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The Aspect Ratio and Gas Permeation in Polymer‐Layered Silicate Nanocomposites

Maged A. Osman、Vikas Mittal、Hans Rudolf Lusti2004-06-01Macromolecular Rapid Communications

Abstract Summary: Organophilized montmorillonite‐epoxy and ‐polyurethane nanocomposites, useful for packaging applications, were prepared and their oxygen permeability was measured. The composite morphology was mixed, exfoliated and intercalated, as shown by wide‐angle X‐ray diffraction (WAXRD) and transmission electr…

Silicone and Siloxane ChemistryPolymer Nanocomposites and PropertiesPolymer crystallization and properties

CVD Technique for Inco Nickel Foam Production

Vladimir Paserin、Sam Marcuson、Jun Shu 等 4 位作者2004-06-01Advanced Engineering Materials

Abstract In this paper, the capability of the CVD technique to produce uniform foams of different properties, with cell size ranging from ∼ 450 to ∼ 3200 μm, porosity from ∼ 70 to ∼ 98 %, and nominal thickness up to 3 mm is presented. In addition to the established application as a battery electrode material, some oth…

Anodic Oxide Films and NanostructuresNanoporous metals and alloys

Polypropylene/graphite nanocomposites by thermo‐kinetic mixing

T. G. Gopakumar、D. J. Y. S. Pagé2004-06-01Polymer Engineering and Science

Abstract Polypropylene (PP)/graphite nanocomposites have been prepared by melt‐mixing PP with different levels of graphite (G) and graphite oxide (GO) using maleated PP(PP‐g‐MA) and graphite oxide (GO) as interface modifiers. Melt‐mixing was achieved using a Gelimat, a high‐speed thermo‐kinetic mixer. The Gelimat syst…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Nanocomposite Synthesis and Irradiation

Fabrication and Characterization of a Nanowire/Polymer-Based Nanocomposite for a Prototype Thermoelectric Device

Alexis R. Abramson、Woochang Kim、Scott T. Huxtable 等 8 位作者2004-06-01Journal of Microelectromechanical Systems

This paper discusses the design, fabrication and testing of a novel thermoelectric device comprised of arrays of silicon nanowires embedded in a polymer matrix. By exploiting the low-thermal conductivity of the composite and presumably high-power factor of the nanowires, a thermoelectric figure of merit, higher than t…

Thermal Radiation and Cooling TechnologiesAdvanced Thermoelectric Materials and DevicesThermal properties of materials

Optically Functional Di-Urethanesil Nanohybrids Containing Eu3+ Ions

M. C. Gonçalves、V. de Zea Bermudez、Rute A. S. Ferreira 等 6 位作者2004-06-01Chemistry of Materials

Sol−gel derived poly(oxyethylene)/siloxane hybrids (di-urethanesils) doped with europium triflate, Eu(CF 3 SO 3 ) 3, were examined by XRD, 13 C and 29 Si MAS NMR and FT-IR, FT-Raman, and photoluminescence spectroscopies. The host framework of these materials consists of a siliceous network grafted through urethane lin…

Luminescence and Fluorescent MaterialsPorphyrin and Phthalocyanine ChemistrySynthesis and Properties of Aromatic Compounds

Temperature Antiquenching of the Luminescence from Capped CdSe Quantum Dots

Sander F. Wuister、Arie van Houselt、Celso de Mello Donegá 等 5 位作者2004-06-01Angewandte Chemie International Edition

Actively passivated: The surprising recovery of the luminescence intensity between 200 and 300 K for CdSe quantum dots gives insight into the importance of the interaction between the capping layer and the nanocrystal semiconductor. The vial on the left is at 160 K while the brightly luminescing solution on the right…

Chalcogenide Semiconductor Thin FilmsAdvanced biosensing and bioanalysis techniquesQuantum Dots Synthesis And Properties

BaTiO 3 ‐Based Ceramics for Tunable Microwave Applications

Antonio Feteira、Derek C. Sinclair、Ian M. Reaney 等 5 位作者2004-06-01Journal of the American Ceramic Society

The dielectric properties of BaTi 0.90 Ga 0.05 Nb 0.05 O 3 (BTGN) and Ba 0.60 Sr 0.40 TiO 3 (BST) ceramics prepared by the conventional solid‐state route have been investigated. Their relative potential for microwave (MW) tunable applications was assessed by the figure of merit ( K ) defined as K = [equation omitted]…

Microwave Dielectric Ceramics SynthesisFerroelectric and Piezoelectric MaterialsMultiferroics and related materials

Surface Passivation of Luminescent Colloidal Quantum Dots with Poly(Dimethylaminoethyl methacrylate) through a Ligand Exchange Process

Xiao-Song Wang、Tieneke E. Dykstra、Mayrose R. Salvador 等 6 位作者2004-06-01Journal of the American Chemical Society

Polydimethylaminoethyl methacrylate (PDMAEMA) was used as a multidentate ligand to modify the surface of CdSe/ZnS core-shell colloidal quantum dots in toluene with trioctylphosphine oxide (TOPO) as the surface ligand. Adsorption of PDMAEMA was accompanied by release of TOPO. The process is free of agglomeration, and t…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanocluster Synthesis and Applications

High-Concentration Dispersion of Single-Wall Carbon Nanotubes

Y. Sabba、Edwin L. Thomas2004-06-01Macromolecules

We report a novel method to exfoliate and disperse single-wall carbon nanotubes (SWNT) into organic and aqueous solutions. The method is based on treatment of single-wall carbon nanotubes with a solution of hydroxylamine hydrochloric acid salt [(NH 2 OH)(HCl)] and does not require truncation of the tubes or surface ad…

Graphene research and applicationsCarbon Nanotubes in CompositesNanopore and Nanochannel Transport Studies

Shape-Memory Polymers for Microelectromechanical Systems

Ken Gall、Peter Kreiner、David M. Turner 等 4 位作者2004-06-01Journal of Microelectromechanical Systems

This paper investigates the use of shape-memory polymer thin films in microelectromechanical systems (MEMS). shape-memory polymers possess the capacity to recover large-strain deformations by the application of heat and are candidates for small-scale transduction. The key advantages of shape-memory polymers are their…

Marine Biology and Environmental ChemistryMarine Sponges and Natural ProductsPolymer composites and self-healing

Properties of nitrogen-implanted p-type ZnO films grown on Si3N4/Si by radio-frequency magnetron sputtering

Chin-Ching Lin、San‐Yuan Chen、Syh‐Yuh Cheng 等 4 位作者2004-06-01Applied Physics Letters

An nitrogen-implanted p-type ZnO film has been grown on a Si substrate buffered with Si3N4 using radio-frequency magnetron sputtering. The Si3N4 buffer layer can effectively improve film stoichiometry and reduce the formation of oxygen vacancies compared to ZnO on Si. The electrical properties of the p-type ZnO films…

Gas Sensing Nanomaterials and SensorsZnO doping and propertiesGa2O3 and related materials

Magnetic properties of carbon structures

T. L. Makarova2004-06-01Semiconductors

Magnetic properties of the main allotropic modifications of carbon (diamond, graphite, nanographite, nanotubes, and fullerenes) are described. Properties of nanocarbon are considered from the standpoint of the interrelation between structural imperfection and magnetic ordering. Experimental data on high-temperature fe…

Boron and Carbon Nanomaterials ResearchGraphene research and applicationsCarbon Nanotubes in Composites

Low-temperature growth and properties of ZnO nanowires

Xuan Wang、Qingwen Li、Zhibo Liu 等 6 位作者2004-06-01Applied Physics Letters

ZnO nanowires were obtained through evaporation of zinc powders under a low temperature of 400 °C. These ZnO nanowires, in the diameter of ∼10 nm, were long and curved with lengths of tens of micrometers. High-resolution transmission electron microscopy showed these ZnO nanowires were mostly crystalline structure; how…

ZnO doping and propertiesGa2O3 and related materialsGas Sensing Nanomaterials and Sensors

Thermoset rubber/layered silicate nanocomposites. Status and future trends

J. Karger‐Kocsis、Chang‐Mou Wu2004-06-01Polymer Engineering and Science

Abstract This paper surveys the recent achievements with thermoset rubber/layered silicate nanocomposites considering their production methods, cure characteristics, structure and basic properties (mechanical, thermal and barrier). It was shown that the properties of the “nanoreinforced” rubbers strongly depend on the…

Polymer composites and self-healingConcrete and Cement Materials ResearchPolymer Nanocomposites and Properties

Evaluation of the physical and electrochemical properties of adobe reinforced and of its component materials

G. Pérez、R. Melo、H. Rojas 等 7 位作者2004-06-01Materiales de Construccion

The search of solutions to the habitacional crisis that exists in Latin America has favored to the use of the soil-cement-sisal, adobe reinforced like alternative material of building, in such sense, prevailing to determine the vulnerability of a building of this type, is for that reason that, the characterization of…

Erratum

V. Lemos、D. Silva、C.A. Luengo 等 5 位作者2004-06-01Materials Research

Influence of deformation on the kinetics of phase transformation in a forging steel during warm working

Mauro Aparecido Ferreira de Oliveira、Alberto Moreira Jorge Jr、Oscar Balancin2004-06-01Materials Research

Dilatometric techniques were used to determine the start and finish transformation heating temperatures for a carbon steel (0.30% C - 1.5% Mn). The mechanical behavior of the steel was measured by torsion testing in the temperature range of 700 to 820 °C with holding times ranging from 1 to 30 min. The flow stress cur…

Characterization of growth sectors in synthetic quartz grown from cylindrical seeds parallel to [0001] direction

Pedro Luiz Guzzo、Armando Hideki Shinohara、Harlan Allen Dantas Costa 等 6 位作者2004-06-01Materials Research

In the present study, the morphology and the impurity distribution were investigated in growth sectors formed around the [0001] axis of synthetic quartz crystals. Plates containing cylindrical holes and cylindrical bars parallel to [0001] were prepared by ultrasonic machining and further used as seed-crystals. The hyd…

Temperature coefficient of piezoelectric constants in Pb(Mg1/3 Nb2/3)O3 - PbTiO3 ceramics

Manuel Henrique Lente、Alberto Luís Zanin、Jovan Vasiljevic 等 6 位作者2004-06-01Materials Research

In this work, the thermal stability of piezoelectric constants of PMN-PT ceramics in the tetragonal and rhombohedral phases were investigated in a wide range of temperatures. The results showed that the tetragonal PMN-PT presented higher thermal stability and, consequently, the temperature coefficients for the piezoel…