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Batch cooling crystallization at constant supersaturation: Technique and experimental results

T. Gutwald、Alfons Mersmann1990-01-01Chemical Engineering & Technology

Abstract A new laboratory plant for batch cooling crystallization is described, which allows to maintain the supersaturation at a constant level during an experimental run. A method for continuous supersaturation measurements has been developed, using a density meter and a hydrocyclone. Experimental results obtained f…

Crystallization and Solubility Studiesnanoparticles nucleation surface interactionsFreezing and Crystallization Processes

Growth and lipid class composition of the marine diatom, Chaetoceros gracilis, in laboratory and mass culture turbidostats

Christopher C. Parrish、Peter J. Wangersky1990-01-01Journal of Plankton Research

Traditionally, laboratory study of phytoplankton ecology and physiology has been performed in batch cultures. Such cultures are also commonly used when phytoplankton are needed as a food supply for herbivores in an experimental or aquaculture setting. The great advantage of batch culture is its simplicity; however, in…

Diatoms and Algae Research

The glass transition: dynamic and static scaling approach

J. Souletie1990-01-01Journal de physique

We discuss the viscosity and the specific heat of glass forming systems near their glass transition in the framework of usual scaling theory at a second order transition. We define this transition through the Kauzmann paradox : i.e. we assume that all the entropy difference between the same crystal and the liquid phas…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesTheoretical and Computational Physics

The effect of the L‐azetidine‐2‐carboxylic acid residue on protein conformation. I. Conformations of the residue and of dipeptides

Adriana Zagari、George Némethy、Harold A. Scheraga1990-01-01Biopolymers

The L-azetidine-2-carboxylic acid (Aze) residue can be incorporated into proteins in the place of L-proline, of which it is the lower homologue. This substitution alters the properties of proteins, especially of collagen. Conformational constraints in N-acetyl-Aze-N'-methylamide and in several dipeptides containing Az…

Protein Structure and DynamicsChemical Synthesis and AnalysisCollagen: Extraction and Characterization

Monomeric surfactants for surface modification of polymers

Maria Torstensson、Bengt Rånby、Anders Hult1990-01-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMonomeric surfactants for surface modification of polymersMaria Torstensson, Bengt Ranby, and Anders HultCite this: Macromolecules 1990, 23, 1, 126–132Publication Date (Print):January 1, 1990Publication History Published online1 May 2002Published inissue 1 January 1990https:…

Microplastics and Plastic PollutionPolymer Surface Interaction Studies

Polymers : fibers and textiles : a compendium

Jacqueline I. Kroschwitz1990-01-01Wiley eBooks

Acrylic Fibers Cellulose Esters, Organic Fibers Composites, Fabrications Cotton Dyeing Fabrics, Coated Fibers Fibers, Elastomeric Fibers, Engineering Fibers, Manufacture Fibers, Vegetable Flammability Identification, Fibers Keratin Leatherlike Materials Nonwoven Fabrics Olefin Fibers Polyamides, Fibers Polyesters, Fib…

Textile materials and evaluations

Molecular precursors of bismuth oxide. Synthesis and structure of [Bi 2 (µ 2 -OC 2 H 4 OMe) 4 (OC 2 H 4 OMe) 2 ]∞, a one-dimensional ribbon-like chain

Marie-Cécile Massiani、R. Papiernik、L.G. Hubert-Pfalzgraf 等 4 位作者1990-01-01Journal of the Chemical Society Chemical Communications

Compounds [Bi(OBut)3]∞ and [Bi2(µ2-OC2H4OMe)4(OC2H4OMe)2]∞ have been obtained by metathesis reactions between bismuth halides and the appropriate alkali alkoxides; X-ray structure analysis shows a one-dimensional extended ‘skew’ chain structure based on dimeric asymmetric Bi2(OC2H4OMe)6 units in which the metal displa…

Crystal Structures and PropertiesInorganic Chemistry and MaterialsInorganic Fluorides and Related Compounds

Influence of phthalic anhydride as a coupling agent on the mechanical behavior of wood fiber–polystyrene composites

D. Maldas、B. V. Kokta1990-01-01Journal of Applied Polymer Science

Abstract The performance of phthalic anhydride used as a coupling agent in wood fiber‐filled polystyrene composites have been verified by evaluating the mechanical properties of the composites materials. Generally, mechanical properties improved along with the increase in concentrations of the coupling agent as well a…

Wood Treatment and PropertiesNatural Fiber Reinforced CompositesAdvanced Cellulose Research Studies

Statics and dynamics of hairpins in worm-like main chain nematic polymer liquid crystals

D. R. M. Williams、Mark Warner1990-01-01Journal de physique

We derive some exact results for the statics of solitary defects (« hairpins ») in the conformations of nematic main chain worm-like polymer liquid crystals in which there is both a bending and a nematic contribution to the potential energy. It is shown that for a polymer of finite length in mechanical equilibrium the…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesNonlinear Dynamics and Pattern Formation

Effects of interface debonding on the toughness of ductile-particle reinforced ceramics

Gang Bao、Chung‐Yuen Hui1990-01-01International Journal of Solids and Structures

A debonding-stretching model is proposed in this work to analyse the effects of interfacial debonding on the ductile particle toughening of ceramics. Perfect bonding imposes lateral constraints on the particles thus prohibiting the full utilization of the particle's inherent ductility. In contrast, partial debonding i…

Advanced ceramic materials synthesisRock Mechanics and ModelingHigh-Velocity Impact and Material Behavior

Polymers : polymer characterization and analysis

Jacqueline I. Kroschwitz1990-01-01Wiley eBooks

Characterization of Polymers. Chemical Analysis. Chromatography. Dielectric Relaxation. Dilatometry. Electron Diffraction. Electron Microscopy. Electron-Spin Resonance. Electrophoresis. Forensic Aspects. Fractionation. Identification. Impact Resistance. Infrared- Absorption Spectroscopy. Light Microscopy. Mass Spectro…

Polymer crystallization and propertiesInorganic and Organometallic ChemistryPolymer Science and PVC

A study of block copolymer adsorption kinetics via internal reflection interferometry

Mark R. Munch、Alice P. Gast1990-01-01Journal of the Chemical Society Faraday Transactions

We present a new experimental approach to investigate polymer adsorption onto dielectric surfaces. This technique, internal reflection interferometry, employs multiple total internal reflections through a prism to measure the average refractive index and thickness of adsorbed layers. The adsorption kinetics of poly(et…

Material Dynamics and PropertiesPolymer Surface Interaction StudiesElectrostatics and Colloid Interactions

Bapn Dose Dependence of Mature Crosslinking in Bone Matrix Collagen of Rabbit Compact Bone: Corresponding Variation of Sonic Velocity and Equatorial Diffraction Spacing

S.-H. Lee、David R. Eyre、Steven M. Barnard1990-01-01Connective Tissue Research

Crosslinking density in demineralized bone matrix collagen was found to depend on the beta-aminopropionitrile (BAPN) dose level for compact bone from rabbit femurs. The dependence was demonstrated for the hydroxypyridinium (HP) concentration, a mature crosslink. A more consistent dependence on BAPN dosage was observed…

Bone Tissue Engineering MaterialsBone health and osteoporosis researchCollagen: Extraction and Characterization

Effect of oxidation–reduction treatments on the infrared spectra of carbon monoxide chemisorbed on a Ru/TiO 2 catalyst

E. Guglielminotti、Geoffrey C. Bond1990-01-01Journal of the Chemical Society Faraday Transactions

The measurement of IR spectra of CO adsorbed on H2-reduced Ru/TiO2(1% Ru, Degussa P-25 TiO2) is made difficult by the very low transparency, caused by partial reduction of the support; reduction at 758 K leads to complete opacity, but spectra can be obtained by multiple scanning on a slightly oxidised sample (transpar…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsElectronic and Structural Properties of Oxides

Cardiac glycosides and pregnanes from Adenium obesum (Studies on the constituents of Adenium. I).

Tatsuo Yamauchi、Fumiko Abe1990-01-01Chemical and Pharmaceutical Bulletin

Cardiac glycosides and pregnanes from the roots and the stems of Adenium obesum Roem. et Schult. were investigated. Among 30 cardiac glycosides including 15 known glycosides and 15 new combinations of the known aglycones and sugars, the structures of 11 glycosides were elucidated. Oleandrigenin beta-gentiobiosyl-beta-…

Phytochemistry and Bioactive Compounds

Displacive transformations and quasicrystalline symmetries

M. Duneau、C. Oguey1990-01-01Journal de physique

The property, for quasiperiodic structures built by the cut and project or any equivalent method, to be related to a periodic lattice by a bounded deformation is a strong restriction on the window defining the strip, or on the atomic surface. We give a sufficient condition (which is also necessary in one dimension) fo…

Quasicrystal Structures and PropertiesMineralogy and Gemology Studies

The Effect of Superficial Hydration on the Mechanical Properties of Human Skin in Vivo

Gregor B. E. Jemec、Barbara Jemec、B. Jemec 等 4 位作者1990-01-01Plastic & Reconstructive Surgery

The influence of topically applied tap water on the mechanical properties of human skin was studied in vivo by applying tap water to the ventral aspect of the forearms of 18 healthy volunteers for 10 or 20 minutes and then measuring distensibility, elastic retraction, and hysteresis. Significant increases in distensib…

Textile materials and evaluations

Infrared spectroscopic surface characterization of zirconium oxide. Part 3.—The CO/CO 2 and CO/H 2 O interactions at the surface of a high-area monoclinic preparation

C. Morterra、L. Orio、C. Emanuel1990-01-01Journal of the Chemical Society Faraday Transactions

Carbon monoxide adsorbs at ambient temperature on microcrystalline monoclinic ZrO2, vacuum activated at 100–600°C, yielding two reversible σ-coordinated species, whose spectral positions depend linearly on the overall CO coverage, and whose frequencies at zero CO coverage depend on the residual surface concentration o…

Catalytic Processes in Materials ScienceAdvancements in Solid Oxide Fuel CellsCatalysis and Oxidation Reactions

Miscibility of copolymer blends

K. J. Zhu、S. F. Chen、Tai Ho 等 5 位作者1990-01-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMiscibility of copolymer blendsK. J. Zhu, S. F. Chen, Tai Ho, Eli M. Pearce, and T. K. KweiCite this: Macromolecules 1990, 23, 1, 150–154Publication Date (Print):January 1, 1990Publication History Published online1 May 2002Published inissue 1 January 1990https://pubs.acs.org…

Polymer crystallization and propertiesAdvanced Polymer Synthesis and Characterization