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Excited-State Proton and Charge Transfer in Protonated Amino and Methylated Derivatives of 2-(2′-Hydroxyphenyl)benzimidazole

Sonia Ríos Vázquez、J. Luis Pérez Lustres、Flor Rodríguez‐Prieto 等 5 位作者2014-10-01The Journal of Physical Chemistry B

We studied the excited-state behavior of a family of mono- and diprotonated derivatives of 2-phenylbenzimidazole in different solvents, using steady-state and time-resolved fluorescence spectroscopy. The species investigated were 2-(4'-amino-2'-hydroxyphenyl)benzimidazole (1), the diethylamino analogue 2-(4'-N,N-dieth…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesPhotoreceptor and optogenetics research

Spray coated indium-tin-oxide-free organic photodiodes with PEDOT:PSS anodes

Morten Schmidt、Aniello Falco、Marius Loch 等 5 位作者2014-10-01AIP Advances

In this paper we report on Indium Tin Oxide (ITO)-free spray coated organic photodiodes with an active layer consisting of a poly(3-hexylthiophen) (P3HT) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) blend and patterned poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) electrodes. External qu…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsNanowire Synthesis and Applications

Adsorption of soluble polymers at liquid interfaces and in foams

Cécile Monteux2014-10-01Comptes Rendus Physique

We review some results from the literature describing the structure and dynamics of polymer molecules adsorbed at liquid interfaces as well as their behavior in foams. The first part describes theoretical and experimental results concerning the structure and dynamics of model polymer systems, i.e. homopolymers and cop…

Surfactants and Colloidal SystemsPolymer Surface Interaction StudiesPickering emulsions and particle stabilization

Electron-hole imbalance and large thermoelectric effect in superconducting hybrids with spin-active interfaces

Mikhail S. Kalenkov、Andrei D. Zaikin2014-10-01Physical Review B

We argue that spin-sensitive quasiparticle scattering may generate electron-hole imbalance in superconducting structures, such as, e.g., superconducting-normal hybrids with spin-active interfaces. We elucidate a transparent physical mechanism for this effect demonstrating that scattering rates for electrons and holes…

Physics of Superconductivity and MagnetismQuantum and electron transport phenomenaMagnetic and transport properties of perovskites and related materials

Dry Friction Contribution to Damage‐Caused Increase of Damping in Fiber‐Reinforced Polymer‐Based Composites

Klaudiusz Holeczek、P. Kostka、Niels Modler2014-10-01Advanced Engineering Materials

The investigations deal with the contribution of the dry friction to the damage‐caused increase of the anisotropic material damping in composite materials. Plate specimens made of glass fiber reinforced epoxy were damaged in controlled impact tests using two different projectile's geometries at three different kinetic…

Mechanical Behavior of CompositesHigh-Velocity Impact and Material BehaviorStructural Response to Dynamic Loads

Gold Complexes for Focused-Electron-Beam-Induced Deposition

Willem F. van Dorp、Xian Wu、J.J.L. Mulders 等 6 位作者2014-10-01Langmuir

Four gold complexes were tested as a precursor for focused-electron-beam-induced deposition: [ClAu(III)Me2]2, ClAu(I)(SMe2), ClAu(I)(PMe3), and MeAu(I)(PMe3). Complexes [ClAu(III)Me2]2 and MeAu(I)(PMe3) are volatile, have sufficient vapor pressure at room temperature for deposition experiments, and were found to yield…

Semiconductor materials and devicesAdvanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy Techniques

Effect of Donor–Acceptor Substitution on Optoelectronic Properties of Conducting Organic Polymers

Ulrike Salzner2014-10-01Journal of Chemical Theory and Computation

The impact of donor-acceptor substitution on optical and electronic properties of conducting polymers was investigated with time-dependent density functional theory (TDDFT). A series of donor-acceptor systems with thiophene, 3,4-ethylenedioxythiophene, and pyrrole as donors and 3,4-difluorothiophene, diketopyrrolopyrr…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Novel Thermosensitive Pentablock Copolymers for Sustained Delivery of Proteins in the Treatment of Posterior Segment Diseases

Sulabh Patel、Ravi Vaishya、Xiaoyan Yang 等 5 位作者2014-10-01Protein and Peptide Letters

Biodegradable and injectable in situ thermosensitive hydrogels were investigated for sustained delivery of pro- tein therapeutics in the treatment of ocular posterior segment neovascular diseases. A series of triblock (TB, polycaprolac- tone-polyethylene glycol-polycaprolactone (PCL-PEG-PCL), B-A-B) and pentablock cop…

Nanoparticle-Based Drug DeliveryHydrogels: synthesis, properties, applicationsAdvanced Drug Delivery Systems

Focusing of liquid surface waves by gradient index lens

Zhenyu Wang、Pei Zhang、Xiaofei Nie 等 4 位作者2014-10-01Europhysics Letters (EPL)

In the long-wavelength limit, a periodic array of bottom-mounted vertical cylinders may be used as a homogeneous medium for liquid surface waves and their effective parameters, such as their refractive index, depending on the filling fraction of the cylinders. Based on this effective medium theory, a gradient index (G…

Metamaterials and Metasurfaces ApplicationsAcoustic Wave Phenomena ResearchAcoustic Wave Resonator Technologies

Double Skin Facades in Energy Efficient Design

Milja Penić、Nikolai Vatin、Vera Murgul2014-10-01Applied Mechanics and Materials

Double skin facade is one of the possible approaches to bioclimatic design. Bright architectural expression is combined with lots of potential natural heating and ventilation of the internal space of buildings. Double skin facade considered as an element of building heating, ventilation, or, finally, as an element of…

Construction Management and SustainabilityStructural mechanics and materialsAdvanced Energy Technologies and Civil Engineering Innovations

An in situ tensile test apparatus for polymers in high pressure hydrogen

Kyle J. Alvine、Tyler A. Kafentzis、Stan G. Pitman 等 8 位作者2014-10-01Review of Scientific Instruments

Degradation of material properties by high-pressure hydrogen is an important factor in determining the safety and reliability of materials used in high-pressure hydrogen storage and delivery. Hydrogen damage mechanisms have a time dependence that is linked to hydrogen outgassing after exposure to the hydrogen atmosphe…

Fuel Cells and Related MaterialsAdvanced Battery Technologies ResearchHydrogen Storage and Materials

Verification of selected models of the size effect based on high-cycle fatigue testing on mini specimens made of EN AW-6063 aluminum alloy

Tomasz Tomaszewski、Janusz Sempruch、T. Piątkowski2014-10-01Journal of Theoretical and Applied Mechanics/Mechanika Teoretyczna i Stosowana

The study presents several cases where use of specimens with reduced overall dimensions, i.e. mini specimens in the course of fatigue tests is advantageous. The high-cycle fatigue tests based on a developed method have been performed on mini specimens and normative specimens (comparative tests). The tests have been co…

Fatigue and fracture mechanicsHigh-Velocity Impact and Material BehaviorMechanical and Thermal Properties Analysis

Frustration phenomena in Josephson point contacts between single-band and three-band superconductors

Y. S. Yerin、A. N. Omelyanchouk2014-10-01Low Temperature Physics

Within the formalizm of Usadel equations the Josephson effect in dirty point contacts between single-band and three-band superconductors is investigated. The general expression for the Josephson current, which is valid for arbitrary temperatures, is obtained. We calculate current-phase relations for very low temperatu…

Physics of Superconductivity and MagnetismIron-based superconductors researchSuperconductivity in MgB2 and Alloys

Fully Porous GaN p–n Junction Diodes Fabricated by Chemical Vapor Deposition

Oleksandr V. Bilousov、Joan J. Carvajal、Hugh Geaney 等 10 位作者2014-10-01ACS Applied Materials & Interfaces

Porous GaN based LEDs produced by corrosion etching techniques demonstrated enhanced light extraction efficiency in the past. However, these fabrication techniques require further postgrown processing steps, which increases the price of the final system. Also, the penetration depth of these etching techniques is limit…

GaN-based semiconductor devices and materialsSemiconductor materials and devicesGa2O3 and related materials

Giant isothermal entropy change In (111)-oriented PMN–PT thin film

Mahmoud A. Hamad2014-10-01Journal of Advanced Dielectrics

An isothermal entropy change of 240 nm (111)-oriented PMN–PT 65/35 film near the ferroelectric Curie temperature, relative cooling power (RCP) and change of heat capacity have been investigated. The extracted data characterized giant isothermal entropy change of more than 16 J/kg K in electric field shift ΔE of 455 kV…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesSolid-state spectroscopy and crystallography

Circuits and AMOLED display with self‐aligned a‐IGZO TFTs on polyimide foil

Manoj Nag、Ajay Bhoolokam、Steve Smout 等 21 位作者2014-10-01Journal of the Society for Information Display

Abstract A process to make self‐aligned top‐gate amorphous indium‐gallium‐zinc‐oxide (a‐IGZO) thin‐film transistors (TFTs) on polyimide foil is presented. The source/drain (S/D) region's parasitic resistance reduced during the SiN interlayer deposition step. The sheet resistivity of S/D region after exposure to SiN in…

Thin-Film Transistor TechnologiesSilicon and Solar Cell TechnologiesSilicon Nanostructures and Photoluminescence

A short review of aging mechanism modeling of proton exchange membrane fuel cell in transportation applications

Elena Breaz、Fei Gao、Abdellatif Miraoui 等 4 位作者2014-10-01OpenAlex

This paper presents a short review of the aging mechanism modeling of proton exchange membrane (PEM) fuel cell in automotive applications. The fuel cell aging mechanism is particularly important for fuel cell transportation applications, because the degradation rates of a fuel cell could increase very fast when operat…

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsFuel Cells and Related Materials

Radiation asymmetries during disruptions on DIII-D caused by massive gas injection

N. Commaux、L. R. Baylor、T.C. Jernigan 等 14 位作者2014-10-01Physics of Plasmas

One of the major challenges that the ITER tokamak will have to face during its operations are disruptions. During the last few years, it has been proven that the global consequences of a disruption can be mitigated by the injection of large quantities of impurities. But one aspect that has been difficult to study was…

Magnetic confinement fusion researchFusion materials and technologiesSuperconducting Materials and Applications

Clavanin bacterial sepsis control using a novel methacrylate nanocarrier

Octávio Luiz Franco、Amanda Caroline Marques Saúde、Alicia Ombredani 等 10 位作者2014-10-01International Journal of Nanomedicine

Controlling human pathogenic bacteria is a worldwide problem due to increasing bacterial resistance. This has prompted a number of studies investigating peptides isolated from marine animals as a possible alternative for control of human pathogen infections. Clavanins are antimicrobial peptides isolated from the marin…

Antimicrobial Peptides and ActivitiesSupramolecular Self-Assembly in MaterialsProtein Hydrolysis and Bioactive Peptides

Bioinspired Catalysis, Metal-Sulfur Complexes

Wolfgang Weigand、Philippe Schollhammer、Apfel, Ulf-Peter2014-10-01HAL (Le Centre pour la Communication Scientifique Directe)

International audience

Corrosion Behavior and InhibitionChemical Synthesis and ReactionsOrganic Chemistry Cycloaddition Reactions