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Turning Gold into “Diamond”: A Family of Hexagonal Diamond-Type Au-Frameworks Interconnected by Triangular Clusters in the Sr–Al–Au System

Andriy Palasyuk、Yuri Grin、Gordon J. Miller2014-01-31Journal of the American Chemical Society

A new homologous series of intermetallic compounds containing three-dimensional (3-d) tetrahedral frameworks of gold atoms, akin to hexagonal diamond, have been discovered in four related Sr-Au-Al systems: (I) hexagonal SrAl3-xAu4+x (0.06(1) ≤ x ≤ 0.46(1), P62m, Z = 3, a = 8.633(1)-8.664(1) Å, c = 7.083(2)-7.107(1) Å)…

Rare-earth and actinide compoundsQuasicrystal Structures and PropertiesInorganic Chemistry and Materials

Modeling and Simulation of Pulsed Electroacoustic Measurement Method

J. S. Chahal、C. C. Reddy2014-01-31IEEE Systems Journal

Pulsed electroacoustic (PEA) method is a very popular method for measurement of charge in dielectrics. In this method, an acoustic wave proportional to charge is generated by a pulsed HV. The acoustic wave traverses several material layers before being sensed and converted to electrical signal by a piezoelectric trans…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationElectrostatic Discharge in Electronics

Controllable Reversible Addition–Fragmentation Termination Monomers for Advances in Photochemically Controlled Covalent Adaptable Networks

Christopher R. Fenoli、James W. Wydra、Christopher N. Bowman2014-01-31Macromolecules

With the advent of systematically designed controllable reversible addition–fragmentation termination (CRAFT) compounds, we have identified structure–property relationships related to the RAFT compositional structure as it impacts photoplasticity in covalent adaptable networks (CANs). In this study, we have expanded t…

Advanced Polymer Synthesis and CharacterizationPolymer composites and self-healingSynthetic Organic Chemistry Methods

Versatile luminescence of Eu^2+,3+-activated fluorosilicate apatites M_2Y_3[SiO_4]_3F (M = Sr, Ba) suitable for white light emitting diodes

Shuyun Qi、Yanlin Huang、Taijū Tsuboi 等 5 位作者2014-01-31Optical Materials Express

Eu-doped fluorosilicate apatites M2Y3[SiO4]3F (M = Sr, Ba) are prepared by solid state reaction. Unlike conventional Eu-doped materials, coexistence of Eu3+ and Eu2+ ions is found from the photoluminescence of Eu-doped apatites M2Y3[SiO4]3F (M = Sr, Ba) which were prepared in reducing atmosphere. Eu2+ ions are convert…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsInorganic Fluorides and Related Compounds

Odd parity pairing and nodeless antiphases±in iron-based superconductors

Ningning Hao、Jiangping Hu2014-01-31Physical Review B

We discuss the sign change of superconducting order parameters in both real and reciprocal spaces when the odd parity spin singlet pairing proposed recently by Hu [Phys. Rev. X 3, 031004 (2013)] is allowed. We show that in this case an nodeless antiphase ${s}^{\ifmmode\pm\else\textpm\fi{}}$ can be generated. In a 2-Fe…

Corporate Taxation and AvoidanceIron-based superconductors research

Novel Model for the Description of the Controlled Release of 5-Fluorouracil from PLGA and PLA Foamed Scaffolds Impregnated in Supercritical CO2

Leticia I. Cabezas、Ignacio Gracia、Antonio de Lucas 等 4 位作者2014-01-31Industrial & Engineering Chemistry Research

Porous biodegradable polymeric foams loaded with drugs have potential applications in tissue engineering and sustained delivery systems. A single-step process using supercritical CO 2 as a foaming and carrier agent was used for the impregnation of 5-fluorouracil in polylactide and poly(lactide- co -glycolide) probes.…

Bone Tissue Engineering MaterialsOrthopaedic implants and arthroplastybiodegradable polymer synthesis and properties

2,6‐Bis(arylsulfonyl)anilines as Fluorescent Scaffolds through Intramolecular Hydrogen Bonds: Solid‐State Fluorescence Materials and Turn‐On‐Type Probes Based on Aggregation‐Induced Emission

Teruo Beppu、So Kawata、Naoya Aizawa 等 7 位作者2014-01-31ChemPlusChem

A series of 2,6-bis[aryl(alkyl)sulfonyl]anilines were synthesized by nucleophilic aromatic substitution of 2,6-dichloronitrobenzene with various aryl or alkyl thiolates (benzyl-, phenyl-, 2-naphthyl-, and 2-aminophenyl thiolate), followed by hydrogenation and subsequent oxidation. All prepared 2,6-bis[aryl-(alkyl)sulf…

Molecular Sensors and Ion DetectionOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

Hyperbranched Polymer–Gold Nanoparticle Assemblies: Role of Polymer Architecture in Hybrid Assembly Formation and SERS Activity

Priyanka Dey、Idriss Blakey、Kristofer J. Thurecht 等 4 位作者2014-01-31Langmuir

Plasmonic gold nanoassemblies that self-assemble with the aid of linking molecules or polymers have the potential to yield controlled hierarchies of morphologies and consequently result in materials with tailored optical (e.g., localized surface plasmon resonances (LSPR)) and spectroscopic properties (e.g., surface-en…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesNanocluster Synthesis and Applications

ZnO-Based Ultraviolet Photodetectors With Novel Nanosheet Structures

Sheng‐Joue Young、Yi-Hsing Liu、Chih-Hung Hsiao 等 8 位作者2014-01-31IEEE Transactions on Nanotechnology

This study presents the fabrication of ZnO nanosheets on a glass substrate using a room-temperature (approximately 25 °C) solution method. The average length and diameter of the ZnO nanosheets were 1.2 μm and approximately 5 nm, respectively. The ultraviolet (UV)-to-visible rejection ratio of the sample is approximate…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials

Chemical phosphorylation improves the moisture resistance of soy flour‐based wood adhesive

Dan Zhu、Srinivasan Damodaran2014-01-31Journal of Applied Polymer Science

ABSTRACT A green‐chemistry approach to improve the moisture resistance of soy flour (SF)‐based wood adhesive is described. Chemical phosphorylation of SF (PSF), using POCl 3 as the phosphorylating agent, dramatically increased its wet bond strength. The optimum POCl 3 :SF ratio that produced maximum wet bond strength…

Nanocomposite Films for Food PackagingNatural Fiber Reinforced CompositesLignin and Wood Chemistry

Nitrogen Deposition Effects on Diatom Communities in Lakes from Three National Parks in Washington State

Richard W. Sheibley、Mihaela Enache、Peter W. Swarzenski 等 5 位作者2014-01-31Water Air & Soil Pollution

The goal of this study was to document if lakes in National Parks in Washington have exceeded critical levels of nitrogen (N) deposition, as observed in other Western States. We measured atmospheric N deposition, lake water quality, and sediment diatoms at our study lakes. Water chemistry showed that our study lakes w…

Aquatic Ecosystems and Phytoplankton DynamicsSoil and Water Nutrient DynamicsDiatoms and Algae Research

Multicolor Emission in a Single‐Phase Phosphor Ca 3 Al 2 O 6 :Ce 3+ ,Li + : Luminescence and Site Occupancy

Yani He、Jilin Zhang、Wenli Zhou 等 8 位作者2014-01-31Journal of the American Ceramic Society

A single‐phase multicolor emitting phosphor, Ca 3 Al 2 O 6 :Ce 3+ ,Li + , was prepared by a solid‐state reaction. When the Ce 3+ concentration is lower than 0.030 (molar ratio in Ca 3 Al 2 O 6 ), yellow and greenish blue emissions can be observed under the excitation by a blue and a near UV light, respectively. The ye…

Advanced Photocatalysis TechniquesLuminescence Properties of Advanced MaterialsAmmonia Synthesis and Nitrogen Reduction

Voltage Tunable Multiferroic Phase Shifter With YIG/PMN-PT Heterostructure

Xi Yang、Yuan Gao、Jian Wu 等 7 位作者2014-01-31IEEE Microwave and Wireless Components Letters

Compact voltage tunable phase shifters on yttrium iron garnet/lead magnesium niobate lead titanate heterostructure are presented. A comparison of E-field tunability between 1-layer PMN-PT structure and two-layer PMN-PT structure using bending mode is discussed. The device exhibited a phase shift of 119 ° under an elec…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMagneto-Optical Properties and Applications

New Type of Super-Lightweight Magnesium Phosphate Cement Foamed Concrete

Yue Li、Bing Chen2014-01-31Journal of Materials in Civil Engineering

Most previous investigations on foam concrete have been confined to portland cement and the density range of 400–1,600 kg/m3. The present study aims to develop a new foam concrete with a density ranging from 250 to 400 kg/m3 by replacing portland cement with magnesia phosphate cement (MPC). Extensive laboratory tests…

Magnesium Oxide Properties and ApplicationsEnvironmental Engineering and Cultural Studies

A Rotary Actuator Using Shape Memory Alloy (SMA) Wires

Donghyun Hwang、Toshiro Higuchi2014-01-31IEEE/ASME Transactions on Mechatronics

This paper presents the conceptual design, operating principle, simplified geometric model-based parametric analysis, experimental driving characterization, and working performance verification of a rotary actuator using shape memory alloy (SMA) wires. To achieve the research goal for developing a bidirectional SMA ro…

Shape Memory Alloy Transformations

Intelligent Control of Electroactive Polymer Actuators Based on Fuzzy and Neurofuzzy Methodologies

Christopher M. Druitt、Gürsel Alıcı2014-01-31IEEE/ASME Transactions on Mechatronics

Conjugated conducting polymer actuators, especially those based on polypyrrole (PPy), possess enormous potential for the creation of biomimetic devices, single-cell manipulators, numerous biomedical applications as well as robotics and prosthetics. This is due to their low actuation voltage, ability to operate at the…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsAnalytical Chemistry and Sensors

Thermal Resistance Analysis of Sn-Bi Solder Paste Used as Thermal Interface Material for Power Electronics Applications

Rui Zhang、Jian Cai、Qian Wang 等 7 位作者2014-01-31Journal of Electronic Packaging

To promote heat dissipation in power electronics, we investigated the thermal conduction performance of Sn-Bi solder paste between two Cu plates. We measured the thermal resistance of Sn-Bi solder paste used as thermal interface material (TIM) by laser flash technique, and a thermal resistance less than 5 mm2 K/W was…

Electronic Packaging and Soldering TechnologiesThermal properties of materialsAdhesion, Friction, and Surface Interactions

Transport properties and valence band feature of high-performance (GeTe)85(AgSbTe2)15thermoelectric materials

Ye Chen、Christopher M. Jaworski、Yuan Gao 等 8 位作者2014-01-31New Journal of Physics

This paper aims at elucidating the origin of the high thermoelectric power factor of p-type (Ag x SbTe x /2+1.5 ) 15 (GeTe) 85 (TAGS) thermoelectric materials with 0.4 ⩽ x ⩽ 1.2. All samples exhibit good thermoelectric figures of merit ( zT) which reach 1.5 at 700 K for x = 0.6. Thermoelectric and thermomagnetic trans…

Advanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin FilmsThermal Radiation and Cooling Technologies

Visible-Blind Photodetectors With Mg-Doped ZnO Nanorods

Yi-Hsing Liu、Sheng‐Joue Young、Chih-Hung Hsiao 等 7 位作者2014-01-31IEEE Photonics Technology Letters

In this letter, Mg-doped ZnO nanorods were fabricated successfully on a glass substrate at 80°C by hydrothermal method. The visible-blind photodetectors show good stability properties in ultraviolet (UV) illumination. The resulting Mg-doped ZnO nanorods have excellent potential for application in a UV photodetector be…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials

Air-Stable, Nanostructured Electronic and Plasmonic Materials from Solution-Processable, Silver Nanocrystal Building Blocks

Aaron T. Fafarman、Sung‐Hoon Hong、Soong Ju Oh 等 9 位作者2014-01-31ACS Nano

Herein we describe a room-temperature, chemical process to transform silver nanocrystal solids, deposited from colloidal solutions, into highly conductive, corrosion-resistant, optical and electronic materials with nanometer-scale architectures. After assembling the nanocrystal solids, we treated them with a set of si…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications