Materials Literature
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Nano-scale Y2Ti2O7 and Y2TiO5 oxides are the major features that provide high strength and irradiation tolerance in nano-structured ferritic alloys. Here, we employ density functional theory to study helium trapping in Y2TiO5. The results suggest that helium is more deeply trapped in Y2TiO5 compared to Y2Ti2O7. Helium…
Abstract Molybdenum oxide (MoO3) mixed tungsten oxide (WO3) thin films have been prepared by hybrid physico‐chemical synthesis involving microwave assisted sol‐gel synthesis (MW‐SGS) of WO3 followed by vacuum evaporation of MoO3 on fluorine doped tin oxide (FTO) coated glass substrates. The optostructural and morpholo…
Abstract Nitrogen‐rich quantum dots (N‐dots) were serendipitously synthesized in methanol or aqueous solution at a reaction temperature as low as 50 °C. These N‐dots have a small size (less than 10 nm) and contain a high percentage of the element nitrogen, and are thus a new member of quantum‐dot family. These N‐dots…
Organic luminophores are widely used in various optoelectronic devices, which serve for photonics, nuclear and particle physics, quantum electronics, medical diagnostics and many other fields of science and technology. Improving their spectral-luminescent characteristics for particular technical requirements of the de…
The purpose of this study was to determine the feasibility of an artificial esophagus using a three-layered poly(ε-caprolactone) (PCL)-silk fibroin (SF) scaffold in a rat model. The artificial esophagus was a three-layered, hybrid-type prosthesis composed of an outer and inner layer of PCL with a middle layer of SF. A…
The concern regarding the ecotoxicological effects of nanomaterials in the terrestrial environment is increasing. Against this background, several studies have investigated the effects of different nanomaterials on various earthworm species. Since the earthworm is a representative invertebrate present in soil and occu…
Novel photo and thermal dual-responsive inverse opal films were fabricated based on a crosslinked liquid crystal polymer (CLCP) containing azobenzene. Accompanying the deformation of the CLCP, switchable behavior on the reflection spectra of the inverse opal film was induced by light or temperature. We found that the…
ABSTRACT The most promising representative of biodegradable plastics in packaging applications is polylactide (PLA). Despite this, there is only a small market of PLA in Europe. Reasons for that are the high price of PLA raw material and the lack of knowledge of the behavior in packaging applications. It has a number…
Fascinating pictures that can be interpreted as showing molecular orbitals have been obtained with various imaging techniques. Among these, angle resolved photoemission spectroscopy (ARPES) has emerged as a particularly powerful method. Orbital images have been used to underline the physical credibility of the molecul…
In a recent paper, Xie et al. [Phys. Rev. B 88, 235128 (2013)], report that the density-functional theory (DFT) with the so-called DFT plus Hubbard $U$ $(\mathrm{DFT}\phantom{\rule{0.16em}{0ex}}+\phantom{\rule{0.16em}{0ex}}U)$ modification improves energetics, volumes, and formation enthalpies over the standard form o…
ABSTRACT Effect of various efficient vulcanization (EV) sulfur cure systems on the compression set of a nitrile rubber filled with carbon black and silica/silane fillers was examined. The cure systems had different amounts of thiuram and sulfenamide accelerators and elemental sulfur, whilst the loading of zinc oxide a…
An optoelectronic sensor for real-time leakage current monitoring on high-voltage (500 kV) and medium-voltage (13.8 kV) power line insulators was developed. The leakage current drives an ultrabright light-emitting diode producing an amplitude modulated light signal. The optically intensity-encoded signal is coupled to…
The contact between Ni(OH) 2 and graphene oxide (GO) determines the specific capacitance, high-rate performance, and stability of Ni(OH) 2 -GO composites when they were used as capacitive materials with high/ultrahigh material loading. To improve this contact, the exfoliated GO from Hummers’ method is oxidized twice f…
Paper-based substrates integrated with plasmonic nanostructures and combined with surface enhanced Raman spectroscopy (SERS) offer a flexible and lightweight platform for the ultrasensitive optical detection of analytes on any surface. Here, we incorporated multibranched gold nanoantennas (MGNs) on inexpensive filter…
Marine mussels utilize multiple bidentate complexes formed by Fe(iii) and DOPA in a mussel adhesive protein (fp-1) to reinforce tough and elastic byssal fibers as a specialized underwater adhesive aid. In this study, mussel-inspired electrospun nanofibers were fabricated using a recombinant mussel adhesive protein (rf…
Combined experimental and computational studies have been performed on the mechanism of formation of poly(hexahydrotriazine) and hemiaminal dynamic covalent network (PHT and HDCN) thermosetting polymers from the reactions of diamines with formaldehyde (Science 2014, 344, 732-735). Results suggest that these polymers a…
ABSTRACT Star copolymers have attracted significant interest due to their different characteristics compared with diblock copolymers, including higher critical micelle concentration, lower viscosity, unique spatial shape, or morphologies. Development of synthetic skills such as anionic polymerization and controlled ra…
Four porous poly(Schiff-base)s, PSN-DA, PSN-TAPB, PSN-TAPA and PSN-TAPM, are synthesized via one-pot condensation from 1,3,5,7-tetrakis(4-formylphenyl)adamantane with rod-like m-phenyldiamine, triangular 1,3,5-tris(4-aminophenyl)benzene and tris(4-aminophenyl)amine as well as tetrahedral tetrakis(4-aminophenyl)methane…
We describe the preparation of porous polymeric scaffolds via polymerization of the oil phase in high internal phase water-in-oil-emulsions using amphiphilic block copolymers polystyrene- b -poly(ethylene oxide), polystyrene- b -poly(acrylic acid), poly(1,4-butadiene)- b -poly(ethylene oxide), and poly(1,4-butadiene)-…
Owing to their versatility and biocompatibility, peptide-based self-assembled structures constitute valuable targets for complex functional designs. It is now shown that artificial capsules based on β-barrel binding motifs can be obtained by means of dynamic covalent chemistry (DCC) and self-assembly. Short peptides (…