Materials Literature
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We compared the relative toxicities of standard concentrations of two magnetic resonance imaging (MRI) contrast agents, ionic gadolinium diethylenetriaminepentacetic acid (DTPA) and low-osmolar gadolinium-1, 4, 7 tris (carboxymethyl)-10-(2'-hydroxypropyl)-1, 4, 7, 10 tetra-azacyclododecane (HP-DO3A) with that of the c…
The photoredox behavior of various iron meso-tetraarylporphyrins in ethanol-containing solvents is examined. The reduction of Fe(III) to Fe(II) is observed in every case under irradiation with light of 350-450 nm. The electron-drawing or -repelling power of the meso-aryl substituents are found to have a scarce influen…
The aqueous gel forming properties of three series of block copolymer surfactants, poloxamers, poloxamines, and Butronic® polyols, are briefly reviewed and compared. The differences in their gel formation properties are explained. Aqueous gel formation of these polymers is attributed to the aggregation of extended lin…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAsymmetric synthesis of the corynantheine alkaloids via an intramolecular Blaise reaction. (-)-Corynantheidol and (-)-dihydrocorynantheolRichard L. Beard and A. I. MeyersCite this: J. Org. Chem. 1991, 56, 6, 2091–2096Publication Date (Print):March 1, 1991Publication History…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA study of colloidal crystal morphology and orientation via polarizing microscopyYiannis Monovoukas and Alice P. GastCite this: Langmuir 1991, 7, 3, 460–468Publication Date (Print):March 1, 1991Publication History Published online1 May 2002Published inissue 1 March 1991https…
Electrochemical impedance spectroscopy measurements were conducted on rotating disk specimens of pure copper and commercial 90‐10 and 70‐30 copper‐nickel alloys over a 28 day period while immersed in an aerated aqueous 3.4% NaCl solution, after vapor deposition of a Pd layer and finally after stripping the detachable…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTConvenient syntheses of carboxylic acid functionalized fluoropolymer surfacesMolly S. Shoichet and Thomas J. McCarthyCite this: Macromolecules 1991, 24, 5, 982–986Publication Date (Print):March 1, 1991Publication History Published online1 May 2002Published inissue 1 March 19…
The softening of phonon modes is sensitive to stress. Both the internal tensile stress formed by Ti11Ni14 precipitates in Ni-rich Ti-Ni alloy and the internal stress introduced by thermal cycling in equiatomic Ti-Ni alloy have strong effects on the softening of phonon modes, especially on phonons with <111> polarizati…
The effects of exposures to high‐temperature gaseous atmospheres on the strength of Nicalon SiC fibers were investigated. The exposure conditions were as follows: (1) H 2 with various P H2O for 10 h at 1000° and 1200°C, and (2) air for 2 to 100 h at 800° to 1400°C. Individual fibers were tested in tension following ea…
Elastic modulus E 1 of crystalline regions in the direction parallel to the chain axis has been measured for various kinds of polyethylene (PE) with different microstructures, such as ultrahigh-modulus PE, linear low-density PE, high-pressure-crystallized PE, and a heat-drawn PE whose crystallite size exceeds its long…
Communication: Transformer cores and read‐write heads are two applications of micronsized ferrite powders. The powders (see figure) can be synthesized by the thermal decomposition of precursors in a solid solution, where, generally, atmospheric oxygen can be thought of as the oxidant. However, due to the low yields (∼…
ABSTRACT Clay mineral data, potassium-argon (K-Ar) ages, and mathematical model simulations indicate the important kinetic factors controlling the smectite to illite transformation (“illitization”) in Upper Cretaceous Mowry and Niobrara core and outcrop bentonites from the Denver basin. The data also provide additiona…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTToward a dinitrogen electroreduction catalyst: characterization of a bis-ammine, a .mu.2-hydrazine, a .mu.2-diazene, and a remarkably stable .mu.2-dinitrogen complex of a ruthenium cofacial diporphyrinJames P. Collman, James E. Hutchison, Michel Angel Lopez, Roger Guilard, a…
Shake flask experiments showed that Pseudomonas oleovorans began to be growth inhibited at 4.65 g of sodium octanoate liter, with total inhibition at 6 g liter. In chemostat studies with 2 g of ammonium sulfate and 8 g of octanoate liter in the feed, the maximum specific growth rate was 0.51 h, and the maximum specifi…
One important issue for providing life extension to operating boiling water nuclear reactors (BWRs) is the control of stress corrosion cracking in all sections of the primary coolant circuit. This paper links experimental and theoretical methods that provide understanding and measurements of the critical parameter, th…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSecond-order nonlinear optical poly(organophosphazenes): synthesis and nonlinear optical characterizationHarry R. Allcock, Alexa A. Dembek, Chulhee Kim, Robert L. S. Devine, Yongqiang Shi, William H. Steier, and Charles W. SpanglerCite this: Macromolecules 1991, 24, 5, 1000–…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTViscoelastic behavior of plasticized sulfonated polystyrene ionomersR. A. Weiss, J. J. Fitzgerald, and D. KimCite this: Macromolecules 1991, 24, 5, 1064–1070Publication Date (Print):March 1, 1991Publication History Published online1 May 2002Published inissue 1 March 1991http…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSite-selective oxygen exchange and substitution of organometallic groups in an amphiphilic quadruple-cubane-type cluster. Synthesis and molecular structure of [(MCp*)4V6O19] (M = rhodium, iridium)Yoshihito Hayashi, Yoshiki Ozawa, and Kiyoshi IsobeCite this: Inorg. Chem. 1991…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHeptadentate ligands for the lanthanides. The first structurally characterized example of a lanthanide heptadentate ligand complex: [tris(3-aza-4-methyl-6-oxohept-4-en-1-yl)amine]ytterbium(III)David J. Berg, Steven J. Rettig, and Chris OrvigCite this: J. Am. Chem. Soc. 1991,…
The stability fields of two high‐pressure polymorphs of ZrO 2 (ortho I and ortho II) were determined by both calorimetry and phase equilibrium experiments. Enthalpies of transition were measured by transposed temperature drop calorimetry. The entropies of transition and slopes of phase boundaries were calculated using…