Materials Literature
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Two PHA synthase phaC1 and phaC2 genes cloned from the new strain Pseudomonas putida KCTC1639 were metabolically engineered for the overproduction of medium-chain-length polyhydroxyalkanoate (mcl-PHA). The overexpressed phaC1 and phaC2 genes in P. putida KCTC1639 were compared in terms of the biosynthesis of mcl-PHA,…
Reactions between the metal(II) salts [M(CH3CN)n](BF4)2 (M = Fe, n = 6; M = Mn, n = 4) and some organic anionic polynitriles were studied. With the pentacyanopropenide anion pcp− [pcp− = (NC)2CC(CN)C(CN)2−], were obtained, according to the experimental conditions, the new complexes [M(pcp)2(H2O)4] (1, M = Fe; 2, M = M…
Residual stress of thin diamond films deposited by chemical vapor deposition (CVD) method was measured using a new method for residual stress measurement we developed. Compressive residual stresses of CVD diamond films were determined from the height and diameter of protuberance of film delaminated by pulse laser spal…
We have investigated in situ and in real-time the formation process of anodic porous alumina on silicon using infrared absorption spectroscopy in the multiple internal reflection geometry (MIR-IRAS). We have collected IR absorption spectra of the interface between a porous alumina film and a Si substrate to elucidate…
Cf/SiC composite was brazed to Ti-alloy by using interlayer of Ag-Cu-Ti-C mixed powder. Microstructure and both the room temperature and 500°C shear strengths of the brazed joint were investigated. In situ synthesized TiCx (x≤1) is formed in the brazing layer of the joint by the reaction of C and Ti in the brazing lay…
A thermodynamic evaluation was performed to predict phase separation in multi-component oxide glasses. Composition ranges for metastable liquid–liquid immiscibility and spinodal decomposition in a SiO2–CaO–MgO–Na2O quaternary system were calculated on the assumption that glasses in the oxide system can be regarded as…
Individual perovskite-like LaCoO 3 obtained by the citrate method and LaCoO 3 supported onto the mesoporous molecular sieve MSM-41 have been characterized by X-ray powder diffraction, EPMA, low-temperature nitrogen adsorption, H 2 TPR, and EXAFS. The catalytic activity of the supported cobaltate in methanol oxidation…
In this study the thermal partial oxidation (TPOX) of Diesel fuel for the production of syngas was investigated theoretically and experimentally. Equilibrium and kinetic calculations were performed to determine the main influence parameters on the thermal partial oxidation. In the experimental study, a high-temperatur…
The crystal chemistry of the new mineral dissakisite-(La), the Mg-analogue of allanite-(La) with ideal formula CaLaAl 2 MgSi 3 O 12 (OH), was studied by single-crystal X-ray diffraction and Mössbauer spectroscopy. Diffraction data indicated that it has a partially metamict state with expanded cell parameters a = 8.959…
The first part of the paper deals with the computation of stress intensity factors for pyramidal indentation cracks with a ratio of crack length c to indentation half-diagonal a between 1 and 2. The residual stress field due to quasi-plastic deformation below the indenter is described by using the Hill model of an exp…
Mixtures of chrysotile (Mg6Si4O10(OH)8) and CaCO3 were burned at temperatures ranging from 500°C to 1000°C; the decomposition temperature of chrysotile was lowered by adding CaCl2. Thermal analysis and succeeding SEM observation confirmed the formation of melts, which was supposed to be responsible for the effect of t…
The FTIR spectra of poly(ether imide) films prepared from their chloroform solutions were recorded in a wide temperature interval. The cast films were shown to contain residual solvent. This residual solvent existed in films as unbound chloroform that may be removed by heating to 60–70°C and as bound chloroform that i…
Novel silicon-deficient mullite (Al5.65Si0.35O9.175) single crystal nanowires were synthesized in large quantities on mica substrates assisted by the intermediate fluoride species. The nanowires have diameters in the range 50-100 nm and typical lengths of several microm. Aligned nanowires were observed at the substrat…
Commercial sub-micron high purity α-Al2O3 powders ground and not ground in the manufacturing process, produced by three different processes; in-situ chemical vapor deposition (A1, A2 and A3), hydrolysis of aluminum alkoxide (B1, B2 and B2) and thermal decomposition of ammonium alum (C1 and C2) methods, were thermally…
A thermal manikin is a useful tool to evaluate thermal environments such as clothing, houses and others. A manikin needs to have the following properties: shape and size, heat production, skin temperature, sweat rate, physiological responses and others. So far, no manikin satisfying all these criteria has been availab…
In this work we present a deterministic numerical scheme solving the one-dimensional Boltzmann--Poisson system for semiconductor materials with a complicated band structure such as GaAs. The model is based on a system of two kinetic equations for the electron population in each of the relevant valleys coupled through…
A highly strained non-luminescent dibenzo-acridinium cationic compound is identified that undergoes in acetonitrile light-induced ring closure to create a highly fluorescent, planar, eight-ringed cationic anti-aromatic dye.
Blends of two highly crystalline polymers containing an elastomer were prepared to study the glass transition of the confined elastomer. The polymers chosen were high density poly ethylene (HDPE), polypropylene (PP), and two elastomers of a different nature: natural number (NR) and EPDM. The dynamic mechanical analyze…
Upconversion spectra of Er/Tm codoped NaY(WO(4))(2) crystal excited by 974nm laser is investigated. Intensive 520nm/550nm and 800nm emissions are observed. Three-photon process at high pumping power is presented in the green upconversion. A model is proposed that the three-photon process is actualized by the energy in…
Energy migration in self-assembled, water soluble, quantum dot (QD) nanoclusters is reported. These spherical nanoclusters are composed of CdSe QDs bound together by pepsin, a digestive enzyme found in mammals. A structural model for the clusters is suggested, based on scanning transmission electron microscopy, as wel…