Materials Literature
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The evolution of molecular hydrogen from UO 2 (100) surfaces exposed to water vapor has been studied using temperature programmed desorption. No hydrogen evolution is observed from well-annealed, pristine surfaces. Significant amounts of hydrogen, however, desorb from highly defected, ion-sputtered surfaces at ∼400 K.…
The preparation of proteins for structural and functional analysis using the Escherichia coli expression system is often hampered by the formation of insoluble intracellular protein aggregates (inclusion bodies). Transferring those proteins into their native states by in vitro protein folding requires screening for th…
Silk produced from the major ampullate (MA) gland supercontracts when wet, and in this paper, we investigate the consequences of high humidity and of the added load of water droplets condensing from saturated air on the mechanical integrity of the spiders' orb web. We measured the development of the supercontraction s…
Sintering of a palladium catalyst supported on alumina (Al2O3) in an oxidizing environment was studied by in situ transmission electron microscopy (TEM). In the case of a fresh catalyst, sintering of Pd particles on an alumina surface in a 500 mTorr steam environment happened via traditional ripening or migration and…
Paracetamol was precipitated from solution in acetone using compressed carbon dioxide (CO 2 ) as an antisolvent in a batch gas antisolvent (GAS) recrystallization process. In this study, the effect of specific carbon dioxide addition rate (0.067−6.0 min -1 ), temperature (5−40 °C), relative solute concentration in ace…
Abstract The ene reaction between plant oil triglycerides (such as soybean and sunflower oils) and paraformaldehyde was used to introduce a homoallylic hydroxyl functionality on the triglyceride. Paraformaldehyde and triglyceride were reacted in the presence of a Lewis acid catalyst, ethylaluminum dichloride, and hydr…
Lipases from different sources were screened to determine their relative performance to catalyze ω-pentadecalactone (PDL) ring-opening polymerization from the hydroxyl group of 2-hydroxyethyl methacrylate (2-HEMA) and ω-hydroxyl-ω‘-methacrylate−poly(ethylene glycol) [PEGMA ( M n 360)]. Novozym 435 was found to be the…
A molecular dynamic simulation of wet polypyrrole film was carried out, in both oxidized and reduced state. The system was modeled by two layers of polypyrrole, water and chloride ions (as counterions required for charge balance in the oxidized state) in atomic detail to provide an insight into some dynamic and steady…
Lysozyme adsorption at the silica/water interface has been studied using a new analytical technique called dual polarization interferometry. This laboratory-based technique allows the build up or removal of molecular layers adsorbing or reacting on a lightly doped silicon dioxide (silica) surface to be measured in ter…
In this study the inhibition by polyglycols of the swelling of montmorillonite in aqueous solutions was investigated through linear swelling and particle size distribution experiments. With addition of KCl, polyglycol adsorbing on montmorillonite can complex with K+ and promote clay particles aggregation and efficient…
We report results from molecular dynamics simulations of cooperative motion in a quasi-two-dimensional system of colloid particles. We find that the onset of the deviation of the single-particle displacement distribution from Gaussian form starts in the liquid phase and extends, with increasing magnitude, through the…
Heterogeneous catalysis is one of the oldest nanosciences. Although model catalysts can be designed, synthesized, and, to a certain degree, characterized, industrial heterogeneous catalysts are often chemically and physically complex systems that have been developed through many years of catalytic art, technology, and…
Three new azo-benzene-based push-pull chromophores with dendritic architecture were synthesized as active materials for electro-optic applications. These chromophores were synthesized in six or seven synthetic steps with an overall yield of around 80% per step and high purity. UV-vis spectroscopy showed significant in…
A polyoxometalate-macrocation ionic crystal of Cs5[Cr3O(OOCH)6(H2O)3][alpha-CoW12O40].7.5H2O (1a) was synthesized by the complexion of an inorganic metal-oxide cluster of [alpha-CoW12O40]6- and a macrocation of [Cr3O(OOCH)6(H2O)3]+. About 50% of the water of crystallization in 1a was desorbed by the evacuation to form…
CuSn alloy nanowires capped with Ni were prepared using sequential electrodeposition of nickel and a copper/tin bronze alloy into nanoporous alumina templates. The liberated nanowires were suspended in solvents and their behavior monitored using optical microscopy. The nanowires were oriented and spun in circles as “n…
Abstract The matrix of the composites that were used in this work was a commercial blend based on starch and cellulose derivatives. The biodegradable polymer was reinforced by short‐sisal fibers with a range in fiber content of 5–15 wt %. The effects of humidity on the diffusion coefficients, equilibrium moisture cont…
Abstract In this study, three cationic surfactants (hexadecyltrimethylammonium chloride, hexadecyldimethylbenzylammonium chloride, and octadecyltrimethylammonium chloride) were used to modify montmorillonite and polyethylene (PE)/maleic anhydride grafted polyethylene (PE‐ g ‐MAH)/organic‐montmorillonite (Org‐MMT) nano…
Hetero-epitaxial growth on a strain-relief vicinal patterned substrate has revealed unprecedented 2D long range ordered growth of uniform cobalt nanostructures. The morphology of a Co sub-monolayer deposit on a Au(111) reconstructed vicinal surface is analyzed by Variable Temperature Scanning Tunneling Microscopy (VT-…
The experimental solubility limit of Zr in Al is well-known. Al3Zr has a stable structure DO23 and a metastable one L12. Consequently there is a metastable solubility limit for which only few experimental data are available. The purpose of this study is to obtain by ab-initio calculations the solubility limit of Zr in…
We study the response of an adsorbed monolayer on a disordered substrate under a driving force using Brownian molecular-dynamics simulation. We find that the sharp longitudinal and transverse depinning transitions with hysteresis still persist in the presence of weak disorder. However, the transitions are smeared out…