Materials Literature
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Abstract Nanocomposites (NCs) composed of an amorphus polyamide (aPA) (Selar® PA 3426) that contains a 2:1 ratio of amide to aromatic groups, and a single alkyl tail modified organoclay (OMMT) (Nanomer® I30 TC) were prepared by melt extrusion and ulterior injection molding. Our results show minor intercalation of the…
Abstract We synthesized a series of n ‐alkylthiomethyl‐substituted polystyrenes (#T‐PS, # = 4, 8, 12, and 16) and n ‐alkylsulfonylmethyl‐substituted polystyrenes (#S‐PS, # = 4, 8, 12, and 16), where # is the number of carbon atoms in the n ‐alkyl side group of the polymers, using polymer analogous reactions to investi…
The normal paper used in any printer is among the cheapest flexible organic materials that exist. We demonstrate that we can print on paper high-frequency circuits tunable with an applied dc voltage. This is possible with the help of an ink containing functionalized carbon nanotubes and water. After the water is evapo…
We present a numerical study of electron transport in a thin film of varying disorder strength with the distance from its surface. A simple tight-binding model is used to describe the system, in which the film is attached to two metallic electrodes and the coupling of this film to the electrodes is illustrated by the…
An oscillatory dependence of the drain current on the drain voltage is found in a nanostructure consisting of two crossing semiconductor carbon nanotubes that are suspended over a dielectric trench, which is backed by a doped silicon substrate that acts as a gate. Alternating positive and negative differential resista…
Porphyrin nanotubes (PNTs) are prepared by self-assembly using meso-tetrakis (4-sulfonatophenyl) porphyrin and Fe(III) meso-Tetra (N-Methyl-4-Pyridyl) porphyrin in water as starting materials. Long tubes of about one micron diameter are formed with bunches of smaller tubes attached to it, as judged from the analysis o…
D-3-Hydroxybutyrate dehydrogenase (HBDH) from Pseudomonas fragi showed a strict stereospecificity to the d-enantiomer of 3-hydroxybutyrate (d-3-HB) as a substrate. The l-enantiomer acts as a competitive inhibitor, with a K(i) value comparable to the K(m) value for d-3-HB. We have determined the crystal structures of t…
The ability to actively control the shape of aerospace structures has spawned the use of shape memory alloy actuators. These actuators can be used for morphing or shape control by modulating their temperature, which is effectively done by applying a voltage difference across their length. Characterization of this temp…
Magnetic lithography is based on a magnetic mask installed on the back of a substrate and the magnet that is set under the mask, which induce a magnetic field toward the substrate through the pattern of the masks. Magnetic nanoparticles are immobilized on selective locations, where the mask induces a magnetic field, r…
The Wave Function Matching (WFM) technique has recently been developed for the calculation of electronic transport in quantum two-probe systems. In terms of efficiency it is comparable with the widely used Green's function approach. The WFM formalism presented so far requires the evaluation of all the propagating and…
Polymeric compounds are of great interest as corrosion inhibitors in acidic environment due to their inherent stability. Polymeric film is effectively used for the protection of metals partly owing to their capacity to act as a physical barrier between the metal surface and the corrosive environment. In this paper, a…
The corrosion properties of Mg-Al-Sr alloy was characterized with comparison to AZ91D alloy. With the addition of Mg-Sr master alloy, the grain size of Mg alloy refined and the corrosion resistance was improved. The experimental results indicated that the formation of small amount of Al4Sr phase was favorable to impro…
Crosslinked UPM/PHBV/PVP fibers were successfully prepared using electrospinning process. The active pharmaceutical ingredient tetracycline hydrochloride (TH) was loaded onto the electrospun fibers through after-treatment method. Scanning electron microscopy (SEM), Fourier-transform infrared (FTIR) and in vitro dissol…
The microstructures, mechanical properties, and formability of an Mg-1.5Zn-0.1Zr alloy with rare earth element of Erbium addition have been examined by using optical microscopy, scanning electron microscopy/energy dispersive X-ray spectroscopy, and thermal mechanical testing. The results showed that Erbium combined wi…
We have used solid-phase peptide synthesis to graft a peptide monolayer from a solid in order to modify the interfacial properties. We grafted a 15-residue peptide, EKEKEKEKEKEKEGG, containing a zwitterionic sequence of alternating lysine and glutamic acid residues from the surface of an aminosilanized silicon wafer b…
Magnesium alloys are considered as candidate materials for biodegradable implants. However, the key issue is that they corrode too fast in physiological environment. The aim of this study is to investigate the effect of microstructure and texture of magnesium alloys on their corrosion resistance. Magnesium alloy AZ31…
Efficient photoexcitation energy transfer in extended pi-electron conjugated molecules is a key factor in applications of such systems as a gain media in signal-amplifying fluorescent chemodetectors. Here we report an unprecedented ratiometric fluorescence amplification phenomenon in the surface-immobilized monolayers…
Abstract Diffusion of single molecules of a substituted terrylene diimide dye in functionalized mesoporous silica films was monitored by single‐molecule fluorescence microscopy. By varying the chemical nature and density of the functional groups, the diffusion dynamics of the dye molecules can be controlled precisely.…
In this work, we have synthesized LaNi5/A and Mg2Ni/A (A = graphite, copper or palladium) nanocomposites. The A elements were distributed on the surface of ball milled alloy particles homogenously and role of these particles is to catalyze the dissociation of molecular hydrogen on the surface of studied alloy. Mechani…
In present work, trace elements Sr and Nd were added into AZ91-1wt%Si alloys. The alloys were cast into a permanent mould and then machined into test bars. The microstructure and mechanical properties at room temperature of the specimens were investigated. Results showed that complicated Chinese script Mg2Si phase dec…