering and Science

Abstract This review presents a general picture of suspension, dispersion, and interfacial polycondensation processes employed for the preparation of beaded resins, dry powders, and high solid dispersions. The polymer systems covered include polyamides, polyesters, polycarbonates, polyurethanes, and phenol‐formaldehyd…

Crystallization and Solubility StudiesThermal and Kinetic AnalysisAdsorption, diffusion, and thermodynamic properties of materials

Comparison of Mo–N and W–N synergism during passivation of stainless steel through x-ray photoelectron spectroscopy and electrochemical analysis

Gary P. Halada、C.R. Clayton1993-07-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

In high nitrogen stainless steels and nitrogen surface-doped Mo-containing alloys, nitrogen has been shown to enhance passivity. The mechanism of this apparent Mo–N synergism appeared to be twofold. First, the formation of stable surface nitrides affects a reduction in active dissolution, and, second, reactions betwee…

Corrosion Behavior and InhibitionMetal and Thin Film MechanicsHydrogen embrittlement and corrosion behaviors in metals

Unexpected selectivity in the alkylation of polyazamacrocycles

William J. Kruper、Philip R. Rudolf、Charles A. Langhoff1993-07-01The Journal of Organic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTUnexpected selectivity in the alkylation of polyazamacrocyclesWilliam J. Kruper Jr., Philip R. Rudolf, and Charles A. LanghoffCite this: J. Org. Chem. 1993, 58, 15, 3869–3876Publication Date (Print):July 1, 1993Publication History Published online1 May 2002Published inissue…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesSynthesis and properties of polymers

Influence of sintering temperature on electrical properties of ZnO varistors

Shr‐Nan Bai、Tseung‐Yuen Tseng1993-07-01Journal of Applied Physics

The electrical properties of the ZnO varistors are demonstrated in this present study to be affected by the sintering temperature. The variation of the non-ohmic behavior with sintering temperature is indicated from I-V and C-V measurements to be a result of the changes of the interface defect density at the grain bou…

ZnO doping and propertiesAdvanced ceramic materials synthesisSemiconductor materials and interfaces

Combined magnetic-dipole and electric-quadrupole hyperfine interactions in rare-earth orthoferrite ceramics

Todd M. Rearick、Gary L. Catchen、James Adams1993-07-01Physical review. B, Condensed matter

Perturbed-angular-correlation (PAC) spectroscopy was used to measure combined nuclear-magnetic-dipole and nuclear-electric-quadrupole interactions in rare-earth orthoferrite (REO) ceramics, R${\mathrm{FeO}}_{3}$ (R=La,Pr,Nd,...,Lu). The rare-earth orthoferrites are canted antiferromagnets that have orthorhombically di…

Multiferroics and related materialsMagnetic Properties and Synthesis of FerritesAdvanced Condensed Matter Physics

Factors influencing the formation of elongated morphologies in immiscible polymer blends during melt processing

R. Gonzalez‐Nunez、Basil D. Favis、Pierre J. Carreau 等 4 位作者1993-07-01Polymer Engineering and Science

Abstract The morphology of the dispersed phase in immiscible polymer blends plays an important role in the determination of the final physical properties. This paper considers factors that influence the final state of deformation of the dispersed phase, and in particular, the formation of fibers and lamellae. Blends o…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesPolymer Foaming and Composites

The Use of Phosphazenes as Fire Resistant Materials

Christopher W. Allen1993-07-01Journal of Fire Sciences

A survey of the use of cyclo- and poly(phosphazenes) in fire resis tant applications is presented. Where appropriate, synthesis and commercial availability will be indicated. Two fundamentally different approaches, phosphazenes as additives or as intrinsically flame resistant materials, will be discussed. While the fo…

Flame retardant materials and properties

Highly conducting wire gratings in the resonance region

Hans Lochbihler、Ricardo A. Depine1993-07-01Applied Optics

We present a theoretical approach for calculating the fields diffracted by gratings made of highlyconducting wires that have a rectangular shape. The fields between the wires are represented in terms of modal expansions that satisfy the approximated impedance boundary condition. Our results show thatthis procedure is…

Plasmonic and Surface Plasmon ResearchPhotonic and Optical DevicesOptical Coatings and Gratings

Immunological Identification of the Major Disulfide-Linked Light Component of Silk Fibroin1

Kazunori Tanaka、Kazuyuki Mori、Shigeki Mizuno1993-07-01The Journal of Biochemistry

The light protein components of silk fibroin were analyzed by Western blotting using polyclonal antibodies against two synthetic peptides that are segment of the light (L-) chain [Yamaguchi et al. (1989) J. Mol. Biol. 210, 127-139] and P25 [Chevillard et al. (1986) Sericologia 26, 435-449], respectively, and against t…

Antimicrobial Peptides and ActivitiesSilk-based biomaterials and applicationsSilkworms and Sericulture Research

A model for hysteretic magnetic properties under the application of noncoaxial stress and field

M. J. Sablik、S. W. Rubin、L. A. Riley 等 6 位作者1993-07-01Journal of Applied Physics

Although descriptions of the effect of stress on spontaneous magnetization within a single domain already exist, there remains no adequate mathematical model for the effects of noncoaxial magnetic field and stress on bulk magnetization in a multidomained specimen. This article addresses the problem and provides a phen…

Magnetic properties of thin filmsMicrostructure and Mechanical Properties of SteelsMagnetic Properties and Applications

Ring‐opening oligomerization reactions using aluminium complexes of schiff's bases as initiators

Alain Le Borgne、Valérie Vincens、Muriel Jouglard 等 4 位作者1993-07-01Makromolekulare Chemie Macromolecular Symposia

Abstract Bifunctional telechelics with defined structure can be prepared by oligomerization of oxiranes, β‐butyrolactone and L‐lactide using aluminium Schiff's base complexes as initiators. Chiral initiator (SALCENAlCl) shows a stereoelective character leading to preferential oligomerization of one enantiomer from a r…

biodegradable polymer synthesis and propertiesSynthetic Organic Chemistry MethodsCarbon dioxide utilization in catalysis

Mesomorphic form of syndiotactic polystyrene as composed of small imperfect crystals of the hexagonal (.alpha.) crystalline form

Finizia Auriemma、Vittorio Petraccone、Francesco Dal Poggetto 等 7 位作者1993-07-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMesomorphic form of syndiotactic polystyrene as composed of small imperfect crystals of the hexagonal (.alpha.) crystalline formFinizia Auriemma, Vittorio Petraccone, Francesco Dal Poggetto, Claudio De Rosa, Gaetano Guerra, Carla Manfredi, and Paolo CorradiniCite this: Macro…

Polymer crystallization and propertiesMaterial Properties and Applications

Synergistic Effects of Inorganic and Organic Cations on Inhibitive Performance of Propargyl Alcohol on Steel Dissolution in Boiling Hydrochloric Acid Solution

D D N Singh、Atanu Dey1993-07-01CORROSION

The role of different inorganic cations of several elements and organic materials in combination with different concentrations of propargyl alcohol (PA) was investigated in an effort to control the dissolution of mild steel in boiling (102 ± 1°C) hydrochloric acid (HCl) solution. Inorganic cations of chromium (Cr6+),…

Corrosion Behavior and InhibitionConcrete Corrosion and Durability

Tetrahedral gold cluster [Au4]2+: crystal structure of {[(tert-Bu)3PAu]4}2+(BF4-)2.2CHCl3

Edgar Zeller、Holger Beruda、Hubert Schmidbaur1993-07-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTetrahedral gold cluster [Au4]2+: crystal structure of {[(tert-Bu)3PAu]4}2+(BF4-)2.2CHCl3Edgar Zeller, Holger Beruda, and Hubert SchmidbaurCite this: Inorg. Chem. 1993, 32, 15, 3203–3204Publication Date (Print):July 1, 1993Publication History Published online1 May 2002Publis…

Organometallic Complex Synthesis and CatalysisNanocluster Synthesis and ApplicationsInorganic Chemistry and Materials