Vincenzo Balzani、Paola Ceroni、Sven Gestermann 等 6 位作者2000-01-01Chemical Communications
In a fourth generation poly(propylene amine) dendrimer decorated with 32 dansyl units at the periphery and containing 30 aliphatic amine units in the interior, the strong fluorescence of all the dansyl units is quenched when a Co2+ ion is incorporated into the dendrimer.
Molecular Sensors and Ion DetectionDendrimers and Hyperbranched PolymersLuminescence and Fluorescent Materials
Jin Zhu、Charles A. Wilkie2000-01-01Polymer International
Nanocomposites of polystyrene and several organophilic clays have been prepared by a bulk polymerization technique. The resulting polymers have an intercalated structure and show enhanced thermal stability, as measured by thermogravimetric analysis and cone calorimetry, relative to virgin polystyrene, even when as lit…
Polymer crystallization and propertiesFlame retardant materials and propertiesPolymer Nanocomposites and Properties
Benjamin Thierry、Maryam Tabrizian、Chantal M. Trepanier 等 5 位作者2000-01-01Journal of Biomedical Materials Research
Nickel-titanium (NiTi) alloy derives its biocompatibility and good corrosion resistance from a homogeneous oxide layer mainly composed of TiO(2), with a very low concentration of nickel. In this article, we described the corrosion behavior of NiTi alloys after mechanical polishing, electropolishing, and sterilization…
Shape Memory Alloy TransformationsTitanium Alloys Microstructure and PropertiesBone Tissue Engineering Materials
W. Götze、Matthias Mayr2000-01-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics
The equations of the mode-coupling theory (MCT) for ideal liquid-glass transitions are used for a discussion of the evolution of the density-fluctuation spectra of glass-forming systems for frequencies within the dynamical window between the band of high-frequency motion and the band of low-frequency-structural-relaxa…
Material Dynamics and PropertiesGlass properties and applicationsBiofield Effects and Biophysics
Jeremy C. Goodwin、Roberta Sessoli、Dante Gatteschi 等 6 位作者2000-01-01Journal of the Chemical Society Dalton Transactions
Ligands of general formula N(CHRCH2OH)(CH2CO2H)2 have been used to capture portions of the Fe(OH)2+ lattice to give particles containing up to nineteen magnetically coupled iron(III) centres. If R = Me or Et, lattices containing only Fe19 clusters result and single crystal X-ray diffraction shows that these are arrang…
Magnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Catalyzed Oxygenation Mechanisms
José L. Segura、Nazario Martı́n2000-01-01Journal of Materials Chemistry
Some of the current directions in research on new organic materials based on functionalized oligoarylenes are reviewed. Particular emphasis is placed upon the use of chemical synthesis for the incorporation of suitable functionalized oligoarylenes into more complex molecular and polymeric systems. Selected examples of…
Luminescence and Fluorescent MaterialsPhotochromic and Fluorescence ChemistryPorphyrin and Phthalocyanine Chemistry
J. F. Suyver、Sander F. Wuister、J. J. Kelly 等 4 位作者2000-01-01Physical Chemistry Chemical Physics
The luminescence properties of nanocrystalline ZnSe:Mn2+ prepared ia an inorganic chemical synthesis are described. Photoluminescence spectra show distinct ZnSe and Mn2+ related emissions, both of which are excited ia the ZnSe host lattice. The Mn2+ emission wavelength and the associated luminescence decay time depend…
Chalcogenide Semiconductor Thin FilmsSemiconductor Quantum Structures and DevicesQuantum Dots Synthesis And Properties
Emmanuel Flahaut、Alain Peigney、Christophe Laurent 等 4 位作者2000-01-01Journal of Materials Chemistry
A carbon nanotube–Co–MgO composite powder is prepared by reducing a Mg0.9Co0.1O solid solution in H2–CH4 atmosphere. The oxide matrix and part of the Co catalyst are dissolved by acid treatment without damage to the nanotubes. More than 80% of the carbon nanotubes have either one or two walls. The diameters of the nan…
Carbon Nanotubes in CompositesGraphene research and applicationsNanotechnology research and applications
Botho Hoffmann、Christoph F. Dietrich、Ralf Thomann 等 5 位作者2000-01-01Macromolecular Rapid Communications
A correlation between morphology development and rheology of polystyrene nanocomposites based upon organophilic layered silicates (organoclay) such as fluoromicas was found as a function of the silicate modification. Organoclay was obtained by means of ion exchange of clay with protonated amine-terminated polystyrenes…
Polymer Nanocomposites and Propertiesbiodegradable polymer synthesis and propertiesPolymer composites and self-healing
Hayao Kobayashi、Akiko Kobayashi、P. Cassoux2000-01-01Chemical Society Reviews
BETS-based salts (BETS = bis(ethylenedithio)tetraselenafulvalene) incorporating Fe3+ ions are most interesting candidate systems for the observation of interplay of conductivity and magnetism. Indeed, in λ-(BETS)2FeCl4, conduction electrons in the BETS layers do interact with spins localised on the (FeCl4)− anions. Sy…
Perovskite Materials and ApplicationsMagnetism in coordination complexesOrganic and Molecular Conductors Research
Peter M. Price、James H. Clark、Duncan J. Macquarrie2000-01-01Journal of the Chemical Society Dalton Transactions
A wide variety of novel materials can be prepared through the chemical modification of silica gels with organic and inorganic functionalities. In addition to their use in chromatographic separations, they have been increasingly used as catalysts in liquid phase organic reactions. It is the application of these materia…
Zeolite Catalysis and SynthesisChemical Synthesis and CharacterizationMesoporous Materials and Catalysis
Andreeta J.P.、Jovanic B.R.2000-01-01Materials Research
High-Temperature Solution crystal growth experiments on Cr3+ doped GdAlO3, are described where the flux and solute stoichiometry was changed for the process optimization to obtain homogeneous and inclusion free larger crystals. Transparent single crystals up to 3.8 cm³ have been grown. The pressure-induced wavelength…
de Biasi R.S.、Ruela A.C.O.、Elias C.N. 等 4 位作者2000-01-01Materials Research
The austenitic stainless steel of orthodontic wires may undergo phase transformation induced by plastic deformation and heat treatment for stress relief. In order to study these changes, arches were made with 0.0215 x 0.027" orthodontic wires and ferromagnetic resonance measurements were performed. The results showed…
A Inoue, C Fan, J Saida and T Zhang2000-01-01Science and Technology of Advanced Materials
It was recently found that the addition of special elements leading to the deviation from the three empirical rules for the achievement of high glass-forming ability causes new mixed structures consisting of the amorphous phase containing nanoscale compound or quasicrystal particles in Zr–Al–Ni–Cu–M (M=Ag, Pd, Au, Pt…
H Ichinose2000-01-01Science and Technology of Advanced Materials
Several contributions of HRTEM on the interface science are reviewed in chronological order. The first contribution of HRTEM is the observation of gold (113)Σ°11 boundary, giving experimental proof of the CSL model. An observation of the asymmetric (112)Σ°3 boundary follows. A SiC grain boundary is effectively assesse…
Zanotto Edgar Dutra2000-01-01Materials Research
Souza M.F. de、Batista P.S.、Regiani I. 等 5 位作者2000-01-01Materials Research
Silica was extracted from rice hulls by three processing routes, starting with acid treatment followed by burning and milling. The amorphous white silica powder showed a surface area of 260 to 480 m²/g, purity above 99% and average particle size of 2.0 to 0.6 mm. This silica is suitable for the preparation of mullite…
S Asai2000-01-01Science and Technology of Advanced Materials
Application of electromagnetic force to materials processing, so called Electromagnetic Processing of Materials (EPM) has been recognized as a cutting edge technology, especially in the fields of advanced materials processing. The background to promote EPM is described. The present state of EPM is given through a brie…
Martínez Espinosa Mariano、Calil Jr. Carlito2000-01-01Materials Research
Medium Density Fiberboard (MDF) is a wood-based composite widely employed in several industrial applications, in addition to its use in structures subjected to dynamic loads. Its fatigue-related aspects, however, have been consistently ignored. This work proposes to study fatigue in MDF, including the following factor…
K Ishihara2000-01-01Science and Technology of Advanced Materials
Novel polymer biomaterials, which can be used in contact with blood, are prepared with strong inspiration from the surface structure of biomembrane. That is, the polymers with a phospholipid polar group in the side chain, 2-methacrylooyloxyethyl phosphorylcholine (MPC) polymers were synthesized. The MPC polymers can i…